Topic
Norbornadiene
About: Norbornadiene is a research topic. Over the lifetime, 2389 publications have been published within this topic receiving 38603 citations.
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TL;DR: Deltacyclenes and deltacyclanes produced from the homo Diels-Alder reaction of norbornadiene are opened to the corresponding biquinanes as mentioned in this paper.
9 citations
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TL;DR: In this paper, the effects of the reaction medium, presence of a cocatalyst and the type of catalysis (homogeneous or heterogeneous) on the morphology of the polymers obtained have been studied and discussed.
Abstract: Scanning electron microscopy characterization of the materials obtained by homogeneous and heterogeneous catalytic polymerization of phenylacetylene is described. The catalysts used are β-dioxygenato rhodium(I) complexes. The effects of the reaction medium, presence of a cocatalyst and the type of catalysis (homogeneous or heterogeneous) on the morphology of the polymers obtained have been studied and discussed. Using a supported complex at 0 °C, nanoparticles with a diameter distribution as narrow as 30 to 70 nm were obtained. Polymer nanopowders were found to be unaffected by ageing. Copyright © 2003 John Wiley & Sons, Ltd.
9 citations
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TL;DR: The norbornadiene(terpyridine) complex [Mo(CO)(C 7 H 8 )(terpy)I]I] as mentioned in this paper was obtained in two steps from either KPF 6 in methanol or AgSbF 6 in CH 2 Cl 2.
9 citations
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TL;DR: The microstructures of both the toluene soluble and o-dichlorobenzene insoluble fractions were characterized by high resolution 13C nuclear magnetic resonance spectroscopy in solution and/or in the solid state and by differential scanning calorimetry as mentioned in this paper.
9 citations
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TL;DR: In this article, the bimetallics Cp 2 Nb(μ-PPh 2 )(μ -CO)M(CO) 3 (PMe 2 H)(M = Cr, W) were prepared by UV irradiation of the dinuclear monobridged complexes.
9 citations