Perovskite solar cell

About: Perovskite solar cell is a research topic. Over the lifetime, 4701 publications have been published within this topic receiving 216807 citations. The topic is also known as: PSC.

Passivating Detrimental DX Centers in CH 3 NH 3 PbI 3 for Reducing Nonradiative Recombination and Elongating Carrier Lifetime

Abstract: After a period of rapid, unprecedented development, the growth in the efficiency of perovskite solar cells has recently slowed. Further improvement of cell efficiency will rely on the in-depth understanding and delicate control of defect passivation. Here, the formation mechanism of iodine vacancies (VI ), a typical deep defect in CH3 NH3 PbI3 (MAPbI3 ), is elucidated. The structural and electronic behaviors of VI are like those of a DX center, a kind of detrimental defect formed by large atomic displacement. Aided by the passivation mechanism of DX centers in tetrahedral semiconductors, it is found that the introduction of Br strengthens chemical bonds and prevents large atomic displacements during defect charging. It therefore reduces the defect states and diminishes electron-phonon coupling. Using time-domain density functional theory (DFT) combined with nonadiabatic molecular dynamics, it is found that the carrier lifetime can be enhanced from 3.2 ns in defective MAPbI3 to 19 ns in CH3 NH3 Pb(I0.96 Br0.04 )3 . This work advances our understanding of how a small amount of Br doping improves the carrier dynamics and cell performance of MAPbI3 . It may also provide a route to enhance the carrier lifetimes and efficiencies of perovskite solar cells by defect passivation.

Green solvent for perovskite solar cell production

Abstract: Perovskite solar cell (PSC) technology is moving closer to commercialization but the ecotoxicity of the solvents involved in perovskite processing remains a barrier. A study now identifies a green solvent that can help PSC sustainability and scalability.

Rapid Scalable Processing of Tin Oxide Transport Layers for Perovskite Solar Cells.

Abstract: The development of scalable deposition methods for perovskite solar cell materials is critical to enable the commercialization of this nascent technology. Herein, we investigate the use and processing of nanoparticle SnO2 films as electron transport layers in perovskite solar cells and develop deposition methods for ultrasonic spray coating and slot-die coating, leading to photovoltaic device efficiencies over 19%. The effects of postprocessing treatments (thermal annealing, UV ozone, and O2 plasma) are then probed using structural and spectroscopic techniques to characterize the nature of the np-SnO2/perovskite interface. We show that a brief "hot air flow" method can be used to replace extended thermal annealing, confirming that this approach is compatible with high-throughput processing. Our results highlight the importance of interface management to minimize nonradiative losses and provide a deeper understanding of the processing requirements for large-area deposition of nanoparticle metal oxides.