Topic
Nickel
About: Nickel is a research topic. Over the lifetime, 79308 publications have been published within this topic receiving 1210058 citations. The topic is also known as: Ni & element 28.
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01 Jan 1979
176 citations
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176 citations
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TL;DR: In this paper, the effect of MB adsorbed on the fly ash surface on the removal efficiency of cadmium, copper and nickel ionic species from complex, multi-cationic dye solutions was studied.
176 citations
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TL;DR: Smith et al. as mentioned in this paper used a hindered, rigid bidentate ligand (L) to create 12-electron methyliron(II) and 13-electronic methylcobalt(II), and showed that the ligand is thermally stable and low coordination number is maintained in solution.
Abstract: Three-coordinate organometallic complexes are rare, especially with the prototypical methyl ligand. Using a hindered, rigid bidentate ligand (L), it is possible to create 12-electron methyliron(II) and 13-electron methylcobalt(II) complexes. These complexes are thermally stable, and (1)H NMR spectra suggest that the low coordination number is maintained in solution. Attempts to create the 14-electron LNiCH(3) led instead to the three-coordinate nickel(I) complex LNi(THF). Single crystals of LMCH(3) are isomorphous with the new three-coordinate chloride complexes LNiCl and LCoCl. Along with the recently reported LFeCl (Smith, J. M.; Lachicotte, R. J.; Holland, P. L. Chem. Commun. 2001, 1542), these are the only examples of three-coordinate iron(II), cobalt(II), and nickel(II) complexes with terminal chloride ligands, enabling the systematic evaluation of the effect of coordination number and metal identity on M-Cl bond lengths. Electronic structure calculations predict the ground states of the trigonal complexes.
176 citations
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TL;DR: In this article, a study has been made of initial activity, steady-state activity and activity in the presence of H2S for CO hydrogenation on a number of supported catalysts.
176 citations