Nickel

About: Nickel is a research topic. Over the lifetime, 79308 publications have been published within this topic receiving 1210058 citations. The topic is also known as: Ni & element 28.

Desulfurization and novel sorbents for same

Abstract: Particulate sorbent compositions which are suitable for the removal of sulfur from streams of cracked-gasoline or diesel fuel are provided which have increased porosity, improved resistance to deactivation through the addition of a calcium compound selected from the group consisting of calcium sulfate, calcium silicate, calcium phosphate or calcium aluminate to the support system comprised of zinc oxide, silica and alumina having thereon a promotor wherein the promotor is metal, metal oxide or metal oxide precursor with the metal being selected from the group consisting of cobalt, nickel, iron, manganese, copper, molybdenum, tungsten, silver, tin and vanadium or mixtures thereof and wherein the valence of such promotor has been substantially reduced to 2 or less. Process for the preparation of such sorbent systems as well as the use of same for the desulfurization of cracked-gasolines and diesel fuels are also provided.

Anthropogenic Nickel Cycle: Insights into Use, Trade, and Recycling

Abstract: The anthropogenic nickel cycle for the year 2000 was analyzed using a material flow analysis at multiple levels: 52 countries, territories, or country groups, eight regions, and the planet. Special attention was given to the trade in nickel-containing products at different stages of the cycle. A new circular diagram highlights process connections, the role and potential of recycling, and the relevance of trade at different life stages. The following results were achieved. (1) The nickel cycle is dominated by six countries or territories: USA, China and Hong Kong, Japan, Germany, Taiwan, and South Korea; only China also mines some of its nickel used. (2) Nickel is mostly used in alloyed form in stainless steels (68%). (3) More scrap is used for the production of stainless steels (42%) than for other first uses (11%). (4) Industrial machinery is the largest end use category for nickel (25%), followed by buildings and infrastructure (21%) and transportation (20%). (5) 57% of discarded nickel is recycled within the nickel and stainless steel industries, and 14% is lost to other metal markets where nickel is an unwanted constituent of carbon steel and copper alloy scrap.

Corrosion-resistant alloys in chloride solutions: materials for surgical implants

Abstract: The behaviour of a number of corrosion-resistant alloys in chloride solutions. in Hanks's physiological solution (simulating the extracellular body fluids) and as surgical implants has been investigated by electrochemical means, namely potential-time curves for isolated specimens, potential-current density curves for anodes, and current density-time curves for anodes maintained electronically at constant potential. Microscopical observation of pitting attack has also been made. Alloys based on iron (e.g. stainless steels), nickel (e.g. Inconel, Nimonic 75, etc.), cobalt (Vitallium), titanium and tantalum exposed to chloride solutions all show a range of potential in which they are passive, and, at sufficiently high chloride concentration and sufficiently positive potential, breakdown giving rise to pits that are electrobrightened. This general phenomenon occurs. in 0$\cdot$17 M sodium chloride solution, at 0$\cdot$2 to 0$\cdot$5 V (normal hydrogen scale) for stainless steels, ca. 0$\cdot$9 V for the cobalt-based alloys, and ca. 20 to 30 V for certain titanium alloys and tantalum. In the passive range, all the alloys show anode current densities in the range 10$^{-6}$ to below 10$^{-9}$ A/cm$^2$, the smaller current densities given by the most passive alloys (e.g. titanium-5% niobium) often tending to decrease yet further with passage of time. We conclude that stainless steels (even of the higher chromium-nickel quality) and nickel alloys are unlikely to resist all breakdown by pitting when exposed to the body fluids (or other media containing chloride) indefinitely; that the cobalt-based alloys may well withstand such exposure for very long times; and that titanium and (especially) some of its alloys should withstand such exposure for an indefinite period. The (extremely slow) passage of cobalt and titanium into the environment is caused by passage of cations through their passivating oxide films, without breakdown.

Surface-Confined Fabrication of Ultrathin Nickel Cobalt-Layered Double Hydroxide Nanosheets for High-Performance Supercapacitors

Abstract: The design and fabrication of 2D nanostructure electrodes with desired electrochemical activities is highly demanded for electrocatalysis and supercapacitors. Herein, the tuned fabrication of ultrathin and tortuous nickel/cobalt-layered double hydroxide (NiCo-LDH) nanosheets via a graphene oxide (GO) surface-confined strategy is reported, yielding nanosheets with a thickness of 1.7–1.8 nm that is duplicated from the graphene oxides in terms of both the lateral size and the shape. It has been found that the C/O functional groups on the GO surface have functioned to promote the oxidation of Co2+ to Co3+, and to transform the β-phase NiCo-hydroxide (NiCo-OH) into the LDH-phase with tuned homogenous composition and geometry. The ultrathin NiCo-LDH nanosheets mimic the morphology and size of the graphene due to the surface-confined and/or surface-guided growth. The as-obtained NiCo-LDH-graphene (NiCo-LDH-G) nanosheets exhibit a superior electrocatalytic activity for oxygen evolution reaction, evidenced by a small overpotential of 0.337 V (@10 mA cm−2 in 0.1 m KOH electrolyte), and a high charge storage capability of 1489 F g−1 as electrodes for supercapacitors. This 2D surface-confined growth strategy may pave a way for the fabrication of ultrathin 2D materials including but not limited to transition metal hydroxides for high-performance electrochemical applications.