Topic
Organomercury Compounds
About: Organomercury Compounds is a research topic. Over the lifetime, 392 publications have been published within this topic receiving 6465 citations.
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01 Jan 2009
TL;DR: In this article, it was shown that trichloride exchanges two of its halogen atoms only for a radical that possesses a trans-configuratlon in cis-trans compounds, or for the radical that experiences electrophilic attack by the hydrogen ion in the decomposition of RHgR' by hydrochloric acid.
Abstract: Thallium trichloride exchanges two of its halogen atoms only for a radical that possesses a trans-configuratlon in cis-trans compounds, or for a radical that experiences electrophilic attack by the hydrogen ion in the decomposition of RHgR' by hydrochloric acid.
TL;DR: In this article, the NQR spectra of halogens in a number of organomercury compounds of the RHgHal and p-ClC6 H4HgX types were investigated.
Abstract: 1.
The NQR spectra of halogens in a number of organomercury compounds of the RHgHal and p-ClC6 H4HgX types were investigated.
2.
In crystals of the compounds studied, coordination interactions arise between the mercury atoms and the halogens. However, when the type of coordination is preserved within a narrow series of compounds, the changes in the NQR frequencies may be determined by the chemical nature of the substituents.
3.
The chemical behavior of the HgHal group depends substantially on the degree of coordination saturation of the mercury atom.