Topic
Nitrobenzene
About: Nitrobenzene is a research topic. Over the lifetime, 5285 publications have been published within this topic receiving 83368 citations. The topic is also known as: essence of mirbane & nitrobenzol.
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TL;DR: The temperature required for the anodic conversion of an organo-solv spruce lignin, in aqueous alkaline solution, may be lowered by the addition of nitrobenzene or 1,3-dinitrobenzinene.
Abstract: The temperature required for the anodic conversion of an organo-solv spruce lignin, in aqueous alkaline solution, may be lowered by the addition of nitrobenzene or 1,3-dinitrobenzene. The additives cause significant and reproducible changes in the Tafel plot for the reaction. Preparativescale experiments are less reproducible although the range of phenolic products is generally similar to that produced by conventional nitrobenzene oxidation or by anodic oxidation at higher temperatures.
37 citations
TL;DR: In this article, the authors investigated the extraction of micro amounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B−) in the presence of TEtDPA, L. The equilibrium data have been explained assuming that the cations HL+, HL23, ML23+, ML23+ and ML33+ (M3+ = Eu3+, Am3+) are extracted into the organic phase.
Abstract: Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B−) in the presence of N,N,N′,N′-tetraethyl-2,6-dipicolinamide (TEtDPA, L) has been investigated. The equilibrium data have been explained assuming that the cations HL+, HL23+, ML23+ and ML33+ (M3+ = Eu3+, Am3+) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined. It has been found that the stability constants of the corresponding complexes EuLn,org3+ and AmLn,org3+, where n = 2, 3 and L is TEtDPA, in the mentioned medium are comparable.
37 citations
TL;DR: In the catalytic hydrogenation of nitrobenzene, the calcined Pt-MCM-41 meso-materials, like the corresponding reduced samples, exhibit high catalytic activities with an excellent selectivity to aniline, which are much better than those of the reduced Pt/MCm-41 prepared by the incipient wetness method.
37 citations
TL;DR: In this paper, an ordered mesoporous carbon (OMC) material was prepared and an OMC/didodecyldimethylammonium bromide (DDAB) composite was used as electrode modification material.
37 citations
TL;DR: In this article, the kinetics of polymerization and the molecular weight of polymers formed from N -vinyl carbazole (NVC) by (a ) chloranil (Ch) in nitrobenzene; (b ) tetranitromethane (TNM) in toluene; and (c ) TNM in nitrophenzene, have been studied.
37 citations