Pentacene

About: Pentacene is a research topic. Over the lifetime, 5051 publications have been published within this topic receiving 161481 citations. The topic is also known as: 2,3:6,7-dibenzanthracene & benzo[b]naphthacene.

Ammonia gas sensor based on pentacene organic field-effect transistor

Abstract: Ammonia (NH3) sensors based on bottom contact organic field-effect transistors (OFETs) were created using pentacene as an active layer and polymerthylmethacrylate (PMMA) as an insulator. The OFET sensors exhibited a change in the electric characteristic such as the threshold voltage, the saturation current, and the field-effect charge carrier mobility when the sensors were exposed to different NH3 concentrations. Meanwhile, the favorable and rapid NH3 response characteristics of the OFET sensors were observed from the change in the drain-source current as a function of time, when the sensors were exposed to various cycles of exposure/evacuation of different NH3 concentrations ranging from 10 to 100 ppm. Moreover, the environmental stability of the OFET sensors to constantly detect the NH3 gas in air was studied by storing the sensors in air for 30 days.

Effect of annealing on the mobility and morphology of thermally activated pentacene thin film transistors

Abstract: Pentacene thin film transistors (TFTs) were fabricated by the organic molecular beam deposition method. The TFTs were characterized in order to study the effect of thermal annealing on the morphology and carrier mobility of the transistors. For all the TFT samples the mobility exhibited an Arrhenius relationship with temperature, indicating a thermally activated transport that could be explained by the carrier trap and thermal release transport mechanism. Therefore, in order to investigate the annealing effect, we tested the data for a significant period of time after annealing until the temperature recovered to room temperature, so that the thermal activation effect was screened and possible effects of thermal expansion and stress were also ruled out. As a result, we found that only with a temperature below a critical temperature of approximately 45°C could annealing improve the mobility, while annealing with T>50°C would decrease the mobility compared to the value before annealing. Atomic force microsco...

Effects of the permanent dipoles of self-assembled monolayer-treated insulator surfaces on the field-effect mobility of a pentacene thin-film transistor

Abstract: In order to investigate the effects of permanent dipoles on insulator surfaces on the electrical properties of organic thin-film transistors, the authors fabricated insulators with various self-assembled monolayers and similar surface energies. Surprisingly, they found that the field-effect mobility of pentacene thin-film transistors increases by a factor of approximately 20 for insulators with an electron-withdrawing group. This remarkable increase in the field-effect mobility is due to the increase in the hole density of the insulator surface that arises from the increased band bending of the insulator/semiconductor interface.

In situ antibody detection and charge discrimination using aqueous stable pentacene transistor biosensors.

Abstract: Pentacene-based organic thin-film transistors were used to create highly sensitive, real-time electronic sensors for selective antibody detection. Bovine serum albumin was covalently attached to a modified pentacene surface to selectively detect the label free monoclonal antiBSA. These sensors displayed a high affinity constant (K(A)) of (1.1 ± 3) × 10(7) M(-1) at pH 7, which is 1 order of magnitude higher than those obtained with a highly sensitive surface plasmon resonance spectroscopy detection system. Furthermore, a high degree of discrimination in the hybrid antiBSA charges was achieved at different pH values. This demonstration of fast, label-free, real-time detection of nanoscale biomolecules in aqueous buffer solutions using the organic transistor sensing platform will have a significant impact on high-performance microarrays in addition to discriminating the presence of ionizable groups.

High‐Resolution Characterization of Pentacene/Polyaniline Interfaces in Thin‐Film Transistors

Abstract: We present the first detailed report that directly correlates the reduced contact resistance in organic thin-film transistors (TFTs) with fundamental structural and morphological characterization at the organic semiconductor/conducting polymer interface. Specifically, the pentacene grains are similar in size and continuous across the channel/electrode interface in bottom-contact TFTs with polyaniline (PANI) electrodes. On a molecular level, the fused rings of pentacene are oriented perpendicular to the surface both in the channel and on PANI. Accordingly, the contact resistance is small in such devices. In TFTs with gold electrodes, however, the pentacene grains are different in size and are discontinuous across the channel/electrode interface. Further, the fused rings of pentacene are oriented perpendicular to the channel surface and parallel to the gold surface. Such differences across the channel/electrode interface lead to structural and electronic disorder, which manifests itself as a significantly larger contact resistance in devices with gold electrodes.