Topic
Norbornadiene
About: Norbornadiene is a research topic. Over the lifetime, 2389 publications have been published within this topic receiving 38603 citations.
Papers published on a yearly basis
Papers
More filters
TL;DR: In this paper, a cyclocodimerization of norbornadiene with acrylates in the presence of bis(η3-allyl)nickel is studied.
Abstract: Cyclocodimerization of norbornadiene with acrylates in the presence of bis(η3-allyl)nickel is studied. The regio- and stereoselectivities of cycloaddition depend on the catalyst composition, temperature, reactant ratio, and the nature of acrylate. Conditions excluding the side direction (norbornadiene homodimerization) are selected. A mechanism that explains the main regularities of codimerization is proposed.
9 citations
TL;DR: In this paper, aldol-type coupling of activated vinyl components with aldehydes was investigated via in situ rhodium silyl enolates, and a related approach, via a similar approach, was also investigated.
9 citations
TL;DR: In this paper, low-temperature photolysis of NbdCr(CO)4(I) (Nbd norbornadiene) in the presence of triphenylphosphine yields trans-NbdCr[P(C6H5)3]
9 citations
TL;DR: The influence of nuclearity and charge of chiral Rh diene complexes on the activity and enantioselectivity in catalytic asymmetric 1,2-additions of organoboron reagents to N-tosylimines and 1,4-add...
9 citations
TL;DR: In this paper, a self-supporting polymeric poly(phenylacetylene) and polystyrene which contain galvinoxyl and trimethylsilyl units was synthesized by copolymerization of the corresponding monomers or polymer reaction of corresponding methyl benzoate polymers with [3,5-di-tert-butyl-4-(trimethylsiloxy)phenyl]lithium.
9 citations