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Showing papers on "Nanofluid published in 2006"


Journal ArticleDOI
TL;DR: In this article, the authors considered seven slip mechanisms that can produce a relative velocity between the nanoparticles and the base fluid and concluded that only Brownian diffusion and thermophoresis are important slip mechanisms in nanofluids.
Abstract: Nanofluids are engineered colloids made of a base fluid and nanoparticles (1-100 nm) Nanofluids have higher thermal conductivity' and single-phase heat transfer coefficients than their base fluids In particular the heat transfer coefficient increases appear to go beyond the mere thermal-conductivity effect, and cannot be predicted by traditional pure-fluid correlations such as Dittus-Boelter's In the nanofluid literature this behavior is generally attributed to thermal dispersion and intensified turbulence, brought about by nanoparticle motion To test the validity of this assumption, we have considered seven slip mechanisms that can produce a relative velocity between the nanoparticles and the base fluid These are inertia, Brownian diffusion, thermophoresis, diffusioplwresis, Magnus effect, fluid drainage, and gravity We concluded that, of these seven, only Brownian diffusion and thermophoresis are important slip mechanisms in nanofluids Based on this finding, we developed a two-component four-equation nonhomogeneous equilibrium model for mass, momentum, and heat transport in nanofluids A nondimensional analysis of the equations suggests that energy transfer by nanoparticle dispersion is negligible, and thus cannot explain the abnormal heat transfer coefficient increases Furthermore, a comparison of the nanoparticle and turbulent eddy time and length scales clearly indicates that the nanoparticles move homogeneously with the fluid in the presence of turbulent eddies so an effect on turbulence intensity is also doubtful Thus, we propose an alternative explanation for the abnormal heat transfer coefficient increases: the nanofluid properties may vary significantly within the boundary layer because of the effect of the temperature gradient and thermophoresis For a heated fluid, these effects can result in a significant decrease of viscosity within the boundary layer, thus leading to heat transfer enhancement A correlation structure that captures these effects is proposed

5,329 citations


Journal ArticleDOI
TL;DR: In this paper, the authors studied the heat transfer behavior of aqueous suspensions of multi-walled carbon nanotubes (CNT nanofluids) flowing through a horizontal tube.

1,334 citations


Journal ArticleDOI
TL;DR: In this paper, the authors present an exhaustive review of the literature in this area and suggest a direction for future developments, including heat transfer, material science, physics, chemical engineering and synthetic chemistry.
Abstract: Suspended nanoparticles in conventional fluids, called nanofluids, have been the subject of intensive study worldwide since pioneering researchers recently discovered the anomalous thermal behavior of these fluids. The enhanced thermal conductivity of these fluids with small-particle concentration was surprising and could not be explained by existing theories. Micrometer-sized particle-fluid suspensions exhibit no such dramatic enhancement. This difference has led to studies of other modes of heat transfer and efforts to develop a comprehensive theory. This article presents an exhaustive review of these studies and suggests a direction for future developments. The review and suggestions could be useful because the literature in this area is spread over a wide range of disciplines, including heat transfer, material science, physics, chemical engineering and synthetic chemistry.

1,069 citations


Journal ArticleDOI
TL;DR: In this article, a comparison between experimental results obtained for nanofluid to homogeneous model in low concentration are close to each other but by increasing the volume fraction, higher heat transfer enhancement for Al 2 O 3 ǫ/ǫ water can be observed.

823 citations


Journal ArticleDOI
TL;DR: In this paper, the effects of variations in the temperature and volume fraction on the steady-state effective thermal conductivity of two different nanoparticle suspensions were examined and the results indicated that the nanoparticle material, diameter, volume fraction, and bulk temperature, all have a significant impact on the effective thermalconductivity of these suspensions.
Abstract: An experimental investigation was conducted to examine the effects of variations in the temperature and volume fraction on the steady-state effective thermal conductivity of two different nanoparticle suspensions. Copper and aluminum oxide, CuO and Al2O3, nanoparticles with area weighted diameters of 29 and 36nm, respectively, were blended with distilled water at 2%, 4%, 6%, and 10% volume fractions and the resulting suspensions were evaluated at temperatures ranging from 27.5to34.7°C. The results indicate that the nanoparticle material, diameter, volume fraction, and bulk temperature, all have a significant impact on the effective thermal conductivity of these suspensions. The 6% volume fraction of CuO nanoparticle/distilled water suspension resulted in an increase in the effective thermal conductivity of 1.52 times that of pure distilled water and the 10% Al2O3 nanoparticle/distilled water suspension increased the effective thermal conductivity by a factor of 1.3, at a temperature of 34°C. A two-factor ...

749 citations


Journal ArticleDOI
TL;DR: Experimental results on the viscosity of alumina-based nanofluids are reported for various shear rates, temperature, nanoparticle diameter, and nanoparticle volume fraction.
Abstract: Experimental results on the viscosity of alumina-based nanofluids are reported for various shear rates, temperature, nanoparticle diameter, and nanoparticle volume fraction. From the data it seems that the increase in the nanofluid viscosity is higher than the enhancement in the thermal conductivity as reported in the literature. It is shown, however, that the viscosity has to be increased by more than a factor of 4—relative to the increase in thermal conductivity—to make the nanofluid thermal performance worse than that of the base fluid.

735 citations


Journal ArticleDOI
TL;DR: The aggregation kinetics of nanoscale colloidal solutions are combined with the physics of thermal transport to capture the effects of aggregation on k and show that colloidal chemistry plays a significant role in deciding the k of colloidal nanosuspensions.
Abstract: The thermal conductivity, k, of nanoscale colloidal suspensions (also known as nanofluid), consisting of nanoparticles suspended in a base liquid, is much higher than the thermal conductivity of the base liquid at very small volume fractions of the nanoparticles. However, experimental results from various groups all across the world have shown various anomalies such as a peak in the enhancement of k with respect to nanoparticle size, an increase as well as a decrease in the ratio of k of these colloidal solutions with the k of the base fluid with increasing temperature, and a dependence of k on pH and time. In this paper, the aggregation kinetics of nanoscale colloidal solutions are combined with the physics of thermal transport to capture the effects of aggregation on k. Results show that the observed anomalies reported in experimental work can be well described by taking aggregation kinetics into account. Finally, we show that colloidal chemistry plays a significant role in deciding the k of colloidal nanosuspensions.

635 citations


Journal ArticleDOI
TL;DR: In this article, the authors show that the enhancement in the effective thermal conductivity of nanofluids is due mainly to localized convection caused by the Brownian movement of the nanoparticles.
Abstract: Here we show through an order-of-magnitude analysis that the enhancement in the effective thermal conductivity of nanofluids is due mainly to the localized convection caused by the Brownian movement of the nanoparticles. We also introduce a convective-conductive model which accurately captures the effects of particle size, choice of base liquid, thermal interfacial resistance between the particles and liquid, temperature, etc. This model is a combination of the Maxwell-Garnett (MG) conduction model and the convection caused by the Brownian movement of the nanoparficles, and reduces to the MG model for large particle sizes. The model is in good agreement with data on water, ethylene glycol, and oil-based nanofluids, and shows that the lighter the nanoparticles, the greater the convection effect in the liquid, regardless of the thermal conductivity of the nanoparticles.

512 citations


Journal ArticleDOI
TL;DR: It is observed that dye diffuses faster in nanofluids compared to that in water, with a peak enhancement at a nanoparticle volume fraction, phi, of 0.5% indicating that convection becomes less important at higher phi.
Abstract: Thermal conductivity enhancement in nanofluids, which are liquids containing suspended nanoparticles, has been attributed to localized convection arising from the nanoparticles' Brownian motion Because convection and mass transfer are similar processes, the objective here is to visualize dye diffusion in nanofluids It is observed that dye diffuses faster in nanofluids compared to that in water, with a peak enhancement at a nanoparticle volume fraction, phi, of 05% A possible change in the slope of thermal conductivity enhancement at that same phi signifies that convection becomes less important at higher phi The enhanced mass transfer in nanofluids can be utilized to improve diffusion in microfluidic devices

479 citations


Journal ArticleDOI
TL;DR: In this article, the cooling performance of a microchannel heat sink with nanoparticle-fluid suspensions (nanofluids) is numerically investigated by using a theoretical model of thermal conductivity of nanofluid that accounts for the fundamental role of Brownian motion.

431 citations


Journal ArticleDOI
TL;DR: In this article, a simple kinetic theory based analysis of heat flow in fluid suspensions of solid nanoparticles (nanofluids) was used to demonstrate that the hydrodynamics effects associated with Brownian motion have a minor effect on the thermal conductivity of the nanofluid.
Abstract: We use a simple kinetic theory based analysis of heat flow in fluid suspensions of solid nanoparticles (nanofluids) to demonstrate that the hydrodynamics effects associated with Brownian motion have a minor effect on the thermal conductivity of the nanofluid. Our conjecture is supported by the results of molecular dynamics simulations of heat flow in a model nanofluid with well-dispersed particles. Our findings are consistent with the predictions of the effective medium theory as well as with recent experimental results on well dispersed metal nanoparticle suspensions.

Journal ArticleDOI
TL;DR: In this article, the effect of the clustering of nanoparticles on the thermal conductivity of nanofluids was investigated and it was found from the variations of the nan-cluster size and thermal conductivities that the reduction of the thermalconductivity was directly related to the agglomeration of nanarticles.
Abstract: Nanofluids have been attractive for the last few years with the enormous potential to improve the efficiency of heat transfer fluids. This work focuses on the effect of the clustering of nanoparticles on the thermal conductivity of nanofluids. Large enhancement of the thermal conductivity is observed in Fe nanofluids sonicated with high powered pulses. The average size of the nanoclusters and thermal conductivity of sonicated nanofluids are measured as time passes after the sonication stopped. It is found from the variations of the nanocluster size and thermal conductivity that the reduction of the thermal conductivity of nanofluids is directly related to the agglomeration of nanoparticles. The thermal conductivity of Fe nanofluids increases nonlinearly as the volume fraction of nanoparticles increases. The nonlinearity is attributed to the rapid clustering of nanoparticles in condensed nanofluids. The thermal conductivities of Fe nanofluids with the three lowest concentrations are fitted to a linear function. The Fe nanofluids show a more rapid increase of the thermal conductivity than Cu nanofluids as the volume fraction of the nanoparticles increases.

Journal ArticleDOI
TL;DR: In this paper, the thermal conductivities of nanofluid containing a small amount of ultra-dispersed diamond (UDD), silver, and silica nanoparticles were measured using a transient hot-wire method.
Abstract: The thermal conductivities of nanofluid containing a small amount of ultra-dispersed diamond (UDD), silver, and silica nanoparticles were measured using a transient hot-wire method. To explain the enhancement of thermal conductivity of nanofluid, the effective volume of nanoparticles was used instead of the real volume to predict the thermal conductivity of nanofluid. The liquid layering on the surface of nanoparticles may be described as the effective volume of nanoparticles. This liquid layering is one important mechanism of the heat transfer in nanofluids. The effective volume of nanoparticles was estimated from high shear viscosity of nanofluid using the Einstein equation. The Hamilton–Crosser model with an effective volume fraction of nanoparticles resulted in better correlation for the thermal conductivities of nanofluids.

Journal ArticleDOI
TL;DR: In this article, the enhancement of the thermal conductivity of water in the presence of copper (Cu) using the chemical reduction method is presented, which is the first time that chemical reduction for synthesis of nanofluids containing Cu nanoparticles in water is reported.

Journal ArticleDOI
TL;DR: In this paper, the thermal conductivity enhancement of water-based MWCNT nanofluid is increased up to 11.3% at a volume fraction of 0.01.

Journal ArticleDOI
TL;DR: Using effective medium theory, the authors of as discussed by the authors demonstrate that the thermal conductivity of nanofluids can be significantly enhanced by the aggregation of nanoparticles into clusters, which is in excellent agreement with detailed numerical calculation on model of fractal clusters.
Abstract: Using effective medium theory the authors demonstrate that the thermal conductivity of nanofluids can be significantly enhanced by the aggregation of nanoparticles into clusters. Predictions of the effective medium theory are in excellent agreement with detailed numerical calculation on model nanofluids involving fractal clusters and show the importance of cluster morphology on thermal conductivity enhancements.

Journal ArticleDOI
TL;DR: In this paper, the effects of Rayleigh number (Ra) and aspect ratio (AR) on the flow pattern and energy transport within the thermal boundary layer were investigated for various pertinent parameters.

Journal ArticleDOI
TL;DR: In this paper, a porous layer of nanoparticles on the heated surface occurs upon boiling of nanofluids containing alumina, zirconia, or silica nanoparticles.
Abstract: Buildup of a porous layer of nanoparticles on the heated surface occurs upon boiling of nanofluids containing alumina, zirconia, or silica nanoparticles. This layer significantly improves the surface wettability, as shown by a reduction of the static contact angle on the nanofluid-boiled surfaces compared with the pure-water-boiled surfaces. The contact angle reduction is attributed to changes in surface energy and surface morphology brought about by the presence of the nanoparticle layer. The high surface wettability can plausibly explain the boiling critical heat flux enhancement in nanofluids.

Journal ArticleDOI
TL;DR: In this paper, a model for predicting the effective thermal conductivity of nanofluids is proposed, which takes into account some additional effects including volume fraction, thickness, thermal conductivities of the interfacial layer and particle size.
Abstract: A model for predicting the effective thermal conductivity of nanofluids is proposed. It has been documented that the interfacial layer at the solid (particle)/liquid interface and particle size is one of the major mechanisms for enhancing the thermal conductivity of nanofluids. Comparing with other classical models, the proposed model takes into account some additional effects including volume fraction, thickness, thermal conductivity of the interfacial layer and particle size. The proposed model is found to be better than the existing models since the predicted effective thermal conductivity of different types of nanofluids are closer to the experimental results.

Journal ArticleDOI
TL;DR: In this paper, the thermal conductivities of Fe3O4 aqueous nanofluids were studied and it was shown that Fe 3O4 has higher thermal conductivity than other oxide aqueues at the same volume fraction and attributed to the observed nanoparticle clustering and alignment.
Abstract: Thermal conductivities of Fe3O4 aqueous nanofluids were studied. The results show that Fe3O4 nanofluids have higher thermal conductivities than other oxide aqueous nanofluids at the same volume fraction. The experimental values are higher than those predicted by the existing models. The abnormal thermal conductivities of Fe3O4 nanofluids are attributed to the observed nanoparticle clustering and alignment.

Journal ArticleDOI
TL;DR: In this paper, various nanoparticles, such as multi-walled carbon nanotube (MWCNT), fullerene, copper oxide, silicon dioxide and silver, are used to produce nanofluids for enhancing thermal conductivity and lubrication.

Journal ArticleDOI
TL;DR: Applying a surface complexation model for the measurement data of hydrodynamic size, zeta potential, and thermal conductivity, it is shown that surface charge states are mainly responsible for the increase in the present condition and may be the factor incorporating all the mechanisms as well.
Abstract: Although various conjectures have been proposed to explain the abnormal increase in thermal conductivity of nanofluids, the detailed mechanism has not been fully understood and explained. The main reason is due to the lack of knowledge of the most fundamental factor governing the mechanisms such as Brownian motion, liquid layering, phonon transport, surface chemical effects, and agglomeration. Applying a surface complexation model for the measurement data of hydrodynamic size, ζ potential, and thermal conductivity, we have shown that surface charge states are mainly responsible for the increase in the present condition and may be the factor incorporating all the mechanisms as well.

Journal ArticleDOI
TL;DR: By combining nanofluids with thermally excited oscillating motion in an oscillating heat pipe (OHP), Wang et al. as mentioned in this paper developed an ultrahighperformance cooling device, called the nanoffluid oscillating pipe.
Abstract: By combining nanofluids with thermally excited oscillating motion in an oscillating heat pipe (OHP), we developed an ultrahigh-performance cooling device, called the nanofluid oscillating heat pipe. Experimental results show that when the OHP is charged with nanofluid, heat transport capability significantly increases. For example, at the input power of 80.0W, diamond nanofluid can reduce the temperature difference between the evaporator and the condenser from 40.9to24.3°C. This study will accelerate the development of a highly efficient cooling device for ultrahigh-heat-flux electronic systems.

Journal ArticleDOI
TL;DR: In this paper, a numerical method based on the control volume approach was used to solve the system of nonlinear and coupled governing equations of a turbulent flow of nanofluids, which are composed of saturated water and Al2O3 nanoparticles at various concentrations, flowing inside a tube submitted to uniform wall heat flux boundary condition.
Abstract: Purpose – To study the hydrodynamic and thermal behaviors of a turbulent flow of nanofluids, which are composed of saturated water and Al2O3 nanoparticles at various concentrations, flowing inside a tube submitted to a uniform wall heat flux boundary condition.Design/methodology/approach – A numerical method based on the “control‐volume” approach was used to solve the system of non‐linear and coupled governing equations. The classical κ‐e model was employed in order to model the turbulence, together with staggered non‐uniform grid system. The computer model, satisfactorily validated, was used to perform an extended parametric study covering wide ranges of the governing parameters. Information regarding the hydrodynamic and thermal behaviors of nanofluid flow are presented.Findings – Numerical results show that the inclusion of nanoparticles into the base fluid has produced an augmentation of the heat transfer coefficient, which has been found to increase appreciably with an increase of particles volume co...

Journal ArticleDOI
TL;DR: In this paper, an optical beam deflection technique was used for measurements of the thermal diffusivity of fluid mixtures and suspensions of nanoparticles with a precision of better than 1%.
Abstract: We describe an optical beam deflection technique for measurements of the thermal diffusivity of fluid mixtures and suspensions of nanoparticles with a precision of better than 1%. Our approach is tested using the thermal conductivity of ethanol-water mixtures; in nearly pure ethanol, the increase in thermal conductivity with water concentration is a factor of 2 larger than predicted by effective medium theory. Solutions of C60–C70 fullerenes in toluene and suspensions of alkanethiolate-protected Au nanoparticles were measured to maximum volume fractions of 0.6% and 0.35vol%, respectively. We do not observe anomalous enhancements of the thermal conductivity that have been reported in previous studies of nanofluids; the largest increase in thermal conductivity we have observed is 1.3%±0.8% for 4nm diam Au particles suspended in ethanol.

Journal ArticleDOI
TL;DR: In this paper, the enhancement of the thermal conductivity of ethylene glycol in the presence of copper oxide (CuO) was investigated by using a modified transient hot wire method.
Abstract: The enhancement of the thermal conductivity of ethylene glycol in the presence of copper oxide (CuO) is investigated. CuO nanofluids are prepared in a two-step method. No surfactant is employed as a dispersant. The volume fraction of CuO nanoparticles suspended in ethylene glycol liquid is below 5 vol.-%. The crystalline phases of the CuO powders are measured with x-ray diffraction patterns (XRD). CuO nanoparticles are examined using scanning electron microscopy (SEM) to determine their microstructure. The thermal conductivities of the CuO suspensions are measured by a modified transient hot wire method. The viscosity was measured with a viscosity instrument. The results show that CuO nanofluids with low concentrations of nanoparticles have considerably higher thermal conductivities than the identical ethylene glycol base liquids without solid nanoparticles. The thermal conductivity ratio improvement for CuO nanofluids is approximately linear with the volume fraction of nanoparticles. For CuO nanoparticles at a volume fraction of 0.05 (5 vol-.%) thermal conductivity was enhanced by up to 22.4 %. CuO nanofluids thus have good potential for effective heat transfer applications.

Journal ArticleDOI
TL;DR: In this article, the effective thermal conductivities and thermal diffusivities of various nanofluids using the transient short-hot-wire technique were measured and the effects of the volume fraction and thermal conductivity of the nanoparticles and temperature were clarified.
Abstract: This paper reports on measurements of the effective thermal conductivity and thermal diffusivity of various nanofluids using the transient short-hot-wire technique. To remove the influences of the static charge and electrical conductance of the nanoparticles on measurement accuracy, the short-hot-wire probes are carefully coated with a pure Al2O3 thin film and only those probes that are coated well are used for measurements. In the present study, the effective thermal conductivities and thermal diffusivities of Au/toluene, Al2O3/water, and carbon nanofiber (CNF)/water nanofluids are measured and the effects of the volume fraction and thermal conductivity of the nanoparticles and temperature are clarified. The average diameters of Au and Al2O3 spherical particles are 1.65 and 20nm, respectively. The average length and diameter of CNFs are 10μm and 150nm, respectively. The uncertainty of the present measurements is estimated to be within 1% for the thermal conductivity and 5% for the thermal diffusivity. The measured results demonstrate that the effective thermal conductivities of the nanofluids show no anomalous enhancements and can be predicted accurately by the model equation of Hamilton and Crosser [Ind. Eng. Chem. Fundam. 1, 187 (1962)] for the spherical nanoparticles and by the unit-cell model equation of Yamada and Ota [Waerme-Stoffuebertrag. 13, 27 (1980)] for carbon nanofibers.

Journal ArticleDOI
TL;DR: In this paper, the laminar forced convection flow of these nanofluids between two coaxial and parallel disks with central axial injection has been considered using temperature-dependent nano-fluid properties.

Journal ArticleDOI
TL;DR: In this article, the authors measured the effective thermal conductivity and thermal diffusivity of various nanofluids using the transient short-hot-wire technique, which can be predicted accurately by the model equation of Hamilton and Crosser, when the spherical nanoparticles are dispersed into fluids.
Abstract: This paper reports measurements of the effective thermal conductivity and thermal diffusivity of various nanofluids using the transient short-hot-wire technique. To remove the influences of the static charge and electrical conductance of the nanoparticles on measurement accuracy, the short-hot-wire probes are carefully coated with a pure Al2O3 thin film. Using distilled water and toluene as standard liquids of known thermal conductivity and thermal diffusivity, the length and radius of the hot wire and the thickness of the Al2O3 film are calibrated before and after application of the coating. The electrical leakage of the short-hot-wire probes is frequently checked, and only those probes that are coated well are used for measurements. In the present study, the effective thermal conductivities and thermal diffusivities of Al2O3/water, ZrO2/water, TiO2/water, and CuO/water nanofluids are measured and the effects of the volume fractions and thermal conductivities of nanoparticles and temperature are clarified. The average diameters of Al2O3, ZrO2, TiO2, and CuO particles are 20, 20, 40, and 33 nm, respectively. The uncertainty of the present measurements is estimated to be within 1% for the thermal conductivity and 5% for the thermal diffusivity. The measured results demonstrate that the effective thermal conductivities of the nanofluids show no anomalous enhancement and can be predicted accurately by the model equation of Hamilton and Crosser, when the spherical nanoparticles are dispersed into fluids.

Journal ArticleDOI
TL;DR: In this article, the size/microstructure of the nanoparticles are characterized by X-ray diffraction and transmission electron microscopy, and the thermal conductivity of the nanofluid is measured using a modified thermal comparator.