Topic
Organomercury Compounds
About: Organomercury Compounds is a research topic. Over the lifetime, 392 publications have been published within this topic receiving 6465 citations.
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TL;DR: In this article, mixed haloforms are used as starting materials in organic synthesis, mainly as precursors of dihalocarbenes, and they are used for preparation of phenyldibromochloromethylmercury and phenylbromodichloromethsylmer cury respectively.
14 citations
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TL;DR: In this article, the effect of coordination, adsorption and the nature and properties of intermediates on these processes as well as on the formation of organomercury derivatives in the adaption of organic and hetero-organic compounds on a mercury electrode are analyzed.
Abstract: Characteristic features of mechanisms and kinetics of electrode reactions of organomercury compounds (symmetrical, non-symmetrical) and organomercury salts on a mercury electrode are analyzed. Attention is focused on the effect of coordination, adsorption and the nature and properties of intermediates on these processes as well as on the formation of organomercury derivatives in the adsorption of organic and hetero-organic compounds on a mercury electrode. The kinetics of heterogeneous chemical equilibrium organic calomel?symmetrical organomercury compound in the adsorption layer and the relative stability of intermediates in the one-electron reduction of organomercury salts are discussed as well as the electrolytic hydrogen evolution catalyzed by organomercury intermediates. The problems of combined and separate electrochemical quantitation of organic and inorganic mercury compounds in natural objects are considered.
14 citations
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14 citations
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13 citations
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TL;DR: In this article, the possibilities for a correlation of the polarographical reduction parameters of organometallic compounds with the pKa-values of CH-acids are discussed.
13 citations