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Norbornadiene
About: Norbornadiene is a research topic. Over the lifetime, 2389 publications have been published within this topic receiving 38603 citations.
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TL;DR: In this article, the standard enthalpies of isomerization, hydrogenation, and formation of norbornadiene, quadricyclane, norbornene, nortriclyn, and norbornan were calculated.
Abstract: We have calculated the standard enthalpies of isomerization, hydrogenation, and formation (ΔhydH298, ΔisomH298, and ΔfH298) of norbornadiene, quadricyclane, norbornene, nortricyclane, and norbornan...
25 citations
TL;DR: In this paper, a photoresponsive polymers bearing norbornadiene (NBD) moieties were synthesized in high yields without any insoluble gel products by the selective cationic polymerization of 2-[[(3-phenyl-2,5-norbornadienyl)-2-carbonyl]oxy] ethyl vinyl ether (PNVE) and also by the copolymerizations with 2-phenoxyethyl vinyl ether, 2-chloroethyl, or isobutyl (IsO(C 2 H 5 )a
Abstract: New photoresponsive polymers bearing norbornadiene (NBD) moieties were synthesized in high yields without any insoluble gel products by the selective cationic polymerization of 2-[[(3-phenyl-2,5-norbornadienyl)-2-carbonyl]oxy] ethyl vinyl ether (PNVE) and also by the copolymerizations with 2-phenoxyethyl vinyl ether, 2-chloroethyl vinyl ether, or isobutyl vinyl ether using BF 3 -O(C 2 H 5 )a as a catalyst in dichloromethane solution.
25 citations
25 citations
25 citations
TL;DR: Diphenylneopentylsilene, Ph 2 Si=CHCH 2 t Bu ( 3 ), is prepared as a reactive intermediate by the reaction of diphenylvinylchlorosilane (1 ) with Li t Bu in nonpolar solvents via the α-lithioadduct Ph 2Si(Cl)CH(Li)CH 2 T Bu ( 2 ) This lithiated species can be trapped by trimethylsilyltriflate and yields silene 3 by 1,2-LiCl-elimination without suitable Si
25 citations