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Perovskite solar cell

About: Perovskite solar cell is a research topic. Over the lifetime, 4701 publications have been published within this topic receiving 216807 citations. The topic is also known as: PSC.


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Journal ArticleDOI
TL;DR: A new class of hole-transport materials based on the bimesitylene core designed for mesoporous perovskite solar cells is introduced, and the stability of the device made using the highest performing HTM (P1) is improved compared with spiro-OMeTAD as evidenced through long-term stability tests.
Abstract: A new class of hole-transport materials (HTMs) based on the bimesitylene core designed for mesoporous perovskite solar cells is introduced. Devices fabricated using two of these derivatives yield higher open-circuit voltage values than the commonly used spiro-OMeTAD. Power conversion efficiency (PCE) values of up to 12.11% are obtained in perovskite-based devices using these new HTMs. The stability of the device made using the highest performing HTM (P1) is improved compared with spiro-OMeTAD as evidenced through long-term stability tests over 1000 h.

45 citations

Journal ArticleDOI
TL;DR: In this paper, the effect of poly(methyl methacrylate) (PMMA)/reduced graphene oxide composite (PRC) passivation layer on the chemical and thermal stability of PSCs was explored.
Abstract: An organic–inorganic perovskite solar cell (PSC) is a very promising candidate for a next-generation photovoltaic system For the last three years, the power conversion efficiency (PCE) of PSCs has been dramatically improved from 97% to 221%; however, a poor long-term stability still limits the commercialization of PSCs In this study, we explore the effect of poly(methyl methacrylate) (PMMA)/reduced graphene oxide (rGO) composite (PRC) passivation layer on the chemical and thermal stability of PSCs The PRC passivation layer shows superior protection performance due to improved hydrophobicity and increased complexity of the O2 or H2O diffusion pathway Moreover, the excellent thermal conductivity of rGO facilitates heat dissipation through the PRC layer When the PRC layer is coated, the aging of PSCs is significantly prevented even under extreme conditions of humidity (>75%) and temperature (∼85 °C) Consequently, the PCE of PRC-passivated PSCs exhibits a negligible change in air, temperature of 35 °C, and humidity of 40% for 1000 h Our study offers a simple and robust way to fabricate long-term stable and highly efficient PSCs, thus providing a path to PSC commercialization

45 citations

Journal ArticleDOI
TL;DR: The synthesis of SnO2 NF/NB ETLs provides a simple, low-cost and large-scale method for PSCs.
Abstract: The implementation of positive alternative electron transporting layers (ETLs) with excellent electronic properties is a most promising method to up-scale low-cost highly efficient perovskite solar cell (PSC) technology. The present work demonstrates the preparation of tin oxide (SnO2) nanofibers (NF) and nanobelts (NB) as an electron transporting layer (ETL) for PSCs. The smooth and uniform nanofibers and nanobelts have been prepared using an electrospinning technique followed by calcination at 600 °C. Thermogravimetric analysis (TGA) analysis performed on the as-spun polyvinylpyrrolidone-tin oxide (PVP-SnO2) composite suggests that a calcination temperature of 600 °C is required to obtain pure SnO2 and to ensure complete removal of PVP along with other organic solvents. The structural analysis confirmed the presence of the pure tetragonal rutile phase of SnO2 nanofibers and nanobelts. The prepared nanofibers and nanobelts were further used as ETLs for PSCs. Our optimized experimental parameters yielded a JSC of 22.46 mA cm-2, a VOC of 1.081 V and FF of 66%, leading to >16% power conversion efficiency (PCE) for SnO2 nanobelts using an (FAPbI3)0.85(MAPbI3)0.15 perovskite absorber layer with good stability. The obtained PCE is much higher than that of the SnO2 NF (12.893%) morphology. Nevertheless, the synthesis of SnO2 NF/NB ETLs provides a simple, low-cost and large-scale method for PSCs.

45 citations

Journal ArticleDOI
07 May 2020
TL;DR: In this article, a doping technique that introduces suitable elements into the host material is extensively utilized to modulate the perovskite lattice structure, stabilize crystallographic phases, and achieve vari...
Abstract: A doping technique that introduces suitable elements into the host material is extensively utilized to modulate the perovskite lattice structure, stabilize crystallographic phases, and achieve vari...

45 citations


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Performance
Metrics
No. of papers in the topic in previous years
YearPapers
2023225
2022409
2021631
2020770
2019835
2018780