Showing papers on "Microstructure published in 2005"

Wetting and self-cleaning properties of artificial superhydrophobic surfaces

Abstract: The wetting and the self-cleaning properties (the latter is often called the “Lotus-Effect”) of three types of superhydrophobic surfaces have been investigated: silicon wafer specimens with different regular arrays of spikes hydrophobized by chemical treatment, replicates of water-repellent leaves of plants, and commercially available metal foils which were additionally hydrophobized by means of a fluorinated agent. Water droplets rolled off easily from those silicon samples which had a microstructure consisting of rather slender spikes with narrow pitches. Such samples could be cleaned almost completely from artificial particulate contaminations by a fog consisting of water droplets (diameter range, 8−20 μm). Some metal foils and some replicates had two levels of roughening. Because of this, a complete removal of all particles was not possible using artificial fog. However, water drops with some amount of kinetic impact energy were able to clean these surfaces perfectly. A substrate where pronounced str...

Interfacial reactions between lead-free solders and common base materials

Abstract: The objective of this review is to study interfacial reactions between pure Sn or Sn-rich solders, and common base metals used in Pb-free electronics production. In particular, the reasons leading to the observed interfacial reactions products and their metallurgical evolution have been analyzed. Results presented in the literature have been critically evaluated with the help of combined thermodynamic–kinetic approach based on the concept of local equilibrium and microstructural knowledge. The following conclusions have been reached: Firstly, the formations of intermetallic compounds in solid/liquid reaction couples are primarily controlled by the dissolution processes of base metals. Other factors that need be considered are the thermodynamic driving force for the formation of intermetallic compounds, their structures and concentration profiles in liquid. Secondly, annealing of solder interconnections in solid state can drastically change the microstructures formed in the solid/liquid reactions, especially if only one of the components in the solder takes part in the interfacial reactions. Thirdly, additional elements can have three major effects on the binary reactions between a base metal and Sn: (i) they can increase or decrease the reaction/growth rates, (ii) the additives can change the physical properties of the phases formed, and (iii) they can form additional reaction products or displace the binary equilibrium phases by forming new reaction products. Finally, if the local stable or metastable equilibrium is established at the interface, stability information together with kinetic considerations can provide a feasible approach to analyze interfacial reactions, which can have significant impact on the reliability of soldered electronics assemblies.

Microstructure characterization of AlxCoCrCuFeNi high-entropy alloy system with multiprincipal elements

Abstract: A new approach for the design of alloy systems with multiprincipal elements is presented in this research. The Al x CoCrCuFeNi alloys with different aluminum contents (i.e., x values in molar ratio, x=0 to 3.0) were synthesized using a well-developed arc-melting and casting method. These alloys possessed simple fcc/bcc structures, and their phase diagram was predicted by microstructure characterization and differential thermal analyses. With little aluminum addition, the alloys were composed of a simple fcc solid-solution structure. As the aluminum content reached x=0.8, a bcc structure appeared and constructed with mixed fcc and bcc eutectic phases. Spinodal decomposition occurred further on when the aluminum contents were higher than x=1.0, leading to the formation of modulated plate structures. A single ordered bcc structure was obtained for aluminum contents larger than x=2.8. The effects of high mixing entropy and sluggish cooperative diffusion enhance the formation of simple solid-solution phases and submicronic structures with nanoprecipitates in the alloys with multiprincipal elements rather than intermetallic compounds.

Sintering: Densification, Grain Growth and Microstructure

Abstract: Basis of Sintering Science Solid State Sintering Models and Densification Grain Growth Microstructure Development Sintering of Ionic Compounds Liquid Phase Sintering

Microstructure evolution during FSW/FSP of high strength aluminum alloys

Abstract: Microstructural characteristics of friction stir processed (FSP) 7075 Al samples in different regions behind the pin tool were investigated. Furthermore, the microstructure evolutions during friction stir welding (FSW)/FSP has been revealed. Multi-mechanisms, including dDRX, grain growth, dislocation introduction, dynamic recovery (DRV) and cDRX, were found to be inherent in the process at different stages. Because inhomogeneous plastic deformation was introduced by the process, individual grains in the final microstructure have undergone different evolution mechanisms. These are either from growth of initially recrystallized grains or are the result of cDRX of subgrains formed during DRV. Grains within the processed region exhibit different densities of dislocations and are in various degrees of recovery.

Internal strain and texture evolution during deformation twinning in magnesium

Abstract: The development of a twinned microstructure in hexagonal close-packed rolled magnesium compressed in the in-plane direction has been monitored in situ with neutron diffraction. The continuous conversion of the parent to daughter microstructure is tracked through the variation of diffraction peak intensities corresponding to each. Approximately 80% of the parent microstructure twins by 8% compression. Elastic lattice strain measurements indicate that the stress in the newly formed twins (daughters) is relaxed relative to the stress field in the surrounding matrix. However, since the daughters are in a plastically “hard” deformation orientation, they quickly accumulate elastic strain as surrounding grains deform plastically. Polycrystal modeling of the deformation process provides insight about the crystallographic deformation mechanism involved.

Microstructural Design of Silicon Nitride with Improved Fracture Toughness: I, Effects of Grain Shape and Size

Abstract: The use of self-reinforcement by larger elongated grains in silicon nitride ceramics requires judicious control of the microstructure to achieve high steady-state toughness and high fracture strength. With a distinct bimodal distribution of grain diameters, such as that achieved by the addition of 2% rodlike seeds, the fracture resistance rapidly rises with crack extension to steady-state values of up to 10 MPa{center_dot}m{sup 1/2} and is accompanied by fracture strengths in excess of 1 GPa. When the generation of elongated reinforcing grains is not regulated, a broad grain diameter distribution is typically generated. While some toughening is achieved, both the plateau (steady-state) toughness and the R-curve response suffer, and the fracture strength undergoes a substantial reduction. Unreinforced equiaxed silicon nitride exhibits the least R-curve response with a steady-state toughness of only 3.5 MPa{center_dot}m{sup 1/2} coupled with a reduced fracture strength.

Simple synthesis of MgFe2O4 nanoparticles as gas sensing materials

Abstract: n-Type semi-conductive nanometer material MgFe2O4 was synthesized by solid-state reaction of inorganic reagents MgSO4, Fe(NO3)3·9H2O, and NaOH. The process was a convenient, environment friendly, inexpensive and efficient preparation method for MgFe2O4 nanomaterial. X-ray diffraction (XRD) was used to confirm the material structure and transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM) to depict the crystallite microstructure. Conductance responses of the nanocrystalline MgFe2O4 thick film were measured by exposing the film to reducing gases like methane (CH4), hydrogen sulfide (H2S), liquefied petroleum gas (LPG) and ethanol gas (C2H5OH). It was found that the sensor exhibited various sensing responses to these gases at different operating temperature. Furthermore, the sensor exhibited a fast response and a good recovery. Successive on and off responses could be repeated without observing major changes in the response signal.

Microstructure of fire-damaged concrete. A case study

Abstract: Concrete is a poor conductor of heat, but can suffer considerable damage when exposed to fire. Unraveling the heating history of concrete is important to forensic research or to determine whether a fire-exposed concrete structure and its components are still structurally sound. Assessment of fire-damage concrete structures usually starts with visual observation of color change, cracking and spalling. On heating, a change in color from normal to pink is often observed and this is useful since it coincides with the onset of significant loss of concrete strength. This paper presents results of cores strength, as well as, optical microscopy investigations of fire-damaged concrete. Samples were taken from concrete that had been exposed to fire. Optical microscopy has focused on microstructure of cement paste, aggregates, microvoids and cracks, as well as, on quantification the crack patterns found in heated concrete samples. The physical condition of concrete sample in combination with the microscopic examination, enable a petrographer to make a reasonable estimation of the minimum exposure temperature and its relative impact to the depth of damage in concrete.

Grain refinement and superplastic flow in an aluminum alloy processed by high-pressure torsion

Abstract: Disks of an Al–3% Mg–0.2% Sc alloy were processed by high-pressure torsion (HPT) to refine the grain size to ∼0.15 μm. Inspection of the disks after processing revealed a central core region having a relatively coarse and ill-defined microstructure. The size of this core region decreased with increasing numbers of turns in HPT. Measurements showed the hardness increased with increasing applied pressure and/or increasing numbers of turns. In addition, the hardness increased with increasing distance from the center of the disk and stabilized at distances greater than ∼2–3 mm. The values of the saturation hardness in the outer regions of the disks were similar at higher applied pressures and after larger numbers of turns. This saturation hardness was ∼3× the hardness in the solution-treated condition. Within the region of hardness saturation, the microstructure was reasonably homogeneous and consisted of ultrafine grains separated by high-angle grain boundaries. Tensile testing demonstrated the occurrence of high strain rate superplasticity after HPT with elongations to failure that were similar to those obtained in samples of the same alloy processed by equal-channel angular pressing (ECAP).

A lead-free high-Curie-point ferroelectric ceramic, CaBi2Nb2O9

Abstract: Nano-powders of BaTiO3, SrTiO3, Ba0.6Sr0.4TiO3, a mixture of the composition (BaTiO3)0.6(SrTiO3)0.4 with particle sizes in the range of 60 to 80 nm, and Bi4Ti3O12 with an average particle size of 100 nm were consolidated by spark plasma sintering (SPS). The kinetics of reaction, densification and grain growth were studied. An experimental procedure is outlined that allows the determination of a “kinetic window” within which dense nano-sized compacts can be prepared. It is shown that the sintering behaviour of the five powders varies somewhat, but is generally speaking fairly similar. However, the types of grain growth behaviour of these powders are quite different, exemplified by the observation that the kinetic window for the (BaTiO3)0.6(SrTiO3)0.4 mixture is 125 oC, ~75 oC for Bi4Ti3O12, ~25oC for BaTiO3 and SrTiO3, while it is hard to observe an apparent kinetic window for obtaining nano-sized compacts of Ba0.6Sr0.4TiO3. During the densification of the (BaTiO3)0.6(SrTiO3)0.4 mixture the reaction 0.6BaTiO3+0.4SrTiO3 → Ba0.6Sr0.4TiO3 takes place, and this reaction is suggested to have a self-pinning effect on the grain growth, which in turn explains why this powder has a large kinetic window. Notably, SPS offers a unique opportunity to more preciously investigate and monitor the sintering kinetics of nano-powders, and it allows preparation of ceramics with tailored microstructures.The dielectric properties of selected samples of (Ba, Sr)TiO3 ceramics have been studied. The results are correlated with the microstructural features of these samples, e.g. to the grain sizes present in the compacts. The ceramic with nano-sized microstructure exhibits a diffuse transition in permittivity and reduced dielectric losses in the vicinity of the Curie temperature, whereas the more coarse-grained compacts exhibit normal dielectric properties in the ferroelectric region.The morphology evolution, with increasing sintering temperature, of bismuth layer-structured ferroelectric ceramics such as Bi4Ti3O12 (BIT) and CaBi2Nb2O9 (CBNO) was investigated. The subsequent isothermal sintering experiments revealed that the nano-sized particles of the BIT precursor powder grew into elongated plate-like grains within a few minutes, via a dynamic ripening mechanism.A new processing strategy for obtaining highly textured ceramics is described. It is based on a directional dynamic ripening mechanism induced by superplastic deformation. The new strategy makes it possible to produce a textured microstructure within minutes, and it allows production of textured ferroelectric ceramics with tailored morphology and improved physical properties.The ferroelectric, dielectric, and piezoelectric properties of the textured bismuth layer-structured ferroelectric ceramics have been studied, and it was revealed that all textured samples exhibited anisotropic properties and improved performance. The highly textured Bi4Ti3O12 ceramic exhibited ferroelectric properties equal to or better than those of corresponding single crystals, and much better than those previously reported for grain-orientated Bi4Ti3O12 ceramics. Textured CaBi2Nb2O9 ceramics exhibited a very high Curie temperature, d33-values nearly three times larger than those of conventionally sintered materials, and a high thermal depoling temperature indicating that it is a very promising material for high-temperature piezoelectric applications.

Microstructure of Fragile Metallic Glasses Inferred from Ultrasound-Accelerated Crystallization in Pd-Based Metallic Glasses

Abstract: By utilizing ultrasonic annealing at a temperature below (or near) the glass transition temperature Tg, we revealed a microstructural pattern of a partially crystallized Pd-based metallic glass with a high-resolution electron microscopy. On the basis of the observed microstructure, we inferred a plausible microstructural model of fragile metallic glasses composed of strongly bonded regions surrounded by weakly bonded regions (WBRs). The crystallization in WBRs at such a low temperature under the ultrasonic vibrations is caused by accumulation of atomic jumps associated with the beta relaxation being resonant with the ultrasonic strains. This microstructural model successfully illustrates a marked increase of elasticity after crystallization with a small density change and a correlation between the fragility of the liquid and the Poisson ratio of the solid.

An Analysis of the Relationship between Grain Size, Solute Content, and the Potency and Number Density of Nucleant Particles

Abstract: To be able to determine the grain size obtained from the addition of a grain refining master alloy, the relationship between grain size (d), solute content (defined by the growth restriction factor Q), and the potency and number density of nucleant particles needs to be understood. A study was undertaken on aluminium alloys where additions of TiB2 and Ti were made to eight wrought aluminum alloys covering a range of alloying elements and compositions. It was found from analysis of the data that $$d = \frac{a}{{\sqrt[3]{{pct TiB_2 }}}} + \frac{b}{Q}$$ . From consideration of the experimental data and from further analysis of previously published data, it is shown that the coefficients a and b relate to characteristics of the nucleant particles added by a grain refiner. The term a is related to the maximum density of active TiB2 nucleant particles within the melt, while b is related to their potency. By using the analysis methodology presented in this article, the performance characteristics of different master alloys were defined and the effects of Zr and Si on the poisoning of grain refinement were illustrated.

Microstructure and mechanical behavior of porous sintered steels

Abstract: The microstructure and mechanical properties of sintered Fe–0.85Mo–Ni steels were investigated as a function of sintered density. A quantitative analysis of microstructure was correlated with tensile and fatigue behavior to understand the influence of pore size, shape, and distribution on mechanical behavior. Tensile strength, Young's modulus, strain-to-failure, and fatigue strength all increased with a decrease in porosity. The decrease in Young's modulus with increasing porosity was predicted by analytical modeling. Two-dimensional microstructure-based finite element modeling showed that the enhanced tensile and fatigue behavior of the denser steels could be attributed to smaller, more homogeneous, and more spherical porosity which resulted in more homogeneous deformation and decreased strain localization in the material. The implications of pore size, morphology, and distribution on the mechanical behavior and fracture of P/M steels are discussed.

Thermo-physical properties of plasma electrolytic oxide coatings on aluminium

Abstract: Plasma electrolytic oxide coatings appear to offer attractive combinations of hardness, wear resistance, corrosion resistance and interfacial adhesion. In order to optimise such characteristics, however, more basic thermo-physical property data are required, together with an understanding of how they are affected by processing conditions and microstructure. In the present study, coatings were produced on 6082 aluminium and characterised using profilometry, scanning electron microscopy, X-ray diffraction and nanoindentation. The in-plane thermal expansivity of detached coatings was measured by dilatometry to be about 8 microstrain K −1 . There is thus a rather substantial mismatch between the expansivities of coating and substrate, amounting to about 15 microstrain K −1 . The global in-plane Young's modulus was estimated using cantilever bending of sandwich coated substrates and also by measuring the curvature generated in a bi-material beam on cooling to low temperature. It was found to lie in the approximate range of 10–40 GPa. Values of this order, which are low compared with the figure of around 370 GPa expected for fully dense polycrystalline alumina, are thought to be associated with the presence of a network of microcracks and voids. A low value is expected to be beneficial in terms of conferring good strain tolerance, and hence resistance to spallation driven by differential thermal expansion.

Texture Development by Templated Grain Growth in Liquid-Phase-Sintered α-Alumina

Abstract: The distribution and orientation of platelet-shaped particles of α-alumina in a fine-grained alumina matrix is shown to template texture development via anisotropic grain growth. The textured microstructure ranges from 4 wt% oriented platelet particles in calcined samples to nearly 100% oriented α-Al2O3 grains after sintering at 1400°C. A CaO + SiO2 liquid phase creates favorable thermodynamic and kinetic conditions for anisotropic grain growth and grain reorientation during sintering. Important criteria for templated grain growth include (1) anisotropic crystal structure and growth, (2) high thermodynamic driving force for template grain growth, and (3) modification of diffusion in the system to continuously provide material to the anisotropically growing template grains.