Topic
Nitrobenzene
About: Nitrobenzene is a research topic. Over the lifetime, 5285 publications have been published within this topic receiving 83368 citations. The topic is also known as: essence of mirbane & nitrobenzol.
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TL;DR: In this paper, a graphite droplet containing iodide is attached to a polygonal graphite electrode and immersed into a chloride containing aqueous (AQ) solution, where the electrochemical reduction of iodine is accompanied by a transfer of chloride ions from NB to water.
37 citations
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TL;DR: Nitrobenzene (NB) was chosen as the probe compound to investigate the material's electro-reduction activity and LC-MS analysis revealed that the dominant reduction pathway on the NDD electrode was NB to phenylhydroxylamine (PHA) to AN.
37 citations
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37 citations
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TL;DR: In this article, the integration of the efficient conversion of nitrobenzene to aniline and transformation of glycerol to valuable chemicals driven by UV-light using Pd/TiO2 as the catalyst and water as the solvent at ambient temperature.
Abstract: Both effective utilization of glycerol and reduction of nitrobenzene to aniline are of great importance It is very interesting to integrate these processes This work reports the integration of the efficient conversion of nitrobenzene to aniline and transformation of glycerol to valuable chemicals driven by UV-light using Pd/TiO2 as the catalyst and water as the solvent at ambient temperature In this integrated reaction process, glycerol acted as the hydrogen source for the reduction of nitrobenzene to aniline and the glycerol was converted into value-added chemicals simultaneously At the optimized conditions, nitrobenzene could be converted completely with aniline selectivity of 95% with a nitrobenzene to glycerol mole ratio of 1 : 5 At the same time, glycerol was oxidized to form fine chemicals, including 1,3-dihydroxyacetone, glyceraldehyde, formic acid, and hydroxyacetic acid This work opens up a new and effective way for transformation of glycerol to fine chemicals and production of aniline from nitrobenzene
37 citations
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TL;DR: The Keggin-type heteropolyanion containing Mo or V as addenda atoms shows an appreciable promoting effect on the catalysis of PdCl 2 in the reductive carbonylation of nitrobenzene to form methyl N -phenylcarbamate in the presence of methanol in a moderately polar solvent such as 1,2-dimethoxyethane at 130-170°C under an initial CO pressure of 11-41 atm.
37 citations