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Showing papers on "Nanoelectronics published in 2020"


Journal ArticleDOI
TL;DR: This review provides a comprehensive analysis of the controlled synthesis, surface assembly, characterization techniques, and potential applications of horizontally aligned SWNT arrays.
Abstract: Single-walled carbon nanotubes (SWNTs) emerge as a promising material to advance carbon nanoelectronics. However, synthesizing or assembling pure metallic/semiconducting SWNTs required for interconnects/integrated circuits, respectively, by a conventional chemical vapor deposition method or by an assembly technique remains challenging. Recent studies have shown significant scientific breakthroughs in controlled SWNT synthesis/assembly and applications in scaled field effect transistors, which are a critical component in functional nanodevices, thereby rendering the horizontal SWNT array an important candidate for innovating nanotechnology. This review provides a comprehensive analysis of the controlled synthesis, surface assembly, characterization techniques, and potential applications of horizontally aligned SWNT arrays. This review begins with the discussion of synthesis of horizontally aligned SWNTs with regulated direction, density, structure, and theoretical models applied to understand the growth results. Several traditional procedures applied for assembling SWNTs on target surface are also briefly discussed. It then discusses the techniques adopted to characterize SWNTs, ranging from electron/probe microscopy to various optical spectroscopy methods. Prototype applications based on the horizontally aligned SWNTs, such as interconnects, field effect transistors, integrated circuits, and even computers, are subsequently described. Finally, this review concludes with challenges and a brief outlook of the future development in this research field.

63 citations


Journal ArticleDOI
15 Oct 2020-Carbon
TL;DR: In this article, the thermal stability, mechanical, electronic and optical properties of carbon-nitride nanosheets were investigated and extensive density functional theory simulations were conducted to explore thermal stability and mechanical properties.

62 citations


Journal ArticleDOI
TL;DR: Local electrostatic gating devices made from this two-dimensional material platform enable highly tunable Josephson junctions, edge tunnelling spectroscopy and single-electron transistor operation.
Abstract: Magic-angle twisted bilayer graphene (MATBG) has recently emerged as a highly tunable two-dimensional (2D) material platform exhibiting a wide range of phases, such as metal, insulator, and superconductor states. Local electrostatic control over these phases may enable the creation of versatile quantum devices that were previously not achievable in other single material platforms. Here, we exploit the electrical tunability of MATBG to engineer Josephson junctions and tunneling transistors all within one material, defined solely by electrostatic gates. Our multi-gated device geometry offers complete control over the Josephson junction, with the ability to independently tune the weak link, barriers, and tunneling electrodes. We show that these purely 2D MATBG Josephson junctions exhibit nonlocal electrodynamics in a magnetic field, in agreement with the Pearl theory for ultrathin superconductors. Utilizing the intrinsic bandgaps of MATBG, we also demonstrate monolithic edge tunneling spectroscopy within the same MATBG devices and measure the energy spectrum of MATBG in the superconducting phase. Furthermore, by inducing a double barrier geometry, the devices can be operated as a single-electron transistor, exhibiting Coulomb blockade. These MATBG tunneling devices, with versatile functionality encompassed within a single material, may find applications in graphene-based tunable superconducting qubits, on-chip superconducting circuits, and electromagnetic sensing in next-generation quantum nanoelectronics.

62 citations


Journal ArticleDOI
TL;DR: S sulfide niobium (NbS3), a novel transition metal trichalcogenide semiconductor with low-symmetry structure, is introduced into a narrowband 2D material with strong anisotropic physical properties both experimentally and theoretically.
Abstract: Low-symmetry 2D materials with unique anisotropic optical and optoelectronic characteristics have attracted a lot of interest in fundamental research and manufacturing of novel optoelectronic devices. Exploring new and low-symmetry narrow-bandgap 2D materials will be rewarding for the development of nanoelectronics and nano-optoelectronics. Herein, sulfide niobium (NbS3 ), a novel transition metal trichalcogenide semiconductor with low-symmetry structure, is introduced into a narrowband 2D material with strong anisotropic physical properties both experimentally and theoretically. The indirect bandgap of NbS3 with highly anisotropic band structures slowly decreases from 0.42 eV (monolayer) to 0.26 eV (bulk). Moreover, NbS3 Schottky photodetectors have excellent photoelectric performance, which enables fast photoresponse (11.6 µs), low specific noise current (4.6 × 10-25 A2 Hz-1 ), photoelectrical dichroic ratio (1.84) and high-quality reflective polarization imaging (637 nm and 830 nm). A room-temperature specific detectivity exceeding 107 Jones can be obtained at the wavelength of 3 µm. These excellent unique characteristics will make low-symmetry narrow-bandgap 2D materials become highly competitive candidates for future anisotropic optical investigations and mid-infrared optoelectronic applications.

59 citations



Journal ArticleDOI
TL;DR: A quantum tomography protocol is developed and demonstrated which extracts the generated electron and hole wavefunctions and their emission probabilities from any electrical current and combines two-particle interferometry with signal processing.
Abstract: In quantum nanoelectronics, time-dependent electrical currents are built from few elementary excitations emitted with well-defined wavefunctions. However, despite the realization of sources generating quantized numbers of excitations, and despite the development of the theoretical framework of time-dependent quantum electronics, extracting electron and hole wavefunctions from electrical currents has so far remained out of reach, both at the theoretical and experimental levels. In this work, we demonstrate a quantum tomography protocol which extracts the generated electron and hole wavefunctions and their emission probabilities from any electrical current. It combines two-particle interferometry with signal processing. Using our technique, we extract the wavefunctions generated by trains of Lorentzian pulses carrying one or two electrons. By demonstrating the synthesis and complete characterization of electronic wavefunctions in conductors, this work offers perspectives for quantum information processing with electrical currents and for investigating basic quantum physics in many-body systems.

32 citations


Journal ArticleDOI
TL;DR: In this paper, the authors proposed a simple improvement technique based on the use of high n-type doping concentration at the level of carbon nanotube underneath the gate while keeping the junctionless paradigm that facilitates tremendously the fabrication processes of ultrascaled FETs.
Abstract: Carbon nanotube field-effect transistors (CNTFETs) and their growing applications are becoming part of modern nanoelectronics, which is in urgent need for high-performance ultrascaled transistors. Sub-10-nm junctionless ballistic carbon nanotube field-effect transistors (JL-CNTFET) with substantial improved performance are computationally proposed herein. The non-equilibrium Green's function (NEGF) simulation is used for the computational assessment. The proposed simple improvement technique is based on the use of high n-type doping concentration at the level of carbon nanotube underneath the gate while keeping the junctionless paradigm that facilitates tremendously the fabrication processes of ultrascaled FETs. It has been found that the proposed doping profile can significantly mitigate several ultrascaling effects while boosting the performance of sub-10-nm JL-CNTFETs. The recorded enhancements include the leakage current, current ratio, subthreshold swing, switching speed, switching energy, drain-induced barrier lowering, and threshold voltage roll-off. The significant improvements obtained in this work for sub-10-nm JL-CNTFETs, make the proposed strategy, which is simple, feasible, and efficient, as a promising technique for improving ultrascaled FETs endowed with other gate geometries and channel nanomaterials while paving the way towards high-performance sub-5-nm FETs.

30 citations


Journal ArticleDOI
18 May 2020
TL;DR: In this article, the authors analyze the increase of the electronic bandgap due to quantum confinement and compare the relative stability of various t-Te nanostructures (t-Te wires and layers of tTe) using first-principles simulations.
Abstract: Trigonal-Tellurium (t-Te) has recently garnered interest in the nanoelectronics community because of its measured high hole mobility and low-temperature growth. However, a drawback of tellurium is its small bulk bandgap (0.33 eV), giving rise to large leakage currents in transistor prototypes. We analyze the increase of the electronic bandgap due to quantum confinement and compare the relative stability of various t-Te nanostructures (t-Te nanowires and layers of t-Te) using first-principles simulations. We found that small t-Te nanowires (≤4 nm2) and few-layer t-Te (≤3 layers) have bandgaps exceeding 1 eV, making Tellurium a very suitable channel material for extremely scaled transistors, a regime where comparably sized silicon has a bandgap that exceeds 4 eV. Through investigations of structural stability, we found that t-Te nanowires preferentially form instead of layers of t-Te since nanowires have a greater number of van der Waals (vdW) interactions between the t-Te-helices. We develop a simplified picture of structural stability relying only on the number of vdW interactions, enabling the prediction of the formation energy of any t-Te nanostructure. Our analysis shows that t-Te has distinct advantages over silicon in extremely scaled nanowire transistors in terms of bandgap and the t-Te vdW bonds form a natural nanowire termination, avoiding issues with passivation.

28 citations


Journal ArticleDOI
TL;DR: In this article, the electronic properties of GaTe/CdS heterostructure using first-principles calculations based on density functional theory (DFT) were investigated, and a direct band gap of 0.804 eV and type-II band alignment were formed at the GaTe and CdS van der Waals heterobilayer interface, which is beneficial to the spatial effective separation of photogenerated electron-hole pairs.

27 citations


Journal ArticleDOI
TL;DR: The solar to electrical power conversion efficiency predicted in this work surpasses the efficiencies reported for InSe based heterostructures, thereby demonstrating its superiority in solar energy harvesting and nanoelectronics.
Abstract: Semiconducting indium selenide (InSe) monolayers have drawn a great deal of attention among all the chalcogenide two-dimensional materials on account of their high electron mobility; however, they suffer from low hole mobility. This inherent limitation of an InSe monolayer can be overcome by stacking it on top of a boron phosphide (BP) monolayer, where the complementary properties of BP can bring additional benefits. The electronic, optical, and external perturbation-dependent electronic properties of InSe/BP hetero-bilayers have been systematically investigated within density functional theory in anticipation of its cutting-edge applications. The InSe/BP heterostructure has been found to be an indirect semiconductor with an intrinsic type-II band alignment where the conduction band minimum (CBM) and valence band maximum (VBM) are contributed by the InSe and BP monolayers, respectively. Thus, the charge carrier mobility in the heterostructure, which is mainly derived from the BP monolayer, reaches as high as 12 × 103 cm2 V-1 s-1, which is very much desired in superfast nanoelectronics. The suitable bandgap accompanied by a very low conduction band offset between the donor and acceptor along with robust charge carrier mobility, and the mechanical and dynamical stability of the heterostructure attests its high potential for applications in solar energy harvesting and nanoelectronics. The solar to electrical power conversion efficiency (20.6%) predicted in this work surpasses the efficiencies reported for InSe based heterostructures, thereby demonstrating its superiority in solar energy harvesting. Moreover, the heterostructure transits from the semiconducting state (the OFF state) to the metallic state (the ON state) by the application of a small electric field (∼0.15 V A-1) which is brought about by the actual movement of the bands rather than via the nearly empty free electron gas (NFEG) feature. This thereby testifies to its potential for applications in digital data storage. Moreover, the heterostructure shows strong absorbance over a wide spectrum ranging from UV to the visible light of solar radiation, which will be of great utility in UV-visible light photodetectors.

27 citations


Journal ArticleDOI
TL;DR: The most widely applied characterization techniques to explore the unique electronic properties of DNA molecules and their amenability with various types of nanomaterials at the nanoscale are described and discussed, including scanning tunneling microscopy, conductive atomic force microscopeopy, and Kelvin probe force microscopy.
Abstract: The bottom-up DNA-templated nanoelectronics exploits the unparalleled self-assembly properties of DNA molecules and their amenability with various types of nanomaterials. In principle, nanoelectronic devices can be bottom-up assembled with near-atomic precision, which compares favorably with well-established top-down fabrication process with nanometer precision. Over the past decade, intensive effort has been made to develop DNA-based nanoassemblies including DNA-metal, DNA-polymer, and DNA-carbon nanotube complexes. This review introduces the history of DNA-based fabrication for nanoelectronics briefly and summarizes the state-of-art advances of DNA-based nanoelectronics. In particular, the most widely applied characterization techniques to explore their unique electronic properties at the nanoscale are described and discussed, including scanning tunneling microscopy, conductive atomic force microscopy, and Kelvin probe force microscopy. We also provide a perspective on potential applications of DNA-based nanoelectronics.

Journal ArticleDOI
TL;DR: This tutorial review considers how the fundamental quantized properties associated with charge transport and storage are linked in a manner that spans nanoscale electronics, electrochemistry, redox switching, and derived nanoscales sensing.
Abstract: This tutorial review considers how the fundamental quantized properties associated with charge transport and storage, particularly in molecular films, are linked in a manner that spans nanoscale electronics, electrochemistry, redox switching, and derived nanoscale sensing. Through this analysis, and by considering the basic principles of chemical reactivity, we show that 'dry' electronic and 'wet' electrochemical characteristics align within a generalized theoretical capacitative framework that connects charge conductance and electron transfer rate. Finally, we discuss the application of these joint theoretical concepts to key developments in nanosensors.

Journal ArticleDOI
TL;DR: In this paper, a gate-all-around (GAA) p-n carbon nanotube TFET (CNT-TFET) is proposed and compared with its conventional counterpart.
Abstract: In this article, a new gate-all-around (GAA) p-n carbon nanotube TFET (CNT-TFET) is proposed and compared with its conventional counterpart. The nonequilibrium Green’s function (NEGF) formalism is used to perform the quantum simulations, where the ballistic transport is assumed. The quantum simulation study includes the transfer characteristics, subthreshold slope, ON–OFF current ratio, switching speed, and power–delay product. The simulations show that the proposed CNT-TFET that has a single junction exhibits better aforementioned figures of merit than the conventional p-i-n device. In addition, the p-n CNT-TFET shows higher current ratio and steeper subthreshold swing than those provided by the conventional design with the gate length downscaling. The obtained results make the proposed nanoscale TFET as a promising device for the future nanoelectronics.

Journal ArticleDOI
26 May 2020-ACS Nano
TL;DR: This work indicates that carbon nanotube has the potential for future integration between nanophotonics and nanoelectronics on a single chip.
Abstract: Monolithic optoelectronic integration based on a single material is a major pursuit in the fields of nanophotonics and nanoelectronics in order to meet the requirements of future fiber-optic telecommunication systems and on-chip optical interconnection systems. However, the incompatibility between silicon-based electronics and germanium or compound semiconductor-based photonics makes it very challenging to realize optoelectronic integration based on a single material. Here, the integration between silicon waveguides and a carbon nanotube (CNT) optoelectronic system is demonstrated. Waveguide-integrated photodetectors based on the CNT exhibit 12.5 mA/W photoresponsivity at 1530 nm, which presents an improvement of 97.6 times enhanced absorption efficiency compared to that without the waveguide. Multiplied output signals of cascading photodetectors are used to control the output of CNT-based logic gates, thereby demonstrating that the CNT-based optoelectronic integration system is compatible with silicon photonics. Our work indicates that carbon nanotubes have the potential for future integration between nanophotonics and nanoelectronics on a single chip.

Journal ArticleDOI
TL;DR: Pushing the low temperature limit of refrigerators beyond milli-kelvin regime holds the promise for new discoveries in the nano-electronic devices.
Abstract: Fragile quantum effects such as single electron charging in quantum dots or macroscopic coherent tunneling in superconducting junctions are the basis of modern quantum technologies. These phenomena can only be observed in devices where the characteristic spacing between energy levels exceeds the thermal energy, kBT, demanding effective refrigeration techniques for nanoscale electronic devices. Commercially available dilution refrigerators have enabled typical electron temperatures in the 10 to 100 mK regime, however indirect cooling of nanodevices becomes inefficient due to stray radiofrequency heating and weak thermal coupling of electrons to the device substrate. Here, we report on passing the millikelvin barrier for a nanoelectronic device. Using a combination of on-chip and off-chip nuclear refrigeration, we reach an ultimate electron temperature of Te = 421 ± 35 μK and a hold time exceeding 85 h below 700 μK measured by a self-calibrated Coulomb-blockade thermometer.

Journal ArticleDOI
07 Jan 2020-ACS Nano
TL;DR: A dopant-free method for controlling polarity ofMoTe2 FETs by modifying Schottky barriers at their MoTe2-metal contacts, via thermal annealing is reported, suggesting this simple and effectual approach may lead to compelling possibilities of rationally controlling transport polarity, on demand, in atomically thin transistors with metal contacts, and their 2D integrated circuits.
Abstract: Two-dimensional (2D) layered molybdenum ditelluride (MoTe2) crystals, featuring a low energy barrier in the crystalline phase transition and a sizable band gap close to that of silicon, are rapidly emerging with substantial potential and promise for future nanoelectronics. It has been challenging, however, to realize n-type MoTe2 field-effect transistors (FETs), thus complementary logic, because MoTe2 FETs mainly exhibit p-type behavior. Here, we report a dopant-free method for controlling polarity of MoTe2 FETs by modifying Schottky barriers at their MoTe2-metal contacts via thermal annealing. Upon annealing, MoTe2 FETs encapsulated by hexagonal boron nitride (h-BN) are consistently changed from hole to electron conduction, displaying an on/off current ratio of 105 or higher. When the MoTe2 channel is sandwiched between top and bottom h-BN thin layers (h-BN/MoTe2/h-BN FETs), higher field-effect mobility is attained, up to 48.1 cm2 V-1 s-1 (hole) and 52.4 cm2 V-1 s-1 (electron) before and after thermal annealing, respectively. The thermally controlled FET polarity change further enables high-performance MoTe2 monolithic complementary inverters with gain as high as 36, suggesting this simple and effectual approach may lead to compelling possibilities of rationally controlling transport polarity, on demand, in atomically thin transistors with metal contacts and their 2D integrated circuits.

Journal ArticleDOI
TL;DR: The proposed design has fewer QCA cells and lower latency and area and uses the coplanar crossover method to overcome the complexity of multilayer quantum wire crossing.
Abstract: Quantum dot cellular automata (QCA) constitute an emergent nanoscale-based digital nanoelectronics technology with comprehensive applications in nanocomputing based on the small nanometer size of such circuits and their ultralow power consumption, fast operation, and high clock frequency in comparison with transistor-based complementary metal–oxide–semiconductor (CMOS) technologies. A novel design for edge-triggered synchronous J-K flip-flop (FF) and D (data or delay) flip-flop memory elements based on QCA cells with quantum wires is presented herein. The proposed design has fewer QCA cells and lower latency and area and uses the coplanar crossover method to overcome the complexity of multilayer quantum wire crossing. The design is analyzed to determine the average output polarization (AOP) of the edge-triggered synchronous D-FF and JK-FF at different temperature levels and the optimized energy dissipation. The layout design and computational simulation of the circuit are carried out using QCADesigner V. 2.0.3 software, while the energy dissipation is analyzed using the QCADesigner-E V. 2.2 tool.

Journal ArticleDOI
TL;DR: In this paper, the authors evaluate the properties of hexagonal boron nitride (hBN) and conclude that while its properties render hBN an ideal candidate for many applications in 2D nanoelectronics, hBN is most likely not suitable as a gate insulator for ultrascaled CMOS devices.
Abstract: Complementary metal oxide semiconductor (CMOS) logic circuits at the ultimate scaling limit place the utmost demands on the properties of all materials involved. The requirements for semiconductors are well explored and could possibly be satisfied by a number of layered two-dimensional (2D) materials, like for example transition-metal dichalcogenides or black phosphorus. The requirements for the gate insulator are arguably even more challenging and difficult to meet. In particular the combination of insulator to semiconductor which forms the central element of the metal oxide semiconductor field effect transistor (MOSFET) has to be of superior quality in order to build competitive devices. At the moment, hexagonal boron nitride (hBN) is the most common two-dimensional insulator and widely considered to be the most promising gate insulator in nanoscaled 2D material-based transistors. Here, we critically assess the material parameters of hBN and conclude that while its properties render hBN an ideal candidate for many applications in 2D nanoelectronics, hBN is most likely not suitable as a gate insulator for ultrascaled CMOS devices.

Journal ArticleDOI
23 Oct 2020
TL;DR: A facile synthesis method for Al-doped MoS2 via plasma-enhanced atomic layer deposition (ALD) is presented, resulting in a particularly sought-after p-type 2D material, and fine control over the doping concentration should ensure compatibility with large-scale fabrication.
Abstract: Extrinsically doped two-dimensional (2D) semiconductors are essential for the fabrication of high-performance nanoelectronics among many other applications. Herein, we present a facile synthesis method for Al-doped MoS2 via plasma-enhanced atomic layer deposition (ALD), resulting in a particularly sought-after p-type 2D material. Precise and accurate control over the carrier concentration was achieved over a wide range (1017 up to 1021 cm-3) while retaining good crystallinity, mobility, and stoichiometry. This ALD-based approach also affords excellent control over the doping profile, as demonstrated by a combined transmission electron microscopy and energy-dispersive X-ray spectroscopy study. Sharp transitions in the Al concentration were realized and both doped and undoped materials had the characteristic 2D-layered nature. The fine control over the doping concentration, combined with the conformality and uniformity, and subnanometer thickness control inherent to ALD should ensure compatibility with large-scale fabrication. This makes Al:MoS2 ALD of interest not only for nanoelectronics but also for photovoltaics and transition-metal dichalcogenide-based catalysts.

Journal ArticleDOI
TL;DR: 2D monolayer hexagonal boron nitride is exploited as an ultrathin decorating layer to form a metal-insulator-semiconductor (MIS) contact, and an innovative device architecture is designed as a platform to reveal a novel diode-like selective enhancement of the carrier transport through the MIS contact.
Abstract: 2D semiconductors such as monolayer molybdenum disulfide (MoS2 ) are promising material candidates for next-generation nanoelectronics. However, there are fundamental challenges related to their metal-semiconductor (MS) contacts, which limit the performance potential for practical device applications. In this work, 2D monolayer hexagonal boron nitride (h-BN) is exploited as an ultrathin decorating layer to form a metal-insulator-semiconductor (MIS) contact, and an innovative device architecture is designed as a platform to reveal a novel diode-like selective enhancement of the carrier transport through the MIS contact. The contact resistance is significantly reduced when the electrons are transported from the semiconductor to the metal, but is barely affected when the electrons are transported oppositely. A concept of carrier collection barrier is proposed to interpret this intriguing phenomenon as well as a negative Schottky barrier height obtained from temperature-dependent measurements, and the critical role of the collection barrier at the drain end is shown for the overall transistor performance.

Journal ArticleDOI
23 Nov 2020
TL;DR: It is suggested that 2D In2Ge2Te6 samples should be highly stable and can be experimentally fabricated by mechanical exfoliation, and the application of van der Waals pressure as a promising strategy to tune the electronic and stacking property of 2D crystals is demonstrated.
Abstract: Ultrathin semiconductors with great electrical and photovoltaic performance hold tremendous promise for fundamental research and applications in next-generation electronic devices. Here, we report new 2D direct-bandgap semiconductors, namely mono- and few-layer In2Ge2Te6, with a range of desired properties from ab initio simulations. We suggest that 2D In2Ge2Te6 samples should be highly stable and can be experimentally fabricated by mechanical exfoliation. They are predicted to exhibit extraordinary optical absorption and high photovoltaic conversion efficiency (≥31.8%), comparable to the most efficient single-junction GaAs solar cell. We reveal that, thanks to the presence of van Hove singularities in the band structure, unusual quantum-phase transitions could be induced in monolayers via electrostatic doping. Furthermore, taking bilayer In2Ge2Te6 as a prototypical system, we demonstrate the application of van der Waals pressure as a promising strategy to tune the electronic and stacking property of 2D crystals. Our work creates exciting opportunities to explore various quantum phases and atomic stacking, as well as potential applications of 2D In2Ge2Te6 in future nanoelectronics.

Journal ArticleDOI
TL;DR: The study provides insight for the molecular de-sign of an sc-SWCNT solubilizer with a high (n,m)-chiral selectivity, which benefits many areas including semiconducting nanoelectronics, thermoelectric, bio and energy materials and devices using solubILizer-free very pure sc- SWCNTs.
Abstract: Single-walled carbon nanotubes (SWCNTs) have the potential to revolutionize nanoscale electronics and power sources; however, their low purity and high separation cost limit their use in practical applications. Here we present a supramolecular chemistry-based one-pot, less expensive, scalable, and highly efficient separation of a solubilizer/adsorbent-free pure semiconducting SWCNT (sc-SWCNT) using flavin/isoalloxazine analogues with different substituents. On the basis of both experimental and computational simulations (DFT study), we have revealed the molecular requirements of the solubilizers as well as provided a possible mechanism for such a highly efficient selective sc-SWCNT separation. The present sorting method is very simple (one-pot) and gives a promising sc-SWCNT separation methodology. Thus, the study provides insight for the molecular design of an sc-SWCNT solubilizer with a high (n,m)-chiral selectivity, which benefits many areas including semiconducting nanoelectronics, thermoelectric, bio and energy materials, and devices using solubilizer-free very pure sc-SWCNTs.

Journal ArticleDOI
01 Jun 2020-Small
TL;DR: It is suggested that an electric-field-induced MIT can be triggered in these strongly correlated systems upon generation of oxygen vacancies and established that lower operational voltages and larger resistance ratios are obtained in those films where the MIT lies closer to room temperature.
Abstract: Strongly correlated perovskite oxides are a class of materials with fascinating intrinsic physical functionalities due to the interplay of charge, spin, orbital ordering, and lattice degrees of freedom. Among the exotic phenomena arising from such an interplay, metal-insulator transitions (MITs) are fundamentally still not fully understood and are of large interest for novel nanoelectronics applications, such as resistive switching-based memories and neuromorphic computing devices. In particular, rare-earth nickelates and lanthanum strontium manganites are archetypical examples of bandwidth-controlled and band-filling-controlled MIT, respectively, which are used in this work as a playground to correlate the switching characteristics of the oxides and their MIT properties by means of local probe techniques in a systematic manner. These findings suggest that an electric-field-induced MIT can be triggered in these strongly correlated systems upon generation of oxygen vacancies and establish that lower operational voltages and larger resistance ratios are obtained in those films where the MIT lies closer to room temperature. This work demonstrates the potential of using MITs in the next generation of nanoelectronics devices.

Journal ArticleDOI
TL;DR: An expanded framework for high-yield synthesis of the 1D tellurides including WTe, an previously unknown family of TMMs is reported, revealing that the choice of suitable metal oxides as a precursor provides a useful yield for their characterization.
Abstract: Atomically thin one-dimensional (1D) van der Waals wires of transition metal monochalocogenides (TMMs) have been anticipated as promising building blocks for integrated nanoelectronics. While reliable production of TMM nanowires has eluded scientists over the past few decades, we finally demonstrated a bottom-up fabrication of MoTe nanowires inside carbon nanotubes (CNTs). Still, the current synthesis method is based on vacuum annealing of reactive MoTe2, and limits access to a variety of TMMs. Here we report an expanded framework for high-yield synthesis of the 1D tellurides including WTe, an previously unknown family of TMMs. Experimental and theoretical analyses revealed that the choice of suitable metal oxides as a precursor provides a useful yield for their characterization. These TMM nanowires exhibit a significant optical absorption in the visible-light region. More important, electronic properties of CNTs can be tuned by encapsulating different TMM nanowires.

Journal ArticleDOI
TL;DR: The use of recoil implantation, a method exploiting momentum transfer from accelerated ions, for versatile and mask-free material doping, is demonstrated, suitable for applications such as electronic and magnetic doping of atomically-thin materials and engineering of near-surface states of semiconductor devices.
Abstract: Modifying material properties at the nanoscale is crucially important for devices in nanoelectronics, nanophotonics and quantum information. Optically active defects in wide band gap materials, for instance, are vital constituents for the realisation of quantum technologies. Yet, the introduction of atomic defects through direct ion implantation remains a fundamental challenge. Herein, we establish a universal method for material doping by exploiting one of the most fundamental principles of physics - momentum transfer. As a proof of concept, we direct-write arrays of emitters into diamond via momentum transfer from a Xe+ focused ion beam (FIB) to thin films of the group IV dopants pre-deposited onto a diamond surface. We conclusively show that the technique, which we term knock-on doping, can yield ultra-shallow dopant profiles localized to the top 5 nm of the target surface, and use it to achieve sub-50 nm lateral resolution. The knock-on doping method is cost-effective, yet very versatile, powerful and universally suitable for applications such as electronic and magnetic doping of atomically thin materials and engineering of near-surface states of semiconductor devices.

Journal ArticleDOI
TL;DR: This review examines the phenomena of transport and the interaction between electro-active charges and the material at the nanoscale and demonstrates how these mechanisms can be exploited to design and fabricate devices for applications in biomedicine and bioengineering.
Abstract: A long-standing goal of nanoelectronics is the development of integrated systems to be used in medicine as sensor, therapeutic, or theranostic devices. In this review, we examine the phenomena of transport and the interaction between electro-active charges and the material at the nanoscale. We then demonstrate how these mechanisms can be exploited to design and fabricate devices for applications in biomedicine and bioengineering. Specifically, we present and discuss electrochemical devices based on the interaction between ions and conductive polymers, such as organic electrochemical transistors (OFETs), electrolyte gated field-effect transistors (FETs), fin field-effect transistor (FinFETs), tunnelling field-effect transistors (TFETs), electrochemical lab-on-chips (LOCs). For these systems, we comment on their use in medicine.

Journal ArticleDOI
TL;DR: Carbon nanotube field effect transistors (CNFETs) exhibit great promise and extensions to silicon MOSFET due to their excellent electronic properties and extremely small size as discussed by the authors.
Abstract: Carbon nanotube field effect transistors (CNFETs) exhibit great promise and extensions to silicon MOSFET due to their excellent electronic properties and extremely small size. Implementable CNFET c...

Book ChapterDOI
01 Jan 2020
TL;DR: In this paper, the authors compared the physical properties of graphene and magnetoresistive phenomena in spintronics, and showed that it could be the long-awaited platform for spintronic applications.
Abstract: Because of its fascinating electronic properties, graphene is expected to produce breakthroughs in many areas of nanoelectronics. For spintronics, its key advantage is the expected long spin lifetime, combined with its large electron velocity. In this chapter, it is reviewed, and the results show that graphene could be the long-awaited platform for spintronics. A critical parameter for both characterization and devices is the resistance of the contact between the electrodes and the graphene, which must be large enough to prevent quenching of the induced spin polarization but small enough to allow for the detection of this polarization. Spin diffusion lengths in the 100-μm range, much longer than those in conventional metals and semiconductors, have been observed. This could be a unique advantage for several concepts of spintronic devices, particularly for the implementation of complex architectures or logic circuits in which information is coded by pure spin currents. The aim of this chapter is to provide possible hints to overcome the difficulties in graphene applications in the field of spintronics by comparing the physical properties of graphene and magnetoresistive phenomena in spintronics. This chapter will be useful for advanced physics, chemistry, and materials science in nanotechnology and the field of spintronics.

Journal ArticleDOI
TL;DR: Tkwant as discussed by the authors is a Python package for the simulation of quantum nanoelectronics devices to which external time-dependent perturbations are applied, which can handle the same types of systems: discrete tight-binding-like models that consist of an arbitrary central region connected to semi-infinite electrodes.
Abstract: Tkwant is a Python package for the simulation of quantum nanoelectronics devices to which external time-dependent perturbations are applied. Tkwant is an extension of the Kwant package (this https URL) and can handle the same types of systems: discrete tight-binding-like models that consist of an arbitrary central region connected to semi-infinite electrodes. The problem is genuinely many-body even in the absence of interactions and is treated within the non-equilibrium Keldysh formalism. Examples of Tkwant applications include the propagation of plasmons generated by voltage pulses, propagation of excitations in the quantum Hall regime, spectroscopy of Majorana fermions in semiconducting nanowires, current-induced skyrmion motion in spintronic devices, multiple Andreev reflection, Floquet topological insulators, thermoelectric effects, and more. The code has been designed to be easy to use and modular. Tkwant is free software distributed under a BSD license and can be found at this https URL.

Journal ArticleDOI
23 Jun 2020-Carbon
TL;DR: In this article, a van der Waals bonded graphene/C60 hybrid was constructed on a plastic substrate to demonstrate a highly sensitive flexible photodetector, which can effectively dissociate the electron-hole pairs and leads to significant photoresponse across ultraviolet to near-infrared (∼104 A/W @ 405