Topic
Nitrobenzene
About: Nitrobenzene is a research topic. Over the lifetime, 5285 publications have been published within this topic receiving 83368 citations. The topic is also known as: essence of mirbane & nitrobenzol.
Papers published on a yearly basis
Papers
More filters
TL;DR: By using different concentrations of beta-CD and HP-beta-CD as extractants, nitrobenzene on active carbon has been desorbed statically and the desorbing of mechanism has been discussed.
45 citations
TL;DR: The ball-milling-induced inter-particle compaction effect was considered crucial to facilitate the interfacial mass/electron transfer processes during the reduction of nitrobenzene, and the enhanced reactivity synergistically resulted from both chemical and physical aspects.
45 citations
TL;DR: In this paper, the chemisorption of toluene, m-xylene, mesitylene, n-butylbenzene, tbutyl benzene and aniline were studied on the (111 and (100) crystal faces of platinum at low pressures (10−9 to 10−7 torr) and at temperatures of 20 to 300 °C by low energy electron diffraction and work function change measurements.
45 citations
TL;DR: A new strategy was developed and applied in monitoring pH response and enzyme activity based on fluorescence emission red shift (FERS) of the conjugated polymer PPP-OR10 induced by the inner filter effect (IFE) of nitrobenzene derivatives, promising in applications in more complex conditions and a broader field.
Abstract: A new strategy was developed and applied in monitoring pH response and enzyme activity based on fluorescence emission red shift (FERS) of the conjugated polymer PPP-OR10 induced by the inner filter effect (IFE) of nitrobenzene derivatives. Neutral poly(p-phenylenes) functionalized with oligo(oxyethylene) side chains (PPP-OR10) was designed and synthesized by the Suzuki cross-coupling reaction. Nitrobenzene derivatives display different light absorption activities in the acidic or basic form due to adopting different electron-transition types. When environmental pH is higher than their pKa values, nitrobenzene derivatives exhibit strong absorbance around 400 nm, which is close to the maximal emission of polymer PPP-OR10. As a result, the maximal emission wavelength of PPP-OR10/nitrobenzene derivatives red shifts with the pH value increasing. Apparently, the IFE plays a very important role in this case. A new method has been designed that takes advantage of this pH-sensitive platform to sensor α-chymotrypsi...
45 citations
45 citations