Nuclear quadrupole resonance

About: Nuclear quadrupole resonance is a research topic. Over the lifetime, 3531 publications have been published within this topic receiving 38801 citations. The topic is also known as: Nuclear quadrupole resonance spectroscopy & NQR.

Detection of Landmines Using Nuclear Quadrupole Resonance (NQR): Signal Processing to Aid Classification

Abstract: Nuclear quadrupole resonance (NQR) is a sensor technology that measures a signature unique to the explosive contained in the mine, thus providing a means of efficiently detecting landmines. Unfortunately, the measured signals are inherently weak and therefore detection times are currently too long (especially for TNT-based landmines) to implement in a man-portable detection system. However, the NQR hardware is light enough to be integrated into a robot based system. This paper investigates several power spectrum estimation algorithms applied to NQR signals in order to distinguish between data containing signals from explosive and data that does not.

Effect of pressure on 14N nuclear quadrupole relaxation in hexamethylenetetramine

Abstract: 14N nuclear quadrupole resonance frequencies and spin‐lattice relaxation time, T1, in hexamethylenetetramine (HMT) were measured as a function of hydrostatic pressure up to 6 katm at 257, 273, 294.5, 309, and 317°K. For the three higher isotherms T1 depends exponentially on pressure up to 3 katm. In this region T1 is determined mainly by molecular reorientation of the tetrahedral HMT molecule around its four threefold axes. This mechanism is discussed in terms of a simple activation process. The activation volume, ΔV*=23.6±1 cm3/mole, and activation enthalpy, ΔH*=17±1 kcal/mole were determined. From thermal expansion and compressibility data, the thermal pressure, Pt = T(∂p/∂T)v, of 6.2 katm and activation energy ΔE* = 12–15 kcal/mole were deduced. These values of ΔH*, ΔE*, and ΔV* are higher than the corresponding values reported by Anderson and Slichter for three other organic solids and might indicate the effect of the large number of hydrogen bonds in HMT.

Spectroscopic Study of $^{75}$As and $^{139}$La NMR on Layered Structure Ferromagnet LaCoAsO

Abstract: $^{75}$As and $^{139}$La field-swept NMR spectra were obtained for the novel weakly itinerant ferromagnet LaCoAsO with 2D layered structure above the Curie temperature of 55 K. By analyzing NMR spectra, temperature dependences of Knight shift $K$ and nuclear quadrupole resonance frequency $ u_Q$ were obtained successfully for each nucleus. We confirmed from the so-called $K$-$\chi$ plots that the macroscopic magnetization of our {LaCoAsO} powder sample is intrinsic and does not contain the contribution from impurity phases. We estimated hyperfine coupling constants from the slope of $K$-$\chi$ plots and compared to that of iron-arsenide superconductor.

NQR parameters of complexes and polarizability effect

Abstract: The literature data on substituent influence on the nuclear quadrupole resonance frequencies (ν), quadrupole coupling constants (e2Qq ⋅ h− 1), and asymmetry parameters (η) for 36 series of the H-complexes, charge–transfer complexes, transition metal complexes and other donor–acceptor complexes have been considered, using the correlation analysis. Generally the ν, e2Qq ⋅ h− 1, and η values were first established to depend on the inductive, resonance, polarizability, and steric effects of substituents. The presence or otherwise of certain effects as well as relation between their contributions are determined by the type of series. The polarizability effect owes its existence to the appearance of an excess charge on the indicator centre as a result of the complexation. The contribution of this effect ranges up to 75%. Copyright © 2012 John Wiley & Sons, Ltd.