Showing papers on "Phase transition published in 2016"
TL;DR: Three-dimensional self-bound quantum droplets of magnetic atoms of ultracold atoms are observed in a trap-free levitation field and it is found that this dilute magnetic quantum liquid requires a minimum, critical number of atoms, below which the liquid evaporates into an expanding gas as a result of the quantum pressure of the individual constituents.
Abstract: Self-bound many-body systems are formed through a balance of attractive and repulsive forces and occur in many physical scenarios. Liquid droplets are an example of a self-bound system, formed by a balance of the mutual attractive and repulsive forces that derive from different components of the inter-particle potential. It has been suggested that self-bound ensembles of ultracold atoms should exist for atom number densities that are 108 times lower than in a helium droplet, which is formed from a dense quantum liquid. However, such ensembles have been elusive up to now because they require forces other than the usual zero-range contact interaction, which is either attractive or repulsive but never both. On the basis of the recent finding that an unstable bosonic dipolar gas can be stabilized by a repulsive many-body term, it was predicted that three-dimensional self-bound quantum droplets of magnetic atoms should exist. Here we report the observation of such droplets in a trap-free levitation field. We find that this dilute magnetic quantum liquid requires a minimum, critical number of atoms, below which the liquid evaporates into an expanding gas as a result of the quantum pressure of the individual constituents. Consequently, around this critical atom number we observe an interaction-driven phase transition between a gas and a self-bound liquid in the quantum degenerate regime with ultracold atoms. These droplets are the dilute counterpart of strongly correlated self-bound systems such as atomic nuclei and helium droplets.
459 citations
TL;DR: TheFerroelectricity in monolayer group-IV monochalcogenides MX is found to be robust and the corresponding Curie temperatures are higher than room temperature, making them promising for realizing ultrathin ferroelectric devices of broad interest.
Abstract: Ferroelectricity usually fades away as materials are thinned down below a critical value. We reveal that the unique ionic-potential anharmonicity can induce spontaneous in-plane electrical polarization and ferroelectricity in monolayer group-IV monochalcogenides $MX$ ($M=\mathrm{Ge}$, Sn; $X=\mathrm{S}$, Se). An effective Hamiltonian has been successfully extracted from the parametrized energy space, making it possible to study the ferroelectric phase transitions in a single-atom layer. The ferroelectricity in these materials is found to be robust and the corresponding Curie temperatures are higher than room temperature, making them promising for realizing ultrathin ferroelectric devices of broad interest. We further provide the phase diagram and predict other potentially two-dimensional ferroelectric materials.
433 citations
TL;DR: It is demonstrated that the phase transition was in fact first-order, although still very close to tricritical, according to the variation of the order parameter Q for this transition scaled with temperature T as Q ∼ (Tc−T)β.
Abstract: We have examined the crystal structures and structural phase transitions of the deuterated, partially deuterated and hydrogenous organic-inorganic hybrid perovskite methyl ammonium lead iodide (MAPbI3) using time-of-flight neutron and synchrotron X-ray powder diffraction. Near 330 K the high temperature cubic phases transformed to a body-centered tetragonal phase. The variation of the order parameter Q for this transition scaled with temperature T as Q ∼ (Tc−T)β, where Tc is the critical temperature and the exponent β was close to ¼, as predicted for a tricritical phase transition. However, we also observed coexistence of the cubic and tetragonal phases over a range of temperature in all cases, demonstrating that the phase transition was in fact first-order, although still very close to tricritical. Upon cooling further, all the tetragonal phases transformed into a low temperature orthorhombic phase around 160 K, again via a first-order phase transition. Based upon these results, we discuss the impact of the structural phase transitions upon photovoltaic performance of MAPbI3 based solar cells.
433 citations
TL;DR: This review summarizes recent developments in molecular ferroelectrics since 2011 and focuses on the relationship between symmetry breaking and ferroelectricity, offering ideas for exploring high-performance molecular ferryelectrics.
Abstract: Ferroelectrics are inseparable from symmetry breaking. Accompanying the paraelectric-to-ferroelectric phase transition, the paraelectric phase adopting one of the 32 crystallographic point groups is broken into subgroups belonging to one of the 10 ferroelectric point groups, i.e. C1, C2, C1h, C2v, C4, C4v, C3, C3v, C6 and C6v. The symmetry breaking is captured by the order parameter known as spontaneous polarization, whose switching under an external electric field results in a typical ferroelectric hysteresis loop. In addition, the responses of spontaneous polarization to other external excitations are related to a number of physical effects such as second-harmonic generation, piezoelectricity, pyroelectricity and dielectric properties. Based on these, this review summarizes recent developments in molecular ferroelectrics since 2011 and focuses on the relationship between symmetry breaking and ferroelectricity, offering ideas for exploring high-performance molecular ferroelectrics.
428 citations
TL;DR: In this article, temperature resolved UV-vis absorption and spectral photocurrent response measurements of MAPbI3 thin films and solar cells, together with ab initio simulations, were used to investigate the changes in material properties occurring across the tetragonal to cubic phase transition.
Abstract: We report temperature resolved UV-vis absorption and spectral photocurrent response measurements of MAPbI3 thin films and solar cells, together with ab initio simulations, to investigate the changes in material properties occurring across the tetragonal to cubic phase transition. We find that the MAPbI3 band-gap does not abruptly change when exceeding the tetragonal to cubic transition temperature, but it rather monotonically blue-shifts following the same temperature evolution observed within the tetragonal phase. Car–Parrinello molecular dynamics simulations demonstrate that the high temperature phase corresponds on average to the expected symmetric cubic structure assigned from XRD measurements, but that the system strongly deviates from such a structure in the sub-picosecond time scale. Thus, on the time scale of electronic transitions, the material seldom experiences a cubic environment, rather an increasingly distorted tetragonal one. This result explains the absence of dramatic changes in the optical of MAPbI3 across the explored temperature range of 270–420 K, which could have important consequences for the practical uptake of perovskite solar cells.
419 citations
TL;DR: The demonstrated strain-modulation of the phase transition temperature is expected to be compatible with other T MDs enabling the 2D electronics utilizing polymorphism of TMDs along with the established materials.
Abstract: We demonstrate a room temperature semiconductor–metal transition in thin film MoTe2 engineered by strain. Reduction of the 2H-1T′ phase transition temperature of MoTe2 to room temperature was realized by introducing a tensile strain of 0.2%. The observed first-order SM transition improved conductance ∼10 000 times and was made possible by an unusually large temperature-stress coefficient, which results from a large volume change and small latent heat. The demonstrated strain-modulation of the phase transition temperature is expected to be compatible with other TMDs enabling the 2D electronics utilizing polymorphism of TMDs along with the established materials.
400 citations
TL;DR: 1T-TiSe2 single crystals with thicknesses of 10 nanometres or less, encapsulated in two-dimensional layers of hexagonal boron nitride, are studied to achieve unprecedented control over the CDW transition temperature, and over the superconductivity transition temperature.
Abstract: To understand the complex physics of a system with strong electron-electron interactions, the ideal is to control and monitor its properties while tuning an external electric field applied to the system (the electric-field effect). Indeed, complete electric-field control of many-body states in strongly correlated electron systems is fundamental to the next generation of condensed matter research and devices. However, the material must be thin enough to avoid shielding of the electric field in the bulk material. Two-dimensional materials do not experience electrical screening, and their charge-carrier density can be controlled by gating. Octahedral titanium diselenide (1T-TiSe2) is a prototypical two-dimensional material that reveals a charge-density wave (CDW) and superconductivity in its phase diagram, presenting several similarities with other layered systems such as copper oxides, iron pnictides, and crystals of rare-earth elements and actinide atoms. By studying 1T-TiSe2 single crystals with thicknesses of 10 nanometres or less, encapsulated in two-dimensional layers of hexagonal boron nitride, we achieve unprecedented control over the CDW transition temperature (tuned from 170 kelvin to 40 kelvin), and over the superconductivity transition temperature (tuned from a quantum critical point at 0 kelvin up to 3 kelvin). Electrically driving TiSe2 over different ordered electronic phases allows us to study the details of the phase transitions between many-body states. Observations of periodic oscillations of magnetoresistance induced by the Little-Parks effect show that the appearance of superconductivity is directly correlated with the spatial texturing of the amplitude and phase of the superconductivity order parameter, corresponding to a two-dimensional matrix of superconductivity. We infer that this superconductivity matrix is supported by a matrix of incommensurate CDW states embedded in the commensurate CDW states. Our results show that spatially modulated electronic states are fundamental to the appearance of two-dimensional superconductivity.
365 citations
TL;DR: It is shown that the semiconductor-to-semimetal phase transition in monolayer MoTe2 can be driven by a gate voltage of several volts with appropriate choice of dielectric, and the transition gate voltage can be reduced arbitrarily by alloying, for example, for MoxW1−xTe2 monolayers.
Abstract: Dynamic control of conductivity and optical properties via atomic structure changes is of technological importance in information storage. Energy consumption considerations provide a driving force towards employing thin materials in devices. Monolayer transition metal dichalcogenides are nearly atomically thin materials that can exist in multiple crystal structures, each with distinct electrical properties. By developing new density functional-based methods, we discover that electrostatic gating device configurations have the potential to drive structural semiconductor-to-semimetal phase transitions in some monolayer transition metal dichalcogenides. Here we show that the semiconductor-to-semimetal phase transition in monolayer MoTe2 can be driven by a gate voltage of several volts with appropriate choice of dielectric. We find that the transition gate voltage can be reduced arbitrarily by alloying, for example, for Mo(x)W(1-x)Te2 monolayers. Our findings identify a new physical mechanism, not existing in bulk materials, to dynamically control structural phase transitions in two-dimensional materials, enabling potential applications in phase-change electronic devices.
318 citations
TL;DR: In this article, the phase structure and phase transitions of hadronic matter in strong magnetic fields B and zero quark chemical potentials µf are discussed. But the authors focus on inverse magnetic catalysis around the transition temperature Tc as a competition between contributions from valence quarks and sea quarks.
Abstract: We review in detail recent advances in our understanding of the phase structure and the phase transitions of hadronic matter in strong magnetic fields B and zero quark chemical potentials µf. Many aspects of QCD are described using low-energy effective theories and models such as the MIT bag model, the hadron resonance gas model, chiral perturbation theory, the Nambu-Jona-Lasinio (NJL) model, the quark-meson (QM) model and Polyakov-loop extended versions of the NJL and QM models. We critically examine their properties and applications. This includes mean-field calculations as well as approaches beyond the mean-field approximation such as the functional renormalization group (FRG). Renormalization issues are discussed and the influence of the vacuum fluctuations on the chiral phase transition is pointed out. Magnetic catalysis at T = 0 is covered as well. We discuss recent lattice results for the thermodynamics of nonabelian gauge theories with emphasis on SU(2)c and SU(3)c. In particular, we focus on inverse magnetic catalysis around the transition temperature Tc as a competition between contributions from valence quarks and sea quarks resulting in a decrease of Tc as a function of B. Finally, we discuss recent efforts to modify models in order to reproduce the behavior observed on the lattice.
290 citations
TL;DR: In this article, the first observation of a DPT in the dynamics of a fermionic many-body state after a quench between two lattice Hamiltonians was reported.
Abstract: Phase transitions are a fundamental concept in science describing diverse phenomena ranging from, e.g., the freezing of water to Bose-Einstein condensation. While the concept is well-established in equilibrium, similarly fundamental concepts for systems far from equilibrium are just being explored, such as the recently introduced dynamical phase transition (DPT). Here we report on the first observation of a DPT in the dynamics of a fermionic many-body state after a quench between two lattice Hamiltonians. With time-resolved state tomography in a system of ultracold atoms in optical lattices, we obtain full access to the evolution of the wave function. We observe the appearance, movement, and annihilation of vortices in reciprocal space. We identify their number as a dynamical topological order parameter, which suddenly changes its value at the critical times of the DPT. Our observation of a DPT is an important step towards a more comprehensive understanding of non-equilibrium dynamics in general.
279 citations
TL;DR: In this article, an electricallyenhanced diffused polymorphic phase transition (EED-PPT) contributed to the boosted thermal stability of KNN based lead-free piezoceramics with high piezoelectricity.
Abstract: High piezoelectricity of (K,Na)NbO3 (KNN) lead-free materials benefits from a polymorphic phase transition (PPT) around room temperature, but its temperature sensitivity has been a bottleneck impeding their applications. We find that good thermal stability can be achieved in CaZrO3-modified KNN lead-free piezoceramics, in which the normalized strain d33* almost keeps constant from room temperature up to 140 oC. In situ synchrotron X-ray diffraction experiments combined with permitivity measurements disclose the occurrence of a new phase transformation under an electrical field, which extends the transition range between tetragonal and orthorhombic phases. It is revealed that such an electrically-enhanced diffused polymorphic phase transition (EED-PPT) contributed to the boosted thermal stability of KNN based lead-free piezoceramics with high piezoelectricity. The present approach based on phase engineering should also be effective in endowing other lead-free piezoelectrics with high piezoelectricity and good temperature stability.
TL;DR: The potential of polariton graphs are investigated as an efficient analogue simulator for finding the global minimum of the XY model and provide a route to study unconventional superfluids, spin liquids, Berezinskii-Kosterlitz-Thouless phase transition, and classical magnetism, among the many systems described by the XY Hamiltonian.
Abstract: Several platforms are currently being explored for simulating physical systems whose complexity increases faster than polynomially with the number of particles or degrees of freedom in the system. Defects and vacancies in semiconductors or dielectric materials, magnetic impurities embedded in solid helium \cite{lemeshko13}, atoms in optical lattices, photons, trapped ions and superconducting q-bits are among the candidates for predicting the behaviour of spin glasses, spin-liquids, and classical magnetism among other phenomena with practical technological applications. Here we investigate the potential of polariton graphs as an efficient simulator for finding the global minimum of the $XY$ Hamiltonian. By imprinting polariton condensate lattices of bespoke geometries we show that we can simulate a large variety of systems undergoing the U(1) symmetry breaking transitions. We realise various magnetic phases, such as ferromagnetic, anti-ferromagnetic, and frustrated spin configurations on unit cells of various lattices: square, triangular, linear and a disordered graph. Our results provide a route to study unconventional superfluids, spin-liquids, Berezinskii-Kosterlitz-Thouless phase transition, classical magnetism among the many systems that are described by the $XY$ Hamiltonian.
TL;DR: It is shown that the surface TSC phase only exists up to a certain bulk pairing gap, and there is a normal-topological phase transition driven by the temperature, which has not been discussed before.
Abstract: As one of the simplest systems for realizing Majorana fermions, the topological superconductor plays an important role in both condensed matter physics and quantum computations. Based on ab initio calculations and the analysis of an effective 8-band model with superconducting pairing, we demonstrate that the three-dimensional extended s-wave Fe-based superconductors such as Fe_{1+y}Se_{0.5}Te_{0.5} have a metallic topologically nontrivial band structure, and exhibit a normal-topological-normal superconductivity phase transition on the (001) surface by tuning the bulk carrier doping level. In the topological superconductivity (TSC) phase, a Majorana zero mode is trapped at the end of a magnetic vortex line. We further show that the surface TSC phase only exists up to a certain bulk pairing gap, and there is a normal-topological phase transition driven by the temperature, which has not been discussed before. These results pave an effective way to realize the TSC and Majorana fermions in a large class of superconductors.
TL;DR: In this article, the average unit cell volume is seen to increase with increasing DC field and has been interpreted in terms of increasing levels of structural disorder in the system, where the structure becomes ferroelectric with high polarization.
Abstract: Solid-state dielectric energy storage is the most attractive and feasible way to store and release high power energy compared to chemical batteries and electrochemical super-capacitors. However, the low energy density (ca. 1 J cm−3) of commercial dielectric capacitors has limited their development. Dielectric materials showing field induced reversible phase transitions have great potential to break the energy storage density bottleneck. In this work, dense AgNbO3 ceramic samples were prepared successfully using solid state methods. Ferroelectric measurements at different temperatures reveal evidence of two kinds of polar regions. One of these is stable up to 70 °C, while the other remains stable up to 170 °C. The associated transition temperatures are supported by second harmonic generation measurements on poled samples and are correlated with the occurrence of two sharp dielectric responses. The average unit cell volume is seen to increase with increasing DC field and has been interpreted in terms of increasing levels of structural disorder in the system. At a high electric field the structure becomes ferroelectric with high polarization. This field induced transition exhibits a recoverable energy density of 2.1 J cm−3, which represents one of the highest known values for lead-free bulk ceramics.
TL;DR: In this paper, a high-frequency expansion for periodically driven quantum systems based on the Brillouin-Wigner perturbation theory was constructed, which generates an effective Hamiltonian on the projected zero-photon subspace in the Floquet theory, reproducing the quasienergies and eigenstates of the original Floquet Hamiltonian up to desired order in $1/ √ √ ϵ, with ϵ being the frequency of the drive.
Abstract: We construct a systematic high-frequency expansion for periodically driven quantum systems based on the Brillouin-Wigner (BW) perturbation theory, which generates an effective Hamiltonian on the projected zero-photon subspace in the Floquet theory, reproducing the quasienergies and eigenstates of the original Floquet Hamiltonian up to desired order in $1/\ensuremath{\omega}$, with $\ensuremath{\omega}$ being the frequency of the drive. The advantage of the BW method is that it is not only efficient in deriving higher-order terms, but even enables us to write down the whole infinite series expansion, as compared to the van Vleck degenerate perturbation theory. The expansion is also free from a spurious dependence on the driving phase, which has been an obstacle in the Floquet-Magnus expansion. We apply the BW expansion to various models of noninteracting electrons driven by circularly polarized light. As the amplitude of the light is increased, the system undergoes a series of Floquet topological-to-topological phase transitions, whose phase boundary in the high-frequency regime is well explained by the BW expansion. As the frequency is lowered, the high-frequency expansion breaks down at some point due to band touching with nonzero-photon sectors, where we find numerically even more intricate and richer Floquet topological phases spring out. We have then analyzed, with the Floquet dynamical mean-field theory, the effects of electron-electron interaction and energy dissipation. We have specifically revealed that phase transitions from Floquet-topological to Mott insulators emerge, where the phase boundaries can again be captured with the high-frequency expansion.
TL;DR: It is discovered that the nature of the new phase is dictated by the stacking order, and the results shed fresh light on the origin of the Mott phase in 1T-TaS2.
Abstract: Electron-electron and electron-phonon interactions are two major driving forces that stabilize various charge-ordered phases of matter. In layered compound 1T-TaS2, the intricate interplay between the two generates a Mott-insulating ground state with a peculiar charge-density-wave (CDW) order. The delicate balance also makes it possible to use external perturbations to create and manipulate novel phases in this material. Here, we study a mosaic CDW phase induced by voltage pulses, and find that the new phase exhibits electronic structures entirely different from that of the original Mott ground state. The mosaic phase consists of nanometre-sized domains characterized by well-defined phase shifts of the CDW order parameter in the topmost layer, and by altered stacking relative to the layers underneath. We discover that the nature of the new phase is dictated by the stacking order, and our results shed fresh light on the origin of the Mott phase in 1T-TaS2.
Fudan University1, Chinese Academy of Sciences2, Forschungszentrum Jülich3, European Synchrotron Radiation Facility4, Fayoum University5, Russian Academy of Sciences6, National University of Science and Technology7, Ural Federal University8, Moscow State University9, Centre national de la recherche scientifique10, Oak Ridge National Laboratory11
TL;DR: The results support recent theoretical proposals that both nematicity and superconductivity are driven by spin fluctuations.
Abstract: In iron-based superconductors the interactions driving the nematic order (that breaks four-fold rotational symmetry in the iron plane) may also mediate the Cooper pairing. The experimental determination of these interactions, which are believed to depend on the orbital or the spin degrees of freedom, is challenging because nematic order occurs at, or slightly above, the ordering temperature of a stripe magnetic phase. Here, we study FeSe (ref. )-which exhibits a nematic (orthorhombic) phase transition at Ts = 90 K without antiferromagnetic ordering-by neutron scattering, finding substantial stripe spin fluctuations coupled with the nematicity that are enhanced abruptly on cooling through Ts. A sharp spin resonance develops in the superconducting state, whose energy (∼4 meV) is consistent with an electron-boson coupling mode revealed by scanning tunnelling spectroscopy. The magnetic spectral weight in FeSe is found to be comparable to that of the iron arsenides. Our results support recent theoretical proposals that both nematicity and superconductivity are driven by spin fluctuations.
TL;DR: A systematic investigation of the size-dependent orthorhombic-to-tetragonal phase transition in perovskite using a combined temperature-dependent optical, electrical transport and transmission electron microscopy study finds that the phase transition temperature decreases with reducing microplate thickness.
Abstract: Methylammonium lead iodide perovskite has attracted considerable recent interest for solution processable solar cells and other optoelectronic applications. The orthorhombic-to-tetragonal phase transition in perovskite can significantly alter its optical, electrical properties and impact the corresponding applications. Here, we report a systematic investigation of the size-dependent orthorhombic-to-tetragonal phase transition using a combined temperature-dependent optical, electrical transport and transmission electron microscopy study. Our studies of individual perovskite microplates with variable thicknesses demonstrate that the phase transition temperature decreases with reducing microplate thickness. The sudden decrease of mobility around phase transition temperature and the presence of hysteresis loops in the temperature-dependent mobility confirm that the orthorhombic-to-tetragonal phase transition is a first-order phase transition. Our findings offer significant fundamental insight on the temperature- and size-dependent structural, optical and charge transport properties of perovskite materials, and can greatly impact future exploration of novel electronic and optoelectronic devices from these materials.
TL;DR: Transmission electron microscopy studies reveal that the interconnected MoS2 nanocrystals created during the phase change process are reformable even after multiple cycles of galvanostatic charging/discharging, which allows them to play important roles in the long term cycling performance of the chemically intercalated TMD materials.
Abstract: Achieving homogeneous phase transition and uniform charge distribution is essential for good cycle stability and high capacity when phase conversion materials are used as electrodes. Herein, we show that chemical lithiation of bulk 2H-MoS2 distorts its crystalline domains in three primary directions to produce mosaic-like 1T′ nanocrystalline domains, which improve phase and charge uniformity during subsequent electrochemical phase conversion. 1T′-LixMoS2, a macroscopic dense material with interconnected nanoscale grains, shows excellent cycle stability and rate capability in a lithium rechargeable battery compared to bulk or exfoliated-restacked MoS2. Transmission electron microscopy studies reveal that the interconnected MoS2 nanocrystals created during the phase change process are reformable even after multiple cycles of galvanostatic charging/discharging, which allows them to play important roles in the long term cycling performance of the chemically intercalated TMD materials. These studies shed light...
TL;DR: In this article, it was shown that the onset of turbulence is a second-order phase transition and falls into the directed percolation universality class, and that the complex laminar-turbulent patterns distinctive for the onset time of turbulence in basic shear flows are characterized by universal critical exponents.
Abstract: Decades-old speculation that the transition to turbulence belongs to the directed percolation universality class is confirmed with experimental and numerical data for flow through a quasi-one-dimensional Couette geometry. Turbulence is one of the most frequently encountered non-equilibrium phenomena in nature, yet characterizing the transition that gives rise to turbulence in basic shear flows has remained an elusive task. Although, in recent studies, critical points marking the onset of sustained turbulence1,2,3 have been determined for several such flows, the physical nature of the transition could not be fully explained. In extensive experimental and computational studies we show for the example of Couette flow that the onset of turbulence is a second-order phase transition and falls into the directed percolation universality class. Consequently, the complex laminar–turbulent patterns distinctive for the onset of turbulence in shear flows4,5 result from short-range interactions of turbulent domains and are characterized by universal critical exponents. More generally, our study demonstrates that even high-dimensional systems far from equilibrium such as turbulence exhibit universality at onset and that here the collective dynamics obeys simple rules.
TL;DR: Observations suggest that the present system can be considered as a potential lead-free material for the applications in electrostrictive area and that BT-based ferroelectric ceramics would have giant electroStrictive coefficient over other ferro electric systems.
Abstract: The electrostrictive effect has some advantages over the piezoelectric effect, including temperature stability and hysteresis-free character. In the present work, we report the diffuse phase transitions and electrostrictive properties in lead-free Fe3+-doped 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 (BZT-0.5BCT) ferroelectric ceramics. The doping concentration was set from 0.25 to 2 mol %. It is found that by introducing Fe3+ ion into BZT-0.5BCT, the temperature corresponding to permittivity maximum Tm was shifted toward lower temperature monotonically by 37 °C per mol % Fe3+ ion. Simultaneously, the phase transitions gradually changed from classical ferroelectric-to-paraelectric phase transitions into diffuse phase transitions with a weak relaxor characteristic. Purely electrostrictive responses with giant electrostrictive coefficient Q33 between 0.04 and 0.05 m4/C2 are observed from 25 to 100 °C for the compositions doped with 1–2 mol % Fe3+ ion. The Q33 of Fe3+-doped BZT-0.5BCT ceramics is almost twice t...
TL;DR: In this paper, a one-dimensional chain of 72 microwave cavities, coupled to a superconducting qubit, was used to coherently drive the system into a nonequilibrium steady state.
Abstract: Condensed matter physics has been driven forward by significant experimental and theoretical progress in the study and understanding of equilibrium phase transitions based on symmetry and topology. However, nonequilibrium phase transitions have remained a challenge, in part due to their complexity in theoretical descriptions and the additional experimental difficulties in systematically controlling systems out of equilibrium. Here, we study a one-dimensional chain of 72 microwave cavities, each coupled to a superconducting qubit, and coherently drive the system into a nonequilibrium steady state. We find experimental evidence for a dissipative phase transition in the system in which the steady state changes dramatically as the mean photon number is increased. Near the boundary between the two observed phases, the system demonstrates bistability, with characteristic switching times as long as 60 ms -- far longer than any of the intrinsic rates known for the system. This experiment demonstrates the power of circuit QED systems for studying nonequilibrium condensed matter physics and paves the way for future experiments exploring nonequilbrium physics with many-body quantum optics.
TL;DR: This work demonstrates room-temperature current switching driven by a voltage-controlled phase transition between CDW states in films of 1T-TaS2 less than 10 nm thick, and exploits the transition between the nearly commensurate and the incommensurate CDW phases.
Abstract: A graphene transistor integrated on-chip on a hexagonal boron nitride-capped TaS2 layer provides a voltage-tunable, low-resistance load for controlling a TaS2 metal–insulator transition, enabling a compact voltage-controlled oscillator operating at room temperature. The charge-density-wave (CDW) phase is a macroscopic quantum state consisting of a periodic modulation of the electronic charge density accompanied by a periodic distortion of the atomic lattice in quasi-1D or layered 2D metallic crystals1,2,3,4. Several layered transition metal dichalcogenides, including 1T-TaSe2, 1T-TaS2 and 1T-TiSe2 exhibit unusually high transition temperatures to different CDW symmetry-reducing phases1,5,6. These transitions can be affected by the environmental conditions, film thickness and applied electric bias1. However, device applications of these intriguing systems at room temperature or their integration with other 2D materials have not been explored. Here, we demonstrate room-temperature current switching driven by a voltage-controlled phase transition between CDW states in films of 1T-TaS2 less than 10 nm thick. We exploit the transition between the nearly commensurate and the incommensurate CDW phases, which has a transition temperature of 350 K and gives an abrupt change in current accompanied by hysteresis. An integrated graphene transistor provides a voltage-tunable, matched, low-resistance load enabling precise voltage control of the circuit. The 1T-TaS2 film is capped with hexagonal boron nitride to provide protection from oxidation. The integration of these three disparate 2D materials in a way that exploits the unique properties of each yields a simple, miniaturized, voltage-controlled oscillator suitable for a variety of practical applications.
TL;DR: A complementary extended molecular field theory was found to be in suggestive accord with the (2)H-NMR studies of CB6OCB-d2, and those already known for CB7CB-d4, including the reduced transition temperature, TNTBN/TNI, and the order parameter of the mesogenic arms in the N phase close to the NTB-N transition.
Abstract: The synthesis and characterisation of the nonsymmetric liquid crystal dimer, 1-(4-cyanobiphenyl-4'-yloxy)-6-(4-cyanobiphenyl-4'-yl)hexane (CB6OCB) is reported. An enantiotropic nematic (N)-twist-bend nematic (NTB) phase transition is observed at 109 °C and a nematic-isotropic phase transition at 153 °C. The NTB phase assignment has been confirmed using polarised light microscopy, freeze fracture transmission electron microscopy (FFTEM), (2)H-NMR spectroscopy, and X-ray diffraction. The effective molecular length in both the NTB and N phases indicates a locally intercalated arrangement of the molecules, and the helicoidal pitch length in the NTB phase is estimated to be 8.9 nm. The surface anchoring properties of CB6OCB on a number of aligning layers is reported. A Landau model is applied to describe high-resolution heat capacity measurements in the vicinity of the NTB-N phase transition. Both the theory and heat capacity measurements agree with a very weak first-order phase transition. A complementary extended molecular field theory was found to be in suggestive accord with the (2)H-NMR studies of CB6OCB-d2, and those already known for CB7CB-d4. These include the reduced transition temperature, TNTBN/TNI, the order parameter of the mesogenic arms in the N phase close to the NTB-N transition, and the order parameter with respect to the helix axis which is related to the conical angle for the NTB phase.
TL;DR: In this paper, first-principles calculations confirm the existence of a potential barrier between the cubic and hexagonal structures, which provides an explanation for the observed thermal hysteresis.
Abstract: A challenge of hybrid perovskite solar cells is device instability, which calls for an understanding of the perovskite structural stability and phase transitions. Using neutron diffraction and first-principles calculations on formamidinium lead iodide (FAPbI3), we show that the entropy contribution to the Gibbs free energy caused by isotropic rotations of the FA+ cation plays a crucial role in the cubic-to-hexagonal structural phase transition. Furthermore, we observe that the cubic-to-hexagonal phase transition exhibits a large thermal hysteresis. Our first-principles calculations confirm the existence of a potential barrier between the cubic and hexagonal structures, which provides an explanation for the observed thermal hysteresis. By exploiting the potential barrier, we demonstrate kinetic trapping of the cubic phase, desirable for solar cells, even at 8.2 K by thermal quenching.
TL;DR: In this paper, the authors studied the thermodynamics of the symmetry restoration phase transition using numerical lattice Monte Carlo simulations of an effective SU(2)×U(1) gauge+Higgs theory, and measured the Higgs field expectation value, thermodynamic quantities like pressure, energy density, speed of sound and heat capacity.
Abstract: With the physical Higgs mass the standard model symmetry restoration phase transition is a smooth cross-over. We study the thermodynamics of the cross-over using numerical lattice Monte Carlo simulations of an effective SU(2)×U(1) gauge+Higgs theory, significantly improving on previously published results. We measure the Higgs field expectation value, thermodynamic quantities like pressure, energy density, speed of sound and heat capacity, and screening masses associated with the Higgs and Z fields. While the cross-over is smooth, it is very well defined with a width of only ∼5 GeV. We measure the cross-over temperature from the maximum of the susceptibility of the Higgs condensate, with the result Tc=159.5±1.5 GeV. Outside of the narrow cross-over region the perturbative results agree well with nonperturbative ones.
TL;DR: A driven-dissipative Josephson junction array realized with a weakly interacting Bose-Einstein condensate residing in a one-dimensional optical lattice is experimentally studied, finding a critical slowing down, indicating the presence of a nonequilibrium phase transition.
Abstract: We experimentally study a driven-dissipative Josephson junction array, realized with a weakly interacting Bose-Einstein condensate residing in a one-dimensional optical lattice. Engineered losses on one site act as a local dissipative process, while tunneling from the neighboring sites constitutes the driving force. We characterize the emerging steady states of this atomtronic device. With increasing dissipation strength γ the system crosses from a superfluid state, characterized by a coherent Josephson current into the lossy site, to a resistive state, characterized by an incoherent hopping transport. For intermediate values of γ, the system exhibits bistability, where a superfluid and an incoherent branch coexist. We also study the relaxation dynamics towards the steady state, where we find a critical slowing down, indicating the presence of a nonequilibrium phase transition.
TL;DR: In this article, the ground state properties of a trapped dipolar condensate under the influence of quantum fluctuations were investigated and it was shown that this system can undergo a phase transition from a low-density Condensate state to a high-density droplet state, which is stabilized by quantum fluctuations.
Abstract: We consider the ground state properties of a trapped dipolar condensate under the influence of quantum fluctuations. We show that this system can undergo a phase transition from a low density condensate state to a high density droplet state, which is stabilized by quantum fluctuations. The energetically favored state depends on the geometry of the confining potential, the number of atoms, and the two-body interactions. We develop a simple variational ansatz and validate it against full numerical solutions. We produce a phase diagram for the system and present results relevant to current experiments with dysprosium and erbium condensates.
TL;DR: In this paper, the cosmological constant is interpreted as thermodynamic pressure and treated as a thermodynamic variable in its own right, whereas the mass of the black hole is identified with the chemical enthalpy.
Abstract: We review recent developments on the thermodynamics of black holes in extended phase space, where the cosmological constant is interpreted as thermodynamic pressure and treated as a thermodynamic variable in its own right. In this approach, the mass of the black hole is no longer regarded as internal energy, rather it is identified with the chemical enthalpy. This leads to an extended dictionary for black hole thermodynamic quantities, in particular a notion of thermodynamic volume emerges for a given black hole spacetime. This volume is conjectured to satisfy the reverse isoperimetric inequality - an inequality imposing a bound on the amount of entropy black hole can carry for a fixed thermodynamic volume. New thermodynamic phase transitions naturally emerge from these identifications. Namely, we show that black holes can be understood from the viewpoint of chemistry, in terms of concepts such as Van der Waals fluids, reentrant phase transitions, and triple points. We also review the recent attempts at extending the AdS/CFT dictionary in this setting, discuss the connections with horizon thermodynamics, applications to Lifshitz spacetimes, and outline possible future directions in this field.
TL;DR: The Schrieffer-Wolff transformation is applied to the periodically driven, strongly interacting Fermi-Hubbard model, for which it is identified two regimes resulting in different effective low-energy Hamiltonians.
Abstract: We generalize the Schrieffer-Wolff transformation to periodically driven systems using Floquet theory. The method is applied to the periodically driven, strongly interacting Fermi-Hubbard model, for which we identify two regimes resulting in different effective low-energy Hamiltonians. In the nonresonant regime, we realize an interacting spin model coupled to a static gauge field with a nonzero flux per plaquette. In the resonant regime, where the Hubbard interaction is a multiple of the driving frequency, we derive an effective Hamiltonian featuring doublon association and dissociation processes. The ground state of this Hamiltonian undergoes a phase transition between an ordered phase and a gapless Luttinger liquid phase. One can tune the system between different phases by changing the amplitude of the periodic drive.