Topic
Nitrobenzene
About: Nitrobenzene is a research topic. Over the lifetime, 5285 publications have been published within this topic receiving 83368 citations. The topic is also known as: essence of mirbane & nitrobenzol.
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TL;DR: In this paper, the Gibbs energies of transfer of ClO3, BrO3−, IO3, IO4−, OCN−, SeCN−, CN−, N3− and cycloalkyl carboxylate anions ((CH2)nCOO−, n n�= 3,…,7) at the water|nitrobenzene interface were determined.
Abstract: The previously introduced three-phase electrode technique was used to determine the Gibbs energies of transfer of ClO3−, BrO3−, IO3−, IO4−, OCN−, SeCN−, CN−, N3−, halogen substituted acetate anions Z3−nCHnCOO−
(Z = F,Cl,Br,I), and cycloalkyl carboxylate anions ((CH2)nCOO−, n = 3,…,7) at the water|nitrobenzene interface. Whereas the data for the small inorganic ions can easily be understood in terms of ion-dipole interactions, the data of the organic ions need consideration of charge delocalisation and its effect on the enthalpy and entropy of solvation.
42 citations
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TL;DR: A mild photochemical approach was applied to construct highly coupled metal-semiconductor dyads, which were found to efficiently facilitate the hydrogenation of nitrobenzene.
Abstract: A mild photochemical approach was applied to construct highly coupled metal-semiconductor dyads, which were found to efficiently facilitate the hydrogenation of nitrobenzene. Aniline was produced in excellent yield (>99 %, TOF: 1183) using formic acid as hydrogen source and water as solvent at room temperature. This general and green catalytic process is applicable to a wide range of nitroarenes without the involvement of high-pressure gases or sacrificial additives.
42 citations
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TL;DR: In this article, two Cu(I) coordination polymers based on the in situ generated 1-(4-tetrazolephenyl)imidazole ligand show intriguing ABW and (4,8)-connected topologies, and both of them are promising luminescent materials for sensing of nitrobenzene.
Abstract: Two Cu(I) coordination polymers based on the in situ generated 1-(4-tetrazolephenyl)imidazole ligand show intriguing ABW and (4,8)-connected topologies, and both of them are promising luminescent materials for sensing of nitrobenzene.
42 citations
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TL;DR: In this article, the pyrolysis of Zn/Co bimetal zeolitic imidazolate framework was used to construct controllable carbon nanocomposites.
Abstract: In this work, cobalt nanoparticles@N-doped carbon nanocomposites (Co@NC) with controllable Co contents have been prepared by pyrolysis of Zn/Co bimetal zeolitic imidazolate framework-9 (Zn/Co-ZIF-9...
42 citations
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TL;DR: In this paper, a linear sweep voltammetry (LSV) technique was used to study the electrochemical oxidation behavior of salicylic acid, benzoic acid, citric acid, aniline and nitrobenzene.
42 citations