Topic
Organomercury Compounds
About: Organomercury Compounds is a research topic. Over the lifetime, 392 publications have been published within this topic receiving 6465 citations.
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TL;DR: In this article, a study was made of the kinetics of the iododemercuration of organomercury compounds, containing strong electron-acceptor substituents, in dimethylformamide and in benzene.
Abstract: 1.
A study was made of the kinetics of the iododemercuration of organomercury compounds, containing strong electron-acceptor substituents, in dimethylformamide and in benzene.
2.
The increase in the rate of the iododemercuration reaction in the discussed series of organomercury compounds proceeds symbatically with increase in the stability of the carbanion, entering into the composition of the organomercury compound.
TL;DR: In this article, the 1H, 13C, and 1H-195Pt INDOR spectra have been investigated with reference to the 13C parameters and δ(199Hg) of the mercury compounds, [HgX(R)](X = Cl, Br, I, or R).
Abstract: Salts, [NPrn4][PtCl2R (CO)](R = Me, Et, Prn, Pri, Bun, or Ph), have been prepared from the reaction of [NPrn4]2-[Pt2Cl4(CO)2] with HgR2, but derivatives with R = But, C2H3, or C3H5 could not be obtained. Infrared and Raman spectra are reported and discussed. The 1H, 13C, and 1H-{195Pt} INDOR spectra have been investigated. The behaviours of 1J(PtC) and δ(195Pt) are discussed with reference to the 13C parameters and δ(199Hg) of the mercury compounds, [HgX(R)](X = Cl, Br, I, or R).