Topic
Methyl vinyl ketone
About: Methyl vinyl ketone is a research topic. Over the lifetime, 1510 publications have been published within this topic receiving 26839 citations. The topic is also known as: 3-buten-2-one & gamma-oxo-alpha-butylene.
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TL;DR: In this article, the first simple, stereoselective synthesis of (E)-3-(nitroxymethyl)alk-3-en-2-ones from Baylis-Hillman adducts was described.
17 citations
TL;DR: A number of 1-and 1-2-disubstituted cyclopropenes undergo [4+2]-cycloaddition to methyl vinyl ketone or acrolein at ambient temperature to produce 2-oxabicyclo[4.1.0]hept-3-enes as mentioned in this paper.
17 citations
TL;DR: In this paper, the Robinson annulation of hydroxycarvone with ethyl vinyl ketone has been repeated and the corresponding isomer was converted to 9-keto-α-agarofuran by epoxidation with m-chloroperoxybenzoic followed by reduction to a Stereoisomeric mixture of 10-epieuclesm-4-en-3,9,11-triols.
17 citations
TL;DR: The Stork-Jung vinylsilane reagent is prepared in two steps and in good overall yield, which provides rapid and efficient access to a useful methyl vinyl ketone surrogate.
Abstract: The Stork-Jung vinylsilane reagent (1) is prepared in two steps and in good overall yield. This provides rapid and efficient access to a useful methyl vinyl ketone surrogate.
17 citations
TL;DR: In this paper, 3-PhS(e)-(1),2-(di)halobutadienes undergo BF3 catalysed cycloadditions with methyl vinyl ketone at 25°C, to give good yields of adducts in which the regiochemistry of addition is mainly controlled by the sulfur (selenium) atom.
17 citations