Topic
Oxalic acid
About: Oxalic acid is a research topic. Over the lifetime, 11584 publications have been published within this topic receiving 173263 citations. The topic is also known as: ethanedioic acid & H2ox.
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TL;DR: There was a small, but unproblematic increase in formic acid levels in comparison to the levels in the controls, and no rise of free acidity was encountered after a combined treatment with formic and oxalic acid during the three trial years.
Abstract: Formic acid and oxalic acid field trials for control of Varroa destructor were carried out in autumn according to the Swiss prescriptions during three successive years in different apiaries in Switzerland. The following parameters were determined in honey that was harvested the year after treatment: formic acid, ox- alic acid and free acidity. The following range of values were found in honeys of untreated colonies: formic acid, from 17 to 284 mg/kg, n = 34; oxalic acid, from 11 to 119 mg/kg, n = 33. There was a small, but unproblematic increase in formic acid levels in comparison to the levels in the controls; average: 46 mg/kg, maximum: 139 mg/kg. No increase in formic acid was found with increasing number of treatment years. If emergency formic acid treatments were carried out in spring, the residue levels were much higher: average in- crease of 193 mg/kg, maximum 417 mg/kg. The oxalic acid content remained unchanged, even after two suc- cessive treatments during the same autumn. No rise of free acidity was encountered after a combined treatment with formic and oxalic acid during the three trial years. honey/residue/formic acid/oxalic acid/free acidity/Varroa destructor
75 citations
TL;DR: In this paper, a study has been made of a leaching process to remove iron from quartziferous industrial minerals using oxalic and sulphuric acid in a drum reactor.
75 citations
TL;DR: In this article, charge density analysis from both experimental and theoretical points of view on two molecular complexes: one formed between nicotinamide and salicylic acid, and the other formed between oxalic acid brings out the quantitative topological features to distinguish a cocrystal from a salt.
Abstract: Charge density analysis from both experimental and theoretical points of view on two molecular complexes: one is formed between nicotinamide and salicylic acid, and the other formed between nicotinamide and oxalic acid brings out the quantitative topological features to distinguish a cocrystal from a salt.
75 citations
TL;DR: In this paper, a group of dicarboxylic acids with mebendazole via liquid-assisted grinding and reaction crystallization methods, and two salts with oxalic and maleic acids, as well as two co-crystals with malonic and glutaric acids were obtained.
Abstract: An anthelmintic drug, mebendazole, shows a very low bioavailability (less than 10%) due to its poor aqueous solubility (0.035 mg/mL at 25 °C for form C). To improve its solubility, we combined a group of dicarboxylic acids with mebendazole via liquid-assisted grinding and reaction crystallization methods, and two salts with oxalic and maleic acids, as well as two co-crystals with malonic and glutaric acids, were obtained. These novel multi-component complexes were characterized by powder X-ray diffraction, differential scanning calorimetry, thermogravimetric analyses and infrared spectra. The single-crystal structures of mebendazole-maleate salt, mebendazole-glutaric acid co-crystal, and mebendazole-monomethyl oxalate salt, in which one of the carboxyl groups of oxalic acid was esterified during the single-crystal growth in methanol, were determined. It was observed that mebendazole combines dicarboxylic acid/ester via a R22(8) hydrogen-bonding motif that involves a carbamyl benzimidazole and a carboxyl group, resulting in the 1:1 stoichiometry. The powder dissolution studies revealed that the apparent solubility of the complexes was significantly increased after the formation of co-crystals and salts.
75 citations
TL;DR: The two strains had almost identical metabolic fluxes, which suggested that it was possible to disrupt the oah gene without pleiotropic consequences and suggested that a sufficient supply of NADPH was available for biosynthesis.
75 citations