Showing papers on "Oxidation of secondary alcohols to ketones published in 2001"
15 Apr 2001
TL;DR: InChIKey as mentioned in this paper ] is a key for storing ammonium heptamolybdate tetrahydrate tetrahedrate under air, which can be used and stored at rt under air.
Abstract: (H2O2) [7722-84-1] H2O2 (MW 34.02)
InChI = 1S/H2O2/c1-2/h1-2H
InChIKey = MHAJPDPJQMAIIY-UHFFFAOYSA-N
((NH4)6Mo7O24) [12027-67-7] H24Mo7N6O24 (MW 1163.88)
((NH4)6Mo7O24·4H2O) [12054-85-2] H32Mo7N6O28 (MW 1235.96)
(epoxidation;2 oxidation of secondary alcohols to ketones;2, 3 oxidation of aldehydes to acids;2 chemoselection between epoxidation and alcohol oxidation2, 4)
Physical Data: (NH4)6Mo7O24·4H2O: dec 190 °C; d 2.498 g cm−3.
Solubility: (NH4)6Mo7O24·4H2O: sol H2O (43 g/100 mL); insol alcohol.
Form Supplied in: (NH4)6Mo7O24·4H2O: colorless or slightly greenish or yellowish crystals; widely available.
Handling, Storage, and Precautions: (NH4)6Mo7O24·4H2O: commercially available ammonium heptamolybdate tetrahydrate can be used and stored at rt under air. For H2O2, see Hydrogen Peroxide.