Topic
Norbornadiene
About: Norbornadiene is a research topic. Over the lifetime, 2389 publications have been published within this topic receiving 38603 citations.
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TL;DR: The results demonstrate that Co-bisphosphane systems are sufficiently reactive and that they lead to high selectivity in the intermolecular process and the first catalytic system with useful levels of enantioselection for the reaction of norbornadiene and trimethylsilylacetylene.
36 citations
36 citations
TL;DR: In this paper, the electronic and steric effects of the ligand were used to determine the activity of catalysts for acetone hydrogenation formed in situ from [Rh(norbornadiene)Cl]2 and phosphines or phosphinic acid esters.
36 citations
TL;DR: In this paper, the synthesis of poly(silsesquioxane)s (poly(SCC)) with excellent refractive indices properties, which have pendant norbornadiene (NBD), azobenzene (AZ), and anthracene (AT) moieties.
Abstract: We succeeded in the synthesis of certain poly(silsesquioxane)s (poly(SCC)) with excellent refractive indices properties, which have pendant norbornadiene (NBD), azobenzene (AZ), and anthracene (AT) moieties. The photochemical reactions of the obtained poly(SCC) derivatives were examined in the film state upon UV irradiation, and it was found that poly(SCC) derivatives with NBD groups, AZ groups, and AT groups had large change in values of the refractive index (ΔnD's) before and after photoirradiation which were in the range of 0.050−0.073, 0.007−0.009, and 0.094−0.116, respectively.
35 citations
TL;DR: In this article, a ring opening metathesis polymerisation (ROMP) of norbornene and norbornadiene derivatives containing oxygen is investigated using Grubbs well-defined ruthenium initiator.
35 citations