Topic
Organic radical battery
About: Organic radical battery is a research topic. Over the lifetime, 821 publications have been published within this topic receiving 53015 citations. The topic is also known as: ORB.
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TL;DR: In this paper, both negative and positive electrode materials in NIB are briefly reviewed, and it is concluded that cost-effective NIB can partially replace Li-ion batteries, but requires further investigation and improvement.
Abstract: Lithium (Li)-ion batteries (LIB) have governed the current worldwide rechargeable battery market due to their outstanding energy and power capability. In particular, the LIB's role in enabling electric vehicles (EVs) has been highlighted to replace the current oil-driven vehicles in order to reduce the usage of oil resources and generation of CO2 gases. Unlike Li, sodium is one of the more abundant elements on Earth and exhibits similar chemical properties to Li, indicating that Na chemistry could be applied to a similar battery system. In the 1970s-80s, both Na-ion and Li-ion electrodes were investigated, but the higher energy density of Li-ion cells made them more applicable to small, portable electronic devices, and research efforts for rechargeable batteries have been mainly concentrated on LIB since then. Recently, research interest in Na-ion batteries (NIB) has been resurrected, driven by new applications with requirements different from those in portable electronics, and to address the concern on Li abundance. In this article, both negative and positive electrode materials in NIB are briefly reviewed. While the voltage is generally lower and the volume change upon Na removal or insertion is larger for Na-intercalation electrodes, compared to their Li equivalents, the power capability can vary depending on the crystal structures. It is concluded that cost-effective NIB can partially replace LIB, but requires further investigation and improvement.
2,885 citations
TL;DR: Constructing S molecules confined in the conductive microporous carbon materials to improve the cyclability of Li-S batteries serves as a prospective strategy for the industry in the future.
Abstract: With the increasing demand for efficient and economic energy storage, Li-S batteries have become attractive candidates for the next-generation high-energy rechargeable Li batteries because of their high theoretical energy density and cost effectiveness. Starting from a brief history of Li-S batteries, this Review introduces the electrochemistry of Li-S batteries, and discusses issues resulting from the electrochemistry, such as the electroactivity and the polysulfide dissolution. To address these critical issues, recent advances in Li-S batteries are summarized, including the S cathode, Li anode, electrolyte, and new designs of Li-S batteries with a metallic Li-free anode. Constructing S molecules confined in the conductive microporous carbon materials to improve the cyclability of Li-S batteries serves as a prospective strategy for the industry in the future.
2,213 citations
Book•
30 Aug 2001
TL;DR: In this article, the authors present the principles of operation and reactions factors affecting battery performance standardization of battery design selection and application of batteries, as well as a discussion of the differences between primary and secondary batteries.
Abstract: Part 1 Principles of operation: basic concepts electrochemical principles and reactions factors affecting battery performance standardization of batteries battery design selection and application of batteries. Part 2 Primary batteries: zinc-carbon (Leclanche) cells magnesium and aluminium cells alkaline-manganese dioxide cells mercuric oxide cells silver oxide cells zinc/air cells lithium cells solid electrolyte batteries. Part 3 Reserve batteries: magnesium water-activated batteries spin-dependent reserve batteries liquid ammonia systems lithium anode reserve batteries thermal batteries. Part 4 Secondary batteries: lead acid batteries industrial nickel-cadmium batteries vented nickel-cadmium batteries sealed nickel-cadmium batteries nickel-zinc batteries iron electrode batteries silver-oxide batteries nickel-hydrogen batteries nickel-metal hydride batteries rechargeable alkaline-manganese dioxide batteries. Part 5 Advanced battery systems: ambient temperature lithium batteries zinc/bromine batteries metal/air batteries lithium/iron sulphide batteries sodium beta batteries.
2,185 citations
TL;DR: In this paper, a 3-volt secondary Na-ion battery possessing environmental and cost friendliness, Na+-shuttlecock hard-carbon/NaNi0.5Mn 0.5O2 cell, demonstrates steady cycling performance as next generation secondary batteries and an alternative to Li-ion batteries.
Abstract: Recently, lithium-ion batteries have been attracting more interest for use in automotive applications. Lithium resources are confirmed to be unevenly distributed in South America, and the cost of the lithium raw materials has roughly doubled from the first practical application in 1991 to the present and is increasing due to global demand for lithium-ion accumulators. Since the electrochemical equivalent and standard potential of sodium are the most advantageous after lithium, sodium based energy storage is of great interest to realize lithium-free high energy and high voltage batteries. However, to the best of our knowledge, there have been no successful reports on electrochemical sodium insertion materials for battery applications; the major challenge is the negative electrode and its passivation. In this study, we achieve high capacity and excellent reversibility sodium-insertion performance of hard-carbon and layered NaNi0.5Mn0.5O2 electrodes in propylene carbonate electrolyte solutions. The structural change and passivation for hard-carbon are investigated to study the reversible sodium insertion. The 3-volt secondary Na-ion battery possessing environmental and cost friendliness, Na+-shuttlecock hard-carbon/NaNi0.5Mn0.5O2 cell, demonstrates steady cycling performance as next generation secondary batteries and an alternative to Li-ion batteries.
1,679 citations
TL;DR: The goal of the present article is to provide a survey of electroactive polymers in view of potential applications in rechargeable batteries, and reviews the preparative methods and the electrochemical performance of polymers as rechargeable battery electrodes.
Abstract: Electrochemical energy storage systems (batteries) have a tremendous role in technical applications In this review the authors examine the prospects of electroactive polymers in view of the properties required for such batteries Conducting organic polymers are considered here in the light of their rugged chemical environment: organic solvents, acids, and alkalis The goal of the present article is to provide, first of all in tabular form, a survey of electroactive polymers in view of potential applications in rechargeable batteries It reviews the preparative methods and the electrochemical performance of polymers as rechargeable battery electrodes The theoretical values of specific charge of the polymers are comparable to those of metal oxide electrodes, but are not as high as those of most of the metal electrodes normally used in batteries Therefore, it is an advantage in conventional battery designs to use the conducting polymer as a positive electrode material in combination with a negative electrode such as Li, Na, Mg, Zn, MeH{sub x}, etc 504 refs
1,481 citations