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Norbornadiene
About: Norbornadiene is a research topic. Over the lifetime, 2389 publications have been published within this topic receiving 38603 citations.
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TL;DR: Pd-catalyzed multicomponent coupling reactions of five-membered heteroaryl halides and norbornadiene (NBD) were developed, demonstrating the versatility of NBD as an acetylene synthon.
7 citations
TL;DR: In this article, the Diels-Alder adducts of benzo-ortho-thiazine structure were confirmed by NMR, IR spectroscopy and XRD analysis.
Abstract: Reactions of N-sulfinylanilines with norbornene and norbornadiene result in the Diels-Alder adducts of benzo-ortho-thiazine structure, which was confirmed by the NMR, IR spectroscopy and XRD analysis. In all cases the diene added to the norbornenes bicyclic system at the side of the endo-methylene bridge. The methyl group of meta-N-sulfinyl toluidine directs the norbornene entry into the para-position.
7 citations
TL;DR: In this paper, the reactions of the complexes [Pt(diene)Cl2]-diene = norbornadiene or dicyclopentadiene with the nucleophiles OPri−, NH2Ph, SPh−, and SCN− have been investigated.
Abstract: The reactions of the complexes [Pt(diene)Cl2](diene = norbornadiene or dicyclopentadiene) with the nucleophiles OPri–, NH2Ph, SPh–, and SCN– have been investigated The dicyclopentadiene complex undergoes attack at the diene in each case and the S-nucleophiles also give substitution at platinum Onlythelatterreactionoccurswith the norbornadiene complexes and S-nucleophiles, but attack on the organic ligand is found with OPri– and NH2Ph, The reactions of these products with neutral uni- and bi-dentate ligands usually leads to bridge-splitting reactions, but in some cases the norbornenyl derivatives undergo rearrangement to nortricyclene systems The reaction of the alkenyl complexes with a further nucleophile (OMe– or NHPh–) to give doubly σ-bonded alkyleneplatinum complexes is described
7 citations
TL;DR: In this paper, an efficient route for the synthesis of norbornadiene-tethered tethered organisms was developed and their intramolecular 1,3-dipolar cycloadditions were found to be highly regio-and stereo-selective.
7 citations
TL;DR: In this article, the stereoselective formation of 8-substituted deltacyclanes by homo Diels-Alder (HDA) reaction using a phosphine modified nickel catalyst generated by reduction of Ni(acac) 2 with alkylaluminums is discussed.
7 citations