Topic
Nitrobenzene
About: Nitrobenzene is a research topic. Over the lifetime, 5285 publications have been published within this topic receiving 83368 citations. The topic is also known as: essence of mirbane & nitrobenzol.
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Papers
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TL;DR: A three-dimensional (3D), luminescent, 5-fold interpenetrating metal-organic framework (MOF) exhibiting highly selective sensing of nitrobenzene (NB) via a fluorescence quenching mechanism has been demonstrated.
Abstract: A three-dimensional (3D), luminescent, 5-fold interpenetrating metal-organic framework (MOF), [Zn2(fdc)2(bpee)2(H2O)]n·2H2O (1) exhibiting highly selective sensing of nitrobenzene (NB) via a fluorescence quenching mechanism has been demonstrated.
94 citations
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TL;DR: An electrochemical sensing platform which comprises gold nanoparticles (Au NPs) incorporated zinc based metal-organic framework (MOF-5) is developed for the sensitive determination of nitrite and nitrobenzene as mentioned in this paper.
94 citations
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TL;DR: In this paper, a pseudo-homogeneous model of the two fixed beds predicts the performance of this novel configuration first proposed by Moustafa and Elnashaie [Simultaneous production of styrene and cyclohexane in an integrated membrane reactor, where both hydrogen and heat are transferred across the surface of membrane tubes.
94 citations
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TL;DR: Pt/CeO2 catalysts with different support shapes and prereduction temperatures were prepared and tested in the liquid-phase hydrogenation of nitrobenzene.
Abstract: Pt/CeO2 catalysts with different support shapes and prereduction temperatures were prepared and tested in the liquid-phase hydrogenation of nitrobenzene. Detailed characterizations reveal that the ...
93 citations
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TL;DR: In this article, a single-atom photocatalyst (Pt@g-C3N4) was proposed for the hydrogenation of nitrobenzene to aniline under visible light.
Abstract: The hydrogenation of nitrobenzene into aniline is one of industrially important reactions, but still remains great challenge due to the lack of highly active, chemo-selective and eco-friendly catalyst. By using extensive density functional theory (DFT) calculations, herein we predict that single Pt atom decorated g-C3N4 (Pt@g-C3N4) exhibits excellent catalytic activity and selectivity for the conversion of nitrobenzene into aniline under visible light. The overall activation energy barrier for the hydrogenation of nitrobenzene on single atom Pt@g-C3N4 catalyst is even lower than that of the bare Pt(111) surface. The dissociation of N–O bonds on single Pt atom is triggered by single hydrogen atom rather than double hydrogen atoms on the Pt(111) surface. Moreover, the Pt@g-C3N4 catalyst exhibits outstanding chemoselectivity towards the common reducible substituents, such as phenyl,–C=C,–C≡C and–CHO groups during the hydrogenation. In addition, the doped single Pt atom can significantly enhance the photoconversion efficiency by broadening the light absorption of the pristine g-C3N4 to visible light region. Our results highlight an interesting and experimentally synthesized single-atom photocatalyst (Pt@g-C3N4) for efficient hydrogenation of nitrobenzene to aniline under a sustainable and green approach.[Figure not available: see fulltext.].
93 citations