Topic
Norbornadiene
About: Norbornadiene is a research topic. Over the lifetime, 2389 publications have been published within this topic receiving 38603 citations.
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6 citations
TL;DR: Co(indenyl)(cod)-catalysed cycloaddition terpolymerisation of CO with diynes HCC(CH2)mCCH(m= 8, 6 and 4) and norbornadiene affors poly(enone)s.
6 citations
TL;DR: The PF 6 salts of the new cationic hexamethylborazinerhodium(I) complexes of general formula [Rh(Me 3 B 3 N 3 Me 3 )(LL′)] + (LL′= 1,5-cyclooctadiene, norbornadiene and tetrafluorobenzobarrelene, trimethyltetra-braselinhodium, L = L′ = ethylene, CO) have been prepared from the reaction between [RhCl(LL') 2, Me 3 B3 NMe 3,
6 citations
TL;DR: In this paper, the effect of the solvent on the reaction pattern is considered in terms of polarity, polarizability, and coordinating ability of a solvent, which are the key factors in selecting the proper solvent.
Abstract: The palladium-catalyzed allylation of norbornadiene is a unique method for the C-C bond formation involving allyl derivatives. This reaction proceeds in solution. However, the selection of the solvent is so far an empirical procedure, and the role of the solvent in this process is poorly understood. The effect of the solvent on the reaction pattern is considered in terms of polarity, polarizability, and coordinating ability of the solvent. These properties were shown to be the key factors in selecting the proper solvent. Based on investigation of the mechanism of individual catalytic cycle stages, the features of the interaction between the solvent, the catalyst, and reagents were analyzed.
6 citations
TL;DR: Tricarbonyl(norbornadiene)-2-carbaldehyde-2-caraldehyde (2-CARDE) was shown to give tricaronyl-1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,34,33,35,36,37,38,39,40,40
Abstract: Tricarbonyl(norbornadiene)iron (1), previously thought not to undergo electrophilic attack at carbon, gives tricarbonyl(norbornadiene-2-carbaldehyde)iron (2) on treatment with dichloromethyl methyl ether and titanium tetrachloride followed by hydrolysis.
6 citations