Showing papers on "Oxidation of secondary alcohols to ketones published in 1997"

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Oxidation of secondary alcohols byN-methylmorpholine-N-oxide (NMO) catalyzed by atrans-dioxo ruthenium(VI) complex or perruthenate complex: A kinetic study

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K. J. Tony¹, V. Mahadevan¹, J. Rajaram¹, C. S. Swamy¹•Institutions (1)

Indian Institute of Technology Madras¹

01 Sep 1997-Reaction Kinetics and Catalysis Letters

TL;DR: The trans-dioxo ruthenium (VI) complex catalyzes the oxidation of secondary alcohols to ketones by N-methylmorpholine-Noxide (NMO) as mentioned in this paper.

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Abstract: Thetrans-dioxo ruthenium (VI) complex, [P(C6H5)3C6H5CH2]+[Ru(O)2OAcCl2] or tetrapropylammonium perruthenate catalyzes the oxidation of secondary alcohols to ketones byN-methylmorpholine-N-oxide (NMO). Kinetic studies showed the formation of a complex between catalyst and substrate (alcohol) as the first step in the mechanism.

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