Topic
Norbornadiene
About: Norbornadiene is a research topic. Over the lifetime, 2389 publications have been published within this topic receiving 38603 citations.
Papers published on a yearly basis
Papers
More filters
TL;DR: The coordination polymerization of 1-ethynylcyclohexene was carried out using various rhodium catalysts as mentioned in this paper, which gave a well defined polyacetylene derivative bearing conjugated double bond moieties, whose UV-vis absorption spectrum has its maximum at 380 nm and cut off at 500 nm.
Abstract: The coordination polymerization of 1-ethynylcyclohexene was carried out using various rhodium catalysts. Polymerization catalyzed with [Rh(norbornadiene)Cl]2/triethylamine gave a well-defined polyacetylene derivative bearing conjugated double bond moieties, whose UV-vis absorption spectrum has its maximum at 380 nm and cut off at 500 nm.
5 citations
TL;DR: In this article, the synthesis and reactions of bimetallic Zr(II)-Mo(0) complexes with bridging C5H4PPh2 ligands are described.
5 citations
TL;DR: The morphan skeleton was prepared from 2-phenylsulfonyl-2-azabicyclo[3.3.1]non-6-ene by adding dichlorocarbene to the monoene 2 and subsequent thermal isomerization of the adduct obtained as mentioned in this paper.
Abstract: The morphan skeleton was prepared from 2-phenylsulfonyl-2-azabicyclo[3.2.1]oct-6-ene (2), derived from norbornadiene, through the addition of dichlorocarbene to the monoene 2 and the subsequent thermal isomerization of the adduct obtained. The isomerization products, 2-phenylsulfonyl-6,7-dichloro-2-azabicyclo[3.3.1]non-7-ene and 2-phenylsulfonyl-7,8-dichloro-2-azabicyclo[3.3.1]non-6-ene, which are mutually convertible in the presence of lithium chloride, were converted into various morphans by reductive dechlorination and alkylation. Furthermore, the 6,7-pyridazino-annelated morphan was synthesized by the cycloaddition of dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate to 2-phenylsulfonyl-2-azabicyclo[3.3.1]non-6-ene.
5 citations
TL;DR: Tetrakis(diisopropyl amide) substituted norbornadiene and quadricyclane derivatives were investigated for their extraction and transport capabilities with alkaline earth metal cations and exhibited a remarkably high preference of Ba(2+) over any other alkali metal or alkalineearth cation.
Abstract: Tetrakis(diisopropyl amide) substituted norbornadiene and quadricyclane derivatives were investigated for their extraction and transport capabilities with alkaline earth metal cations. Both amides exhibited a remarkably high preference of Ba2+ over any other alkali metal or alkaline earth cation. The binding geometries were determined by quantum chemical DFT calculations.
5 citations
TL;DR: In this paper, the intramolecular photoaddition of 1,4,4a,5,8,8ahexahydro-1, 4, 5,8-endo,endo -dimethanonaphthalene to provide a cage isomer is reported.
5 citations