scispace - formally typeset
Search or ask a question
Topic

Perovskite (structure)

About: Perovskite (structure) is a research topic. Over the lifetime, 51482 publications have been published within this topic receiving 1541750 citations.


Papers
More filters
Journal ArticleDOI
TL;DR: All inorganic CsPbX3 (X = Cl, Br, I) perovskite nanocrystals with 50-85% photoluminescence quantum yields and tunable emission in the range of 440-682 nm have been successfully synthesized at room temperature in open air.

310 citations

Journal ArticleDOI
21 Jun 2016-ACS Nano
TL;DR: This work proposes and demonstrates facile solution synthesis of a series of colloidal organometal halide perovskite CH3NH3PbX3 (X = halides) nanoparticles with amorphous structure, which exhibit high quantum yield and tunable emission from ultraviolet to near-infrared in light-emitting devices.
Abstract: Organometal halide perovskite has recently emerged as a very promising family of materials with augmented performance in electronic and optoelectronic applications including photovoltaic devices, photodetectors, and light-emitting diodes. Herein, we propose and demonstrate facile solution synthesis of a series of colloidal organometal halide perovskite CH3NH3PbX3 (X = halides) nanoparticles with amorphous structure, which exhibit high quantum yield and tunable emission from ultraviolet to near-infrared. The growth mechanism and photoluminescence properties of the perovskite amorphous nanoparticles were studied in detail. A high-efficiency green-light-emitting diode based on amorphous CH3NH3PbBr3 nanoparticles was demonstrated. The perovskite amorphous nanoparticle-based light-emitting diode shows a maximum luminous efficiency of 11.49 cd/A, a power efficiency of 7.84 lm/W, and an external quantum efficiency of 3.8%, which is 3.5 times higher than that of the best colloidal perovskite quantum-dot-based lig...

310 citations

Journal ArticleDOI
TL;DR: In this paper, the authors investigate the performance and photostability of metal halide perovskites across a compositional space of formamidinium (FA) and cesium (Cs) at the A-site at various halide compositions.
Abstract: Metal halide perovskites are attractive candidates for the wide band gap absorber in tandem solar cells. While their band gap can be tuned by partial halide substitution, mixed halide perovskites often have lower open-circuit voltage than would be expected and experience photoinduced trap formation caused by halide segregation. We investigate solar cell performance and photostability across a compositional space of formamidinium (FA) and cesium (Cs) at the A-site at various halide compositions and show that using more Cs at the A-site rather than more Br at the X-site to raise band gap is more ideal as it improves both VOC and photostability. We develop band gap maps and design criteria for the selection of perovskite compositions within the CsxFA1–xPb(BryI1–y)3, space. With this, we identify perovskites with tandem-relevant band gaps of 1.68 and 1.75 eV that demonstrate high device efficiencies of 17.4 and 16.3%, respectively, and significantly improved photostability compared to that of the higher Br-co...

310 citations

Journal ArticleDOI
TL;DR: The dynamic microstructure phenomena are attributed to the charge imbalance from the replacement of A-site cations with La3+ and local stress on Cosite sub-lattice with the cubic perovskite structure.
Abstract: La0.3(Ba0.5Sr0.5)0.7Co0.8Fe0.2O3−δ is a promising bifunctional perovskite catalyst for the oxygen reduction reaction and the oxygen evolution reaction. This catalyst has circa 10 nm-scale rhombohedral LaCoO3 cobaltite particles distributed on the surface. The dynamic microstructure phenomena are attributed to the charge imbalance from the replacement of A-site cations with La3+ and local stress on Co-site sub-lattice with the cubic perovskite structure.

309 citations

Journal ArticleDOI
TL;DR: It is shown that the structural distortions of the perovskite lattice can determine the defectivity of the material by modulating the defect formation energies.
Abstract: Only a selected group of two-dimensional (2D) lead–halide perovskites shows a peculiar broad-band photoluminescence. Here we show that the structural distortions of the perovskite lattice can determine the defectivity of the material by modulating the defect formation energies. By selecting and comparing two archetype systems, namely, (NBT)2PbI4 and (EDBE)PbI4 perovskites (NBT = n-butylammonium and EDBE = 2,2-(ethylenedioxy)bis(ethylammonium)), we find that only the latter, subject to larger deformation of the Pb–X bond length and X–Pb–X bond angles, sees the formation of VF color centers whose radiative decay ultimately leads to broadened PL. These findings highlight the importance of structural engineering to control the optoelectronic properties of this class of soft materials.

309 citations


Network Information
Related Topics (5)
Amorphous solid
117K papers, 2.2M citations
93% related
Oxide
213.4K papers, 3.6M citations
93% related
Thin film
275.5K papers, 4.5M citations
93% related
Graphene
144.5K papers, 4.9M citations
92% related
Raman spectroscopy
122.6K papers, 2.8M citations
91% related
Performance
Metrics
No. of papers in the topic in previous years
YearPapers
20235,193
20229,857
20216,144
20205,859
20195,498
20184,741