Topic
Norbornadiene
About: Norbornadiene is a research topic. Over the lifetime, 2389 publications have been published within this topic receiving 38603 citations.
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TL;DR: The presence de 4 centres de chiralite dans le compose du titre as mentioned in this paper is mentioned in the pre-publication version of this article, and qu'une serie compliquée de decyclisation et d'epimerisations soit a l'origine du compose
Abstract: Presence de 4 centres de chiralite dans le compose du titre. Il semblerait qu'une serie compliquee de decyclisation et d'epimerisations soit a l'origine du compose
4 citations
TL;DR: In this paper, photooxygenation of quadricyclane(1) was shown to proceed via the electron transfer mechanism on the basis of the structure revision of a methoxy alcohol.
Abstract: Photooxygenation of quadricyclane(1) was shown to proceed via the electron transfer mechanism on the basis of the structure revision of a methoxy alcohol. Photoisomerization of 1 to norbornadiene occurred during the irradiation.
4 citations
TL;DR: In this paper, the reaction of dimethyl anti-7-(trimethylsilyl)-2,5-norbornadiene-2,3-dicarboxylate with nitronium tetrafluoroborate (NTBF) was shown to obtain the title compound 2 (65%).
Abstract: Reaction of dimethyl anti-7-(trimethylsilyl)-2,5-norbornadiene-2,3-dicarboxylate (dimethyl anti-7-(trimethylsilyl)bicyclo[2.2.1]hepta- 2,5-diene-2,3-dicarboxylate, 1) with nitronium tetrafluoroborate affords the title compound 2 (65%). Subsequent photolysis of 2 affords the corresponding substituted quadricyclane derivative 3 (75%). Flash vacuum pyrolysis of 2 at 600 o C affords dimethyl phthalate (67%) as the only isolable product
4 citations
TL;DR: In this paper, a reaction mechanism was proposed for 2-(4-chlorophenylimino)-1-phenylethanone with methanol and SO 2 catalysis with low degree of electroselectivity and π-facial stereoselectivity.
4 citations
TL;DR: The addition of aryl azidosulfates to norbornadiene gives in high yields and selectively, the N-[aroxysulfonyl]-2-azabicyclol[3,2,1]-3,6-octadienes resulting from ring enlargement by insertion of nitrogen as mentioned in this paper.
4 citations