Topic
Norbornadiene
About: Norbornadiene is a research topic. Over the lifetime, 2389 publications have been published within this topic receiving 38603 citations.
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TL;DR: In this article, the longitudinal nuclear spin relaxation times and NOE enhancement factors of 13 C nuclei of the compounds named in the title, dissolved in CDCl 3, were measured in two magnetic fields.
3 citations
TL;DR: In this article, the cis-to-trans isomerization was also induced when the pristine predominant cis polymer was subjected to mechanochemical grinding (MCG) treatment at 77 K using a mortar filled with liquid nitrogen to decrease the cis content from ca. 68% to ca. 7%.
3 citations
TL;DR: The final product from the reaction of norbornadiene and Rh6(CO)16 is a dinuclear species containing the novel C8H8O ligand, formally an acylvinyl cyclopentene derivative, which is bound by both σ- and π-bonds to both rhodium atoms.
Abstract: The final product from the reaction of norbornadiene and Rh6(CO)16 is a dinuclear species containing the novel C8H8O ligand, formally an acylvinyl cyclopentene derivative, which is bound by both σ- and π-bonds to both rhodium atoms.
3 citations
Patent•
05 May 1986TL;DR: Bicycle diamines are prepared by a process comprising reacting 5-vinyl-2-norbornene or norbornadiene, synthesis gas and an amine from the group consisting of primary amines and secondary amines in the presence of a catalyst comprising a ruthenium-containing compound, an amide solvent and a quaternary phosphonium salt.
Abstract: Bicyclic diamines are prepared by a process comprising reacting 5-vinyl-2-norbornene or norbornadiene, synthesis gas and an amine from the group consisting of primary amines and secondary amines in the presence of a catalyst comprising a ruthenium-containing compound, an amide solvent and a quaternary phosphonium salt.
3 citations
3 citations