Topic
Organomercury Compounds
About: Organomercury Compounds is a research topic. Over the lifetime, 392 publications have been published within this topic receiving 6465 citations.
Papers published on a yearly basis
Papers
More filters
Journal Article•
3 citations
TL;DR: In this paper, it was shown that the essence of nucleophilic catalysis in reactions of the SE1-N type consists in the one-electron reduction of the metal-carbon bond with the formation of the carbanion.
Abstract: 1
On the example of the carboranyl derivatives of mercury it was shown that the essence of nucleophilic catalysis in reactions of the SE1-N type consists in the one-electron reduction of the metal-carbon bond with the formation of the carbanion.
2.
Under anionic catalysis conditions organomercury compounds, which contain strong electron-acceptor substituents, are capable of exchange and addition reactions that outwardly resemble the analogous transformations of organomagnesium and organolithium compounds.
3 citations
TL;DR: It has been shown that organomercury compounds containing strongly electro-negative groups in the β-position and which are not capable of inter-and intramolecular interaction with the mercury atom, undergo symmetrization and substitution reactions rather than β-elimination in the presence of nucleophiles as discussed by the authors.
3 citations
TL;DR: It is concluded that 6-thioguanine acts as a bidentate ligand, coordinating through the 6thione group and deprotonation of N-7 to display significant activity against L1210 leukemia cells.
3 citations
01 Jan 1978
TL;DR: In this article, the authors propose a method to solve the problem of unstructured data in order to improve the quality of the data collected by the data collection system and the system itself.
Abstract: . . . . . . . . . . . . . . . ». . . . . . . . . . . , viii
3 citations