Showing papers on "Phenocryst published in 2022"

Variety of the drift pumice clasts from the 2021 <scp>Fukutoku‐Oka‐no‐Ba</scp> eruption, Japan

Abstract: Pumice rafts that arrived at the Nansei Islands, Japan, provided a unique opportunity to investigate the Fukutoku-Oka-no-Ba (FOB) eruption of August 2021. Despite drifting for 2 months for ~1300 km, the drift pumice raft had a large volume and contained a variety of pumice clasts, some of which were deposited during a high tide in a typhoon, while others were washed up on a sandy beach. Most of the drift pumice clasts are gray in color, vesicular, and have a groundmass containing black enclaves. Rare black pumice and the main gray pumice components have similar trachytic compositions, with SiO2 = 61–62 mass% and total alkalis = 8.6–10 mass% (on an anhydrous basis). Both pumice types contain clinopyroxene, plagioclase, and rare olivine phenocrysts. Thin-section observations show that the gray pumice has more elongated vesicles as compared with the black pumice that has spherical vesicles, even where the two types of pumice are in the same clast. The glass in the black pumice is transparent and brown in color, while that in the gray pumice is colorless. No micro or nano-crystals were observed during electron and optical microscopy. Raman spectra of the brown-colored glass exhibit a clear magnetite peak, suggesting magnetite nanolites cause the brown color. High-Mg olivine in the black pumice has an equilibrium temperature of c. 1200 °C and a rim diffusion profile indicative of re-equilibration with the surrounding melt over a period of hours to days. The textural relationships between the gray and black pumice suggest that the black pumice had become black and viscous before the two types of pumice mixed. Therefore, crystallization of magnetite nanolites and a corresponding increase in melt viscosity were important in the eruption preparation process, which then resulted in a large-scale Plinian eruption.

Generation of the Giant Porphyry Cu-Au Deposit by Repeated Recharge of Mafic Magmas at Pulang in Eastern Tibet

Abstract: The giant Pulang porphyry Cu-Au district (446.8 Mt at 0.52% Cu and 0.18 g/t Au) is located in the Yidun arc, eastern Tibet. The district is hosted in an intrusive complex comprising, in order of emplacement, premineralization fine-grained quartz diorite and coarse-grained quartz diorite, intermineralization quartz monzonite, and late-mineralization diorite porphyry, which were all emplaced at ca. 216 ± 2 Ma. Mafic magmatic enclaves are found in both the coarse-grained quartz diorite and quartz monzonite. The well-preserved primary mineral crystals in such a systematic magma series (including contemporaneous relatively mafic intrusions) with well-defined timing provide an excellent opportunity to investigate upper crustal magma reservoir processes, particularly to test the role of mafic magma recharge in porphyry Cu formation. Two groups of amphibole crystals, with different aluminum contents, are observed in these four rocks. Low-Al amphibole crystals (Аl2О3 = 6.2–7.6 wt %) with crystallization temperatures of ~780°C mainly occur in the coarse-grained quartz diorite and quartz monzonite, whereas high-Al amphibole crystals (Al2O3 = 8.0–13.3 wt %) with crystallization temperatures of ~900°C mainly occur in the fine-grained quartz diorite and diorite porphyry. These characteristics, together with detailed petrographic observations and mineral chemistry studies, indicate that the coarse-grained quartz diorite and quartz monzonite probably formed by crystal fractionation in the same felsic magma reservoir, whereas the fine-grained quartz diorite and diorite porphyry formed from relatively mafic magmas sourced from different magma reservoirs. The occurrence of mafic magmatic enclaves, disequilibrium phenocryst textures, and cumulate clots indicates that the coarse-grained quartz diorite and quartz monzonite evolved in an open crustal magma storage system through a combination of crystal fractionation and repeated mafic magma recharge. Mixing with incoming batches of hotter mafic magma is indicated by the appearance of abundant microtextures, such as reverse zoning (Na andesine core with Ca-rich andesine or labradorite rim overgrowth), sharp zoning (Ca-rich andesine or labradorite core with abrupt rimward anorthite decrease) and patchy core (Ca-rich andesine or labradorite and Na andesine patches) textured plagioclase, zoned amphibole, high-Al amphibole clots, skeletal biotite, and quartz ocelli (mantled quartz xenocrysts). Using available partitioning models for apatite crystals from the coarse-grained quartz diorite, quartz monzonite, and diorite porphyry, we estimated absolute magmatic S contents to be 20–100, 25–130, and >650 ppm, respectively. Estimates of absolute magmatic Cl contents for these three rocks are 1,000 ± 600, 1,800 ± 1,100, and 1,300 ± 1,000 ppm, respectively. The slight increase in both magmatic S and Cl contents from the premineralization coarse-grained quartz diorite magma to intermineralization quartz monzonite magma was probably due to repeated recharge of the relatively mafic diorite porphyry magma with higher S but similar Cl contents. Mass balance constraints on Cu, S, and Cl were used to estimate the minimum volume of magma required to form the Pulang porphyry Cu-Au deposit. Magma volume calculated using Cu mass balance constraints implies that a minimum of 21–36 km3 (median of 27 km3) of magma was required to provide the total of 2.3 Mt of Cu at Pulang. This magma volume can explain the Cl endowment of the deposit but is unlikely to supply the sulfur required. Recharge of 5–11 km3 of diorite porphyry magma to the felsic magma reservoir is adequate to account for the additional 6.5–15 Mt of S required at Pulang. Repeated diorite porphyry magma recharge may have supplied significant amounts of S and some Cl and rejuvenated the porphyry system, thus aiding formation of the large, long-lived magma reservoir that produced the porphyry Cu-Au deposit at Pulang.

Generation of the Giant Porphyry Cu-Au Deposit by Repeated Recharge of Mafic Magmas at Pulang in Eastern Tibet

Abstract: Abstract The giant Pulang porphyry Cu-Au district (446.8 Mt at 0.52% Cu and 0.18 g/t Au) is located in the Yidun arc, eastern Tibet. The district is hosted in an intrusive complex comprising, in order of emplacement, premineralization fine-grained quartz diorite and coarse-grained quartz diorite, intermineralization quartz monzonite, and late-mineralization diorite porphyry, which were all emplaced at ca. 216 ± 2 Ma. Mafic magmatic enclaves are found in both the coarse-grained quartz diorite and quartz monzonite. The well-preserved primary mineral crystals in such a systematic magma series (including contemporaneous relatively mafic intrusions) with well-defined timing provide an excellent opportunity to investigate upper crustal magma reservoir processes, particularly to test the role of mafic magma recharge in porphyry Cu formation. Two groups of amphibole crystals, with different aluminum contents, are observed in these four rocks. Low-Al amphibole crystals (Аl2О3 = 6.2–7.6 wt %) with crystallization temperatures of ~780°C mainly occur in the coarse-grained quartz diorite and quartz monzonite, whereas high-Al amphibole crystals (Al2O3 = 8.0–13.3 wt %) with crystallization temperatures of ~900°C mainly occur in the fine-grained quartz diorite and diorite porphyry. These characteristics, together with detailed petrographic observations and mineral chemistry studies, indicate that the coarse-grained quartz diorite and quartz monzonite probably formed by crystal fractionation in the same felsic magma reservoir, whereas the fine-grained quartz diorite and diorite porphyry formed from relatively mafic magmas sourced from different magma reservoirs. The occurrence of mafic magmatic enclaves, disequilibrium phenocryst textures, and cumulate clots indicates that the coarse-grained quartz diorite and quartz monzonite evolved in an open crustal magma storage system through a combination of crystal fractionation and repeated mafic magma recharge. Mixing with incoming batches of hotter mafic magma is indicated by the appearance of abundant microtextures, such as reverse zoning (Na andesine core with Ca-rich andesine or labradorite rim overgrowth), sharp zoning (Ca-rich andesine or labradorite core with abrupt rimward anorthite decrease) and patchy core (Ca-rich andesine or labradorite and Na andesine patches) textured plagioclase, zoned amphibole, high-Al amphibole clots, skeletal biotite, and quartz ocelli (mantled quartz xenocrysts). Using available partitioning models for apatite crystals from the coarse-grained quartz diorite, quartz monzonite, and diorite porphyry, we estimated absolute magmatic S contents to be 20–100, 25–130, and &gt;650 ppm, respectively. Estimates of absolute magmatic Cl contents for these three rocks are 1,000 ± 600, 1,800 ± 1,100, and 1,300 ± 1,000 ppm, respectively. The slight increase in both magmatic S and Cl contents from the premineralization coarse-grained quartz diorite magma to intermineralization quartz monzonite magma was probably due to repeated recharge of the relatively mafic diorite porphyry magma with higher S but similar Cl contents. Mass balance constraints on Cu, S, and Cl were used to estimate the minimum volume of magma required to form the Pulang porphyry Cu-Au deposit. Magma volume calculated using Cu mass balance constraints implies that a minimum of 21–36 km3 (median of 27 km3) of magma was required to provide the total of 2.3 Mt of Cu at Pulang. This magma volume can explain the Cl endowment of the deposit but is unlikely to supply the sulfur required. Recharge of 5–11 km3 of diorite porphyry magma to the felsic magma reservoir is adequate to account for the additional 6.5–15 Mt of S required at Pulang. Repeated diorite porphyry magma recharge may have supplied significant amounts of S and some Cl and rejuvenated the porphyry system, thus aiding formation of the large, long-lived magma reservoir that produced the porphyry Cu-Au deposit at Pulang.

Genetic relationship between subduction of slab topographic anomalies and porphyry deposit formation: Insight from the source and evolution of Rio Blanco magmas

Abstract: The Rio Blanco deposit, which is one of the largest porphyry Cu-Mo deposits in northern Peru, formed coevally with the subduction of the Inca Oceanic Plateau at 12–10 Ma. However, the genetic relationship between the subduction of oceanic plateaus and the porphyry deposit formation remains unclear. Igneous rocks emplaced at 23–12 Ma in northern Peru, including the Portachuela batholith (which hosts the Rio Blanco porphyry complex), are normal calc-alkaline to weakly adakitic. In comparison, the 12–8 Ma igneous rocks, including the ore-related Rio Blanco porphyry complex, have typical adakitic signatures, such as high Sr/Y ratios (up to 180) and LaN/YbN ratios (up to 32). The Rio Blanco igneous rocks (Portachuela batholith and Rio Blanco porphyry complex) have uniform zircon εHf(t) values (+0.3 ± 1.2) and δ18O values (6.5 ± 0.14‰). These geochemical characteristics indicate that the Rio Blanco igneous rocks evolved from mantle-derived parental melts in a long-lived, stable, homogeneous isotopic reservoir at the crust–mantle boundary. However, whereas both the Portachuela batholith and the Rio Blanco porphyry complex formed from hydrous parental magmas (>5 wt %; based on plagioclase hygrometry), the ones of the Rio Blanco porphyry complex seem to be more oxidized compared with the older batholitic rocks. Reverse zoning in plagioclase phenocrysts, with a systematic core–mantle–rim variation in An (anorthite) and Fe (total iron) contents, are common in the intermineralization rocks. The An content of the mantles of the plagioclase phenocrysts correlates positively with the Fe content, but in the rims, the An contents significantly decrease while Fe remains constant. The apatite inclusions in the mantles are richer in S (0.24 ± 0.06 wt %) and Cl (1.42 ± 0.32 wt %) than those in the phenocryst cores (S: 0.09 ± 0.07 wt % and Cl: 1.03 ± 0.56 wt %) and rims (S: 0.14 ± 0.09 wt % and Cl: 0.83 ± 0. 35 wt %). These systemic geochemical variations in the plagioclase phenocrysts suggest recharge by S- and Cl-rich melts followed by fluid exsolution. This magma recharge and subsequent fluid exsolution may have triggered porphyry Cu mineralization at Rio Blanco. The coincidence of timing between the geochemical transition and collision (initial subduction) of the Inca Oceanic Plateau with the South American plate may indicate a change in the tectonic regime to a compressional state of stress and a thickening of the crust during the collision. The tectonic transition would have facilitated the fractionation of mantle-derived magma in a deep crustal hot zone, resulting in oxidized, volatile-rich residual melts. Replenishment of the upper-crustal magma chamber by such volatile-rich magmas and the subsequent discharge of fluids are interpreted to be fundamental for porphyry Cu mineralization at Rio Blanco and plausibly for the formation of Late Miocene porphyry ore deposits in northern Peru in general.

Petrographic characteristics in the pumice clast deposited along the Gulf of Thailand, drifted from Fukutoku-Oka-no-Ba

Abstract: The 2021 eruption of Fukutoku-Oka-no-Ba (FOB) in the northwest Pacific on 13 August 2021 produced a large volume of pumice that drifted westward for ~1300 km to the Nansei Islands, Japan, and some extent. In February 2022, pumice with similar characteristics to the FOB pumice was deposited along the Gulf of Thailand. The pumice clasts deposited in Songkhla Province, Thailand, were fine-grained with <4 cm in size and rounded. Most of the clasts consisted of clinopyroxene, plagioclase (andesine), and olivine phenocrysts in a vesiculated grey groundmass, with black-coloured spots exhibiting signatures of a basaltic magma. The whole-rock compositions of the pumice are trachytic, with 61 mass% SiO 2 and 9 mass% total alkali (Na 2 O + K 2 O). The overall characteristics in the pumice from Thailand are similar to those in FOB pumice. These pumice in Thailand were from the 2021 FOB eruption, and drifted >2800 km south-westward across the South China Sea.

Age and petrogenesis of ultramafic lamprophyres of the Arbarastakh alkaline-carbonatite complex, Aldan-Stanovoy shield, South of Siberian Craton (Russia): evidence for ultramafic lamprophyre-carbonatite link

Abstract: In this study, we discuss mineral chemistry data, melt inclusion study results, and report Ar-Ar phlogopite age for the aillikite dykes of the Arbarastakh alkaline-carbonatite complex on the Aldan-Stanovoy shield, Russia. Aillikite was crystallised at 631 ± 8.5 Ma, coeval with the intrusion age of the Arbarastakh rocks. The Arbarastakh complex was formed during the late Neoproterozoic epoch of REE-Nb ore-bearing alkaline-carbonatite magmatic activity that was widespread on the southwestern and southern margins of the Siberian craton, related to rifting processes during the breakup of the supercontinent Rodinia. The aillikites show mineralogical characteristics of primitive magmas such as highly forsteritic olivine, Mg-ilmenite, and Cr-rich spinel. The variance in olivine zonation, morphologies, and chemical element distribution indicate that olivine in the aillikites is represented by several genetic types: xenogenic olivines (Fe-poor cores) from the sheared peridotite; olivine antecrysts (Fe-rich cores) related to mantle metasomatism by preceding proto-aillikite melt; and olivine phenocrysts formed during crystallization of aillikite melt. The latter shows decreasing Ni and Cr due to fractional crystallization of olivine, ilmenite, and chromite; along with increasing Mn and Ca concentrations that are consistent with enrichment of these elements in the residual melt. The olivine phenocrysts chemistry shows variations that are characteristic of the presence of phlogopite and carbonate in the mantle source (low 100*Ca/Fe (0.4-1.2) and 100*Mn/Fe (1-2), moderate 100*Ni/Mg (1.4-0.4)). Spinel shows a wide compositional variation with two compositional zoning trends, one of which follows the titanomagnetite trend, while the other follows the qandilite-rich magnesio-ulvöspinel-magnetite one. The latter trend indicates an increase in fO2 and attendant Fe oxidation to Fe3+ during crystallization. Ilmenite composition evolution (from Mg-rich to Mn-rich) also reflects the carbonate-rich nature of aillikite melt. We identify primary melt inclusions hosted in phlogopite and secondary melt inclusions in olivine; both melt inclusions types have daughter minerals dominated by dolomite, calcite, Na-Ca carbonates, phosphates, and phlogopite, consistent with the carbonate-rich nature of aillikite melt. The calculated temperatures reflect the early stage of aillikite crystallization, with values ranging from 1169 to 1296°C and fO2 values (olivine-spinel pair) varying from +0.40 to +1.03 ΔFMQ, and from ΔNNO −0.9 to ΔNNO −2.0 (perovskite oxygen barometer); in contrast, the homogenization temperature of the secondary melt inclusions in olivine (700-720 °C) characterizes late-stage aillikite melt evolution. The carbonate-rich nature of the Arbarastakh aillikite and its similar age to the carbonatites are consistent with a genetic relationship between them.

La Queglia carbonatitic melnöite: a notable example of an ultra-alkaline rock variant in Italy

Abstract: Abstract Very primitive ultramafic igneous rocks occur at Mt. La Queglia (Abruzzo, Italy). They form a strongly deformed sill–dyke system now tilted vertically. These rocks were initially classified as alnöite and, subsequently, have been suggested to be a carbonatitic olivine melilitite. However, further investigation and interpretation of these rocks is needed due to the presence of hand-specimen-scale textural variation suggesting a complex petrogenesis. We study the texture, mineral chemistry, and whole-rock geochemistry to define three main rock-types. (1) A brecciated rock with an ocellar texture composed of calcite pseudomorphs after olivine and melilite, plus fresh diopside in a groundmass of mica, aegirine, garnet, calcite, apatite, perovskite, titanate and chlorite. Zoned ocelli in this rock show an amoeboid shape, agglutination, and menisci typical of a plastic state. (2) A quenched rock showing a spinifex texture containing long feathery phenocrysts of cpx and mica suspended in a groundmass of nepheline, aegirine, apatite, Ti–rich magnetite, plus abundant calcite and some K-feldspar and zeolites. (3) A coarse-grained rock is composed of calcite plus intergranular glauconite, a mixture of spinel mineral group and Ti–rich magnetite, accessory barite, pyrite, and chabazite-K. The igneous rocks at Mt. La Queglia show extreme SiO 2 -undersaturation (33.5–37.3 wt% SiO 2 ), high MgO contents and TiO 2 /Al 2 O 3 ratios. Rock-type 1 has a lower Mg number Mg# = 100 × [Mg/(Mg + Fe 2+ )], higher Ca number Ca# = 100 × [Ca/(Ca + Mg)], high Cr (up to 720 ppm) Ni (up to 379 ppm), higher rare earth elements (REE) contents as well as La/Lu ratio, compared to rock-type 2. Perovskite and chromite accumulation seems an important agent during rock differentiation. Rock-type 3 shows REE cross-over with rock-type 2 suggesting light (L)REE concentration in a carbothermal residuum. Mt. La Queglia rocks are an end-member compared to other Upper Cretaceous and Paleogene Italian lamprophyres, suggesting a low degree of melting of a HIMU (a colloquialism for “high-μ”; referring to mantle domains with high 238 U/ 204 Pb) garnet-bearing mantle source.

Automated Segmentation of Olivine Phenocrysts in a Volcanic Rock Thin Section Using a Fully Convolutional Neural Network

Abstract: An example of automated characterization and interpretation of the textural and compositional characteristics of solids phases in thin sections using machine learning (ML) is presented. In our study, we focus on the characterization of olivine in volcanic rocks, which is a phase that is often chemically zoned with variable Mg/(Mg + Fe) ratios, so-called magnesian number or mg#. As the olivine crystals represent only less than 10 vol% of the volcanic rock, a pre-processing step is necessary to automatically detect the phases of interest in the images on a pixel level, which is achieved using Deep Learning. A major contribution of the presented approach is to use backscattered electron (BSE) images to: 1) automatically segment all olivine crystals present in the thin section; 2) determine quantitatively their mg#; and 3) identify different populations depending on zoning type (e.g., normal vs reversal zoning) and textural characteristics (e.g., microlites vs phenocrysts). The segmentation of the olivine crystals is implemented with a pretrained fully convolutional neural network model with DeepLabV3 architecture. The model is trained to identify olivine crystals in backscattered electron images using automatically generated training data. The training data are generated automatically from images which can easily be created from X-Ray element maps. Once the olivines are identified in the BSE images, the relationship between BSE intensity value and mg# is determined using a simple regression based on a set of microprobe measurements. This learned functional relationship can then be applied to all olivine pixels of the thin section. If the highest possible map resolution (1 micron per 1 pixel) is selected for the data acquisition, the full processing time of an entire thin section of ∼ 3 × 4 c m containing more than 1,500 phenocrysts and 20.000 microliths required 140 h of data acquisition (BSE + X-Ray element maps), 8 h of training and 16 h of segmentation and classification. Our further tests demonstrated that the 140 h of data acquisition can be reduced at least by a factor of 4 since only a part of the thin section area (25% or even less) needs to be used for training. The characterization of each additional thin section would only require the BSE data acquisition time (less than 48 h for a whole thin section), without an additional training step. The paper describes the training and processing in detail, shows analytical results and outlines the potential of this Deep Learning approach for petrological applications, resulting in the automatic characterization and interpretation of mineral textures and compositions with an unprecedented high resolution.

Mineral Chemistry and Trace Element Composition of Clinopyroxenes from the Middle Cambrian Ust’-Sema Formation Ankaramites and Diopside Porphyry Basalts and the Related Barangol Complex Intrusions, Gorny Altai, Russia

Abstract: The origin and geodynamic settings of the Ust’-Sema Formation and the Barangol Complex are some of the most controversial issues in the Early Paleozoic history of the Altai–Sayan Fold Belt. The Ust’-Sema Formation volcanic rocks are enriched in high-Ca clinopyroxene phenocrysts and were classified as ankaramites and diopside porphyry basalts. In this work, we first present LA-ICP-MS analyses of the clinopyroxenes, along with studies of the petrography, mineral composition, and whole-rock chemistry of the Ust’-Sema Formation and related Barangol Complex rocks. An LA-ICP-MS clinopyroxene study showed a slight depletion of light rare-earth elements (La/Yb)N = 0.1–1.0 (on average 0.4); and strong depletion of the high-field-strength elements (Zr, Hf, and Nb) and large-ion lithophile (Rb) elements. An Sr anomaly showed a positive correlation with Mg#. Major- and trace-element composition of the clinopyroxene cores show that these clinopyroxene grains were not captured from the mantle rocks as previously assumed and that the Ust’-Sema Formation and the Barangol Complex rocks were formed from magma with island arc characteristics. The increased titanium and light rare-earth element contents in the phenocryst rims from Biyka volcano suggest an active interaction of the ankaramitic magma with rocks or melts of OIB type.

Blue coloured haüyne from Mt. Vulture (Italy) volcanic rocks: SEM‐EDS and Raman investigation of natural and heated crystals

Abstract: Haüyne mineral, belonging to sodalite group, characterizes two lithotypes of Mount Vulture area (Italy): phonolite of Toppo San Paolo and haüynophyre of Melfi. In the latter, haüyne phenocrysts can appear colourless-white, grey-to-black or blue in colour. The blue colour of these crystals—sometimes in literature classified as lazurite—is known to be due to the presence of S 3 − polysulphides radical anion chromophores. Since it has been previously observed that heating these rocks up to 750 °C in oxidizing conditions leads haüyne crystals to acquire the blue colour, it was decided to investigate the reasons of this chromatic transformation. SEM-EDS and Raman spot microanalyses were performed on single crystals of the pristine rocks; furthermore, detailed X-ray and Raman maps were carried out on two white and two black haüyne crystals of haüynophyre before and after heating up to 750 °C. This allowed to investigate the role of very fine inclusions in the chromatic change: the sulphur-, barium- and iron-based species included in haüyne, principally ‘pyrrhotite-like’ crystals and baryte, with the increasing of temperature and under control of oxygen and sulphur fugacity, give rise to the formation of new phases, chiefly haematite and new baryte crystals and of S 3 − groups.

Substitution of ‘small’ divalent cations (e.g. Mg) for Si and Al in the nepheline tetrahedral framework: 2. The occurrence of Mg-rich nepheline and kalsilite

Abstract: Abstract Natural nepheline usually contains very small amounts of MgO (<0.1 wt.%), although these examples are mainly from Mg-poor alkaline igneous rocks such as nepheline syenites. However, this work shows that nepheline and kalsilite with much higher MgO concentrations can occur in the groundmass of strongly SiO2-undersaturated, feldspar-free, mafic volcanic rocks (i.e. olivine-rich foidites). Furthermore, a strong positive correlation is evident between their Mg and Fe contents. The occurrence of Mg-rich nepheline and kalsilite seems to be related to their derivation from Mg-rich magmas when compared to most of the host rocks investigated to date. Additionally, the physicochemical conditions of crystallisation seem to have an important role in the incorporation of ‘small’ divalent cations by these minerals. The prevalence of Mg-rich nepheline and kalsilite as late magmatic phases and the divergent Mg and Fe relationships for phenocrysts and ‘quenched’ groundmass crystals support this hypothesis. The positive correlation between Mg and Fe contents reflects their strong geochemical affinity and the entrance of Fe3+, Fe2+ and Mg2+ cations into the same crystallographic site of nepheline and kalsilite structures. The calculation of atomic formulae and stoichiometry parameters for nepheline-group minerals where data for the T2+ cations (e.g. Mg2+) are incorporated gives more reliable compositional parameters (see Paper 1). Calculated excess silica values (Si′) are affected significantly when the coupled substitution 2Al3+ = Mg2+ + Si4+ is considered. Thus, specific analyses of ‘small’ divalent cations are essential to obtain more realistic values of excess Si′, in particular, for nepheline and kalsilite that crystallised from Mg-rich, Si-poor, mafic–ultramafic alkaline lavas.

Polymagmatic Glaciovolcanism: Cracked Mountain Tuya, Canadian Cascades

Abstract: Monogenetic volcanoes are characterized as having no temporal break in eruptive activity and are often assumed to have a simple (singular) magmatic plumbing system. However, recent studies on monogenetic systems have started to recover evidence of complexities within the magma-crustal dynamics. Here we investigate Cracked Mountain (CM), a 401 ± 38 ka glaciovolcanic basaltic landform in southwest, British Columbia, Canada. The volcano covers an area of ∼1.5 km2, has an eruptive volume of ∼0.18 km3, and comprises lapilli tuff, breccia, peperite, pillow and sheet lava, and dykes with no erosional surfaces present between the stratigraphic successions. The paleomagnetic signature of all volcanic lithofacies records a single-pole direction and, in conjunction with stratigraphic evidence, implies a monogenetic eruption. We establish that the Cracked Mountain volcano was fed by two separate crustally-stored magmas (i.e., polymagmatic), each characterized by a unique phenocryst assemblage indicative of different pre-eruptive storage conditions. The first mineral assemblage is an olivine-and-plagioclase phyric (OP) suite, and the second is an olivine-plagioclase-and-augite phyric (OPA) suite. The major-element geochemical compositions of the two petrographic suites vary slightly, with OPA samples higher in SiO2 and total-alkali contents than OP. The two magmas have similar rare earth (REE) trace element signatures, suggesting the same mantle source. We use thermodynamic modeling (Rhyolite-MELTS) to show that the OP suite derives from magma stored at depths <6 km (< 2 kbar) and temperatures of 1240–1155°C. In contrast, the OPA magmas crystallized at depths between 7–9 km (∼2–2.5 kbar) at 1,250–1,150°C prior to eruption. Both magmas are shown to be nearly “dry” having less than 0.5 H2O wt% in their respective systems. We use Pearce Element Ratios (PER) to show that the chemical variations within and between the two CM magmas are controlled solely by the crystal fractionation of two phenocryst assemblages that underwent syn-eruptive mixing. This study concludes that the polymagmatic plumbing system at Cracked Mountain shows similar complexities to other global investigations of monogenetic volcanoes. Lastly, we propose a causal link between the crustal dynamics of magma systems and the impact of crustal loading and unloading during cycles of glaciation.

Petrographic characteristics in the pumice clast deposited along the Gulf of Thailand, drifted from Fukutoku-Oka-no-Ba

Abstract: The 2021 eruption of Fukutoku-Oka-no-Ba (FOB) in the northwest Pacific on 13 August 2021 produced a large volume of pumice that drifted westward for ~1300 km to the Nansei Islands, Japan, and some extent. In February 2022, pumice with similar characteristics to the FOB pumice was deposited along along the Gulf of Thailand. The pumice clasts deposited in Songkhla Province, Thailand, were <4 cm in length and rounded. Most of the clasts consisted of clinopyroxene, plagioclase (andesine), and olivine phenocrysts in a vesiculated grey groundmass, with black-coloured spots exhibiting signatures of a basaltic magma. The whole-rock compositions of the pumice are trachytic, with 61 mass% SiO2 and 9 mass% total alkali (Na2O + K2O). The overall characteristics in the pumice from Thailand are similar to those in FOB pumice. These pumice in Thailand were from the 2021 FOB eruption, and drifted >2800 km south-westward across the South China Sea.

Magmatic immiscibility and the origin of magnetite-(apatite) iron deposits

Abstract: Abstract The origin of magnetite-(apatite) iron deposits (MtAp) is among the most contentious issue in ore geology with competing models involving purely hydrothermal to magmatic processes. We study here melt inclusions trapped in plagioclase phenocrysts in andesite hosting the emblematic MtAp mineralization at El Laco, Chile. Our high-resolution study reveals that individual melt inclusions preserve complex processes of melt immiscibility including the separation of Si- and Fe-rich melts, the latter hosting other Cu-sulfide, phosphate-rich, and C-O-HFSE-rich residual melts. This assemblage is a small-scale analogue of the ore mineralization and establishes the missing link between silicate and Fe-P-rich melts which subsequently produce extrusive magnetite. These results strongly indicate that El Laco mineralization derives from crystallization of Fe-P-rich melts providing insight into the formation of similar deposits elsewhere.

Plumbing system architecture of late-stage hotspot volcanoes in eastern Australia

Abstract: Eastern Australia encompasses the longest track (~2000 km) of age-progressive continental volcanoes on Earth. These so-called “central volcanoes” are shield volcanoes considered as surficial expressions of Cenozoic mantle plume activity under the northward moving Australian continent. Here, we investigate three central volcanoes located in the southern, younger part of the volcanic track (Ebor, Nandewar, and Canobolas) with the aim of unravelling the plumbing system architecture during waning hotspot activity. We explore the duration of volcanic activity and compare long-term evolution of magmatic processes via 40Ar/39Ar geochronology, mineral and groundmass chemistry, mineral-melt thermobarometry, and Rhyolite-MELTS thermodynamic simulations. 40Ar/39Ar geochronology on groundmass and mineral separates indicates that Ebor is the oldest of the three volcanoes, with a duration of at least ~1 Ma (20.4 ± 0.09 to 19.4 ± 0.07 Ma). Nandewar also lasted ~1 Ma (19.4 ± 0.03 to 18.5 ± 0.03 Ma). The Canobolas volcanic complex was younger and shorter-lived at ~0.5 Ma (12.0 ± 0.02 to 11.55 ± 0.05 Ma). Interestingly, all three volcanoes share a repetitive tempo of ~0.1 Ma between eruptions. The volcanoes produced porphyritic to aphyric lavas with basalt to trachyte compositions. The phenocryst assemblage includes plagioclase and K-feldspar, pink and green clinopyroxene, rare olivine, and titanomagnetite. Textural and compositional zoning of phenocrysts reveals successive events of mafic replenishment and magma transport prior to eruption. Dissolution textures in plagioclase, coupled with increasing An and FeOt and decreasing Ba and Ce from crystal cores to mantles, indicate recharge with mafic, oxidised melt. Increasing Mg# and Cr from clinopyroxene cores to rims also supports primitive magma replenishment. Mineral-melt thermobarometry and Rhyolite-MELTS simulations indicate a main level of magma storage in the three volcanoes in the middle crust (18–25 km depth; ~1100 °C), repeatedly replenished by undegassed, primitive melts. A positive correlation between porphyricity and maficity in the lavas and their crystal cargoes suggests enhanced phenocryst transport by mafic magma influx. Green clinopyroxene cores crystallised in isolated pockets where magmas underwent extensive fractionation at depths of 15 to 30 km and ~800 °C. The shallow level plumbing system was volumetrically minor and dominated by crystallisation of low-An plagioclase with large melt inclusions, possibly crystallised from degassed, reduced and evolved magma, as suggested by plagioclase hygrometry and fO2 modelling. Our combined geochronological and geochemical approach reveals that the three spatially separated but genetically linked volcanoes had comparable, complex plumbing system architectures. Fractionation and repeated magma rejuvenation were critical processes throughout the lifespans of volcanism, and eruptive tempos were controlled by recurrent mafic influx. Other volcanoes active during the late stages of plume activity in eastern Australia share similar textural and geochemical features, suggesting that waning hotspot activity may result in increased complexity in magma transport and storage.