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Norbornadiene
About: Norbornadiene is a research topic. Over the lifetime, 2389 publications have been published within this topic receiving 38603 citations.
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41 citations
TL;DR: A palladium-catalyzed arylboration of norbornene or norbornadiene with aryL halides and bis(pinacolato)diboron has been disclosed and is complementary to the existing methods and well tolerable with a variety of functional groups.
Abstract: A palladium-catalyzed arylboration of norbornene or norbornadiene with aryl halides and bis(pinacolato)diboron has been disclosed. Mechanistic studies suggest that the reaction proceeds under a Catellani-type coupling to render versatile multifunctionalized alkylboranes in good yields. This reaction is complementary to the existing methods and is well tolerable with a variety of functional groups and readily scaled-up to a gram scale without deteriorating the yield.
41 citations
TL;DR: Structures cristallines des deux formes polymorphes du [Rh ((R)-Cycphos) (norbornadiene)] ClO 4. Mise en evidence d'orientation differente des cycles phenyle and cyclohexyle. Complexes plan carre as discussed by the authors.
41 citations
TL;DR: In this paper, the synthesis, spectroscopic and structural characterisation, and electrochemical behaviour of some rhodium and iridium complexes of the form LM(X1)(X2)+, where L is a chelating bis(carbene) derived from an imidazolium-linked ortho-cyclophane, were described.
41 citations
TL;DR: A group of mixed ligand ruthenium(II)-Schiff base complexes has been synthesized and characterized in this article, and they have been found to serve as good catalyst precursors for ring-opening metathesis polymerization (ROMP) and atom transfer radical polymerization of different vinyl monomers.
Abstract: A group of four mixed ligand ruthenium(II)-Schiff base complexes has been synthesized and characterized. These complexes are easily accessible from [RuCl2(p-cymene)]2, [RuCl2(NBD)]n, [RuCl2(COD)]x and salicylaldimine salts. They have been found to serve as good catalyst precursors for ring-opening metathesis polymerization (ROMP) and atom transfer radical polymerization (ATRP) of different vinyl monomers. The catalytic activity and the control over the produced polymer can be dramatically improved after the addition of additives such as Et2AlCl and (n-Bu)2NH.
41 citations