Topic
Nitrobenzene
About: Nitrobenzene is a research topic. Over the lifetime, 5285 publications have been published within this topic receiving 83368 citations. The topic is also known as: essence of mirbane & nitrobenzol.
Papers published on a yearly basis
Papers
More filters
TL;DR: Using lutetium bis(tetra-tert-butylphthalocyaninato) as a redox probe for the three-phase electrode, the transfer of both anions and cations across the water/nitrobenzene interface can be studied in a single experiment.
Abstract: The redox properties of lutetium bis(tetra-tert-butylphthalocyaninato) (LBPC) have been studied in nitrobenzene that is deposited as a microfilm on the surface of highly oriented pyrolytic graphite electrodes. The behavior of the modified electrode, which is immersed in an aqueous electrolyte solution, is typical for the three-phase electrode (Scholz, F.; Komorsky-Lovric, S.; Lovric, M. Electrochem. Comm. 2000, 2, 112−118). LBPC can be both oxidized and reduced in one electron reversible processes. The oxidation and the reduction of LBPC at the graphite|nitrobenzene interface is accompanied by the transfer of anion or cation, respectively, from the aqueous phase into the organic layer. Thus, using LBPC as a redox probe for the three-phase electrode, the transfer of both anions and cations across the water|nitrobenzene interface can be studied in a single experiment. The hydrophobicity of LBPC is so high that it enables inspection of cations and anions with ≤ 43 kJ/mol and ≤ 50 kJ/mol, respectively. The di...
38 citations
TL;DR: In this article, the reduction of nitrobenzene to aniline with CO + H2O is used as a model reaction to analyze the catalytic system formed by a Group VIII transition metal cluster and a nitrogen-containing chelating ligand.
38 citations
TL;DR: The results suggested that the modification process promoted the catalytic activity of raw CH catalyst, namely the impregnation of metals (Mn, Cu and K) maybe enhance the initiation of hydroxyl radical (OH).
38 citations
TL;DR: In this article, the authors observed that degradation of Nitrobenzene by thermally activated persulfate oxidation process resulted in the formation of a suite of intermediates including 2-nitrophenol (2-NP), 3-nephenol(3-NP) and 4-nitro group upon SO 4 − /HO attack is proposed to play an important role in formation of polynitrated compounds.
38 citations
TL;DR: Sorption and diffusion of five monocyclic aromatic liquids (three halogenated benzenes, nitrobenzene, and aniline) with five engineering polymers (e.g., polyethylene propylene diene ter-polymer, nitrile butadiene rubber, styrene butadiane rubber, natural rubber, and neoprene) have been investigated in the temperature interval of 25-60°C as discussed by the authors.
Abstract: Sorption and diffusion of five monocyclic aromatic liquids—three halogenated benzenes, nitrobenzene, and aniline—with five engineering polymers—ethylene propylene diene ter-polymer, nitrile butadiene rubber, styrene butadiene rubber, natural rubber, and neoprene—have been investigated in the temperature interval of 25–60°C. Solvent diffusivity into polymer membranes was determined from the immersion/weight gain experiments. Permeability coefficients were also calculated from the diffusion and sorption data. A temperature dependence of sorption and transport was also investigated to estimate the activation parameters. The experimental results and computed quantities were used to study the type of transport mechanism and the nature of polymer-solvent interactions.
38 citations