Topic
Norbornadiene
About: Norbornadiene is a research topic. Over the lifetime, 2389 publications have been published within this topic receiving 38603 citations.
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TL;DR: In this paper, the authors proposed a structure for mononuclear complexes of the type [Rh(diolefin)(μ-X)]2 [X = Cl or Br; diolefins = cod (cycloocta-1,5-diene) or nbd (norbornadiene)] undergo dihalobridge cleavage with 2-substituted benzimidazoles.
Abstract: Complexes of the type [Rh(diolefin)(μ-X)]2 [X = Cl or Br; diolefin = cod (cycloocta-1,5-diene) or nbd (norbornadiene)] undergo dihalobridge cleavage with 2-substituted benzimidazoles to produce mononuclear complexes, RhX(diolefin)(R-BzlH) (R = α-Py or Ph), and N-heterocycle bridged dimers, [RhX(diolefin)]2(μ-N–N) (N–N = β-PyBzlH or γ-PyBzlH). Facile replacement ofone or both diolefins by CO occurs in the products to yield the corresponding di/tetracarbonyl complexes. Probable structures have been proposed for the complexes on the basis of physical, i.r., far-i.r. and 1H- and 13C-n.m.r. spectral techniques and FAB-MS.
4 citations
TL;DR: In this article, a quadricyclane derivative stable in water was first synthesized, and its valence isomerization was shown to be very clean, to be promising for a solar energy storage system.
Abstract: A quadricyclane derivative stable in water was first synthesized. Valence isomerization between the quadricyclane and the corresponding norbornadiene was very clean, to be promising for a solar energy storage system.
4 citations
TL;DR: In this paper, new heterogenizated catalysts for the allylation of norbornadiene (NBD) were prepared by the adsorption immobilization and surface assembly methods.
Abstract: New heterogenizated catalysts for the allylation of norbornadiene (NBD) were prepared by the adsorption immobilization and surface assembly methods. The obtained catalysts were screened in the allylation of NBD, and the main technological parameters of the process were determined.
4 citations
TL;DR: The photocycloaddition of a steroidal 4-en-3-one and a 4,6-dien-3 -one to bicyclo[2.2.1]heptene and bicyclo [2.3.2] heptadiene has been studied in this article.
4 citations
TL;DR: The chemoselectivity of norbornadiene was studied in this paper, showing that it is not changed by pressure in the catalyzed addition of propynoates, but is not altered in the corresponding addition to norbornene.
Abstract: The chemoselectivity is changed by pressure in the catalyzed addition of propynoates to norbornadiene, but is not altered in the corresponding addition to norbornene.
4 citations