Showing papers on "Organomercury Compounds published in 1983"
TL;DR: The first transition metal complexes containing ortho-nitroaryl ligands were proposed in this paper. But they did not contain ortho -nitro-cyclic ligands.
39 citations
TL;DR: In this paper, a linear correlation between the chemical shift, δ(199Hg), and the sum of the orbital electronegativities on silicon is reported for symmetric species.
19 citations
TL;DR: The insertion of a fragment Pd(CO)L in the course of reaction of organomercury compounds with pd(0) complexes has been observed for the first time.
Abstract: 1.
Organomercury compounds react with the cluster Pd10(CO)12(PBu3)6 to form mononuclearσ-complexes of palladium.
2.
The insertion of a fragment Pd(CO)L in the course of reaction of organomercury compounds with Pd(0) complexes has been observed for the first time.
4 citations
1 citations
1 citations
TL;DR: The mechanism of solvation of a series of symmetrical organomercury compounds of different classes has been studied in this article, where the spin-spin coupling constants of several types, where one of the interesting nuclei is the metal nucleus, were chosen as the measured parameter.
Abstract: The mechanism of solvation of a series of symmetrical organomercury compounds of different classes has been studied. Spin-spin coupling constants of several types, where one of the interesting nuclei is the metal nucleus, were chosen as the measured parameter. The observed solvation changes in the spin-spin coupling constants have been interpreted from the viewpoint of the two most important mechanisms of solvation-electrostatic, resulting from the solvation Stark effect, and donor-acceptor. The relationship between the solvation changes in the symmetrical organomercury compounds and the electron distribution in the metalcarbon bond, and also the sign of the spin-spin coupling constants, has been examined.