Topic
Organomercury Compounds
About: Organomercury Compounds is a research topic. Over the lifetime, 392 publications have been published within this topic receiving 6465 citations.
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TL;DR: In this article, conditions for the formation of organomercury compounds from other organometallics are outlined, where the phenyl group causes a considerable shift of the redox potential to negative values as compared with the Cr(dipy) 3 3+ system.
4 citations
TL;DR: A new, selective test technique for the determination of organomercury compounds and mercury combines their preliminary separation by thin-layer chromatography on silica with further enzymatic determination employing o-dianisidine oxidation catalysed by horseradish peroxidase.
4 citations
TL;DR: In this article, β-substituted homo- and hetero-metallic trianions of the type C (Ph) with alkali metal cations (Li, Na, and K) were obtained from β-sourced organomercury compounds via low temperature mercury-alkali metal transmetallation; the lithiated trianion reacts regioselectively at both carbanionic carbon atoms with electrophilic agents such as D2O, EtBr, Me2S2, and Me3SiCl.
Abstract: New β-substituted homo- and hetero-metallic trianions of the type C (Ph) with alkali metal cations (Li, Na, and K) are obtained from β-substituted organomercury compounds via low temperature mercury–alkali metal transmetallation; the lithiated trianion reacts regioselectively at both carbanionic carbon atoms with electrophilic agents such as D2O, EtBr, Me2S2, and Me3SiCl.
4 citations
01 Jan 1985
4 citations
TL;DR: The reaction of unsymmetrical organomercury compounds RHgR′ with carbon tetrachloride in the presence of benzoyl peroxide has been investigated in this paper.
4 citations