Topic
Photoemission spectroscopy
About: Photoemission spectroscopy is a research topic. Over the lifetime, 10821 publications have been published within this topic receiving 250888 citations. The topic is also known as: photoelectron spectroscopy & PES.
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TL;DR: In this article, a method for global analysis of x-ray photoelectron spectra of plasma-deposited polymer films is presented, which is based on fitting a series of spectra obtained by monitoring the surface composition of a plasma polymer film over extended periods of time after deposition.
Abstract: A protocol for global analysis of x-ray photoelectron spectra of plasma-deposited polymer films is presented. These materials are difficult to analyse because of the multitude of different chemical groups present. The combination of different primary and secondary binding energy shifts results in relatively broad, featureless photoelectron peaks. The protocol is based on fitting a series of spectra obtained by monitoring the surface composition of a plasma polymer film over extended periods of time after deposition. Information obtained from this first round of curve-fitting is used in the form of additional constraints for a second round of fitting. This leads to a self-consistent procedure which is akin to a global approach to curve-fitting. To illustrate application of this method, results of a study of ann-heptylamine plasma polymer are described. The spectral changes on ageing provided clear evidence for radical-initiated oxidation reactions. These reactions generated additional radicals, which sustained the oxidation process for many months and not only led to substantial incorporation of oxygen into the material (forming a variety of carbon–oxygen functionalities) but also to conversion of most of the existing carbon–nitrogen functionalities to an oxidized form.
171 citations
TL;DR: The results demonstrate that the topological surface state on Bi2Se3 is highly spin polarized and that the dominant factors limiting the polarization are mainly extrinsic.
Abstract: We performed high-resolution spin- and angle-resolved photoemission spectroscopy studies of the electronic structure and the spin texture on the surface of Bi{sub 2}Se{sub 3}, a model TI. By tuning the photon energy, we found that the topological surface state is well separated from the bulk states in the vicinity of k{sub z} = Z plane of the bulk Brillouin zone. The spin-resolved measurements in that region indicate a very high degree of spin polarization of the surface state, {approx}0.75, much higher than previously reported. Our results demonstrate that the topological surface state on Bi{sub 2}Se{sub 3} is highly spin polarized and that the dominant factors limiting the polarization are mainly extrinsic.
171 citations
TL;DR: In this paper, the origin of the carbon nanomesh template arises from the self-organization of excess carbon atoms forming a honeycomb arrangement atop the 6H-SiC(0, 0,0,1) surface after annealing at 1100°C.
170 citations
TL;DR: A giant Rashba-type spin splitting on a semiconducting substrate by means of a Bi-trimer adlayer on a Si(111) wafer with an energy much larger than what has previously been reported for any semiconductor heterostructure is demonstrated.
Abstract: We demonstrate a giant Rashba-type spin splitting on a semiconducting substrate by means of a Bi-trimer adlayer on a Si(111) wafer. The in-plane inversion symmetry is broken inducing a giant spin splitting with a Rashba energy of about 140 meV, much larger than what has previously been reported for any semiconductor heterostructure. The separation of the electronic states is larger than their lifetime broadening, which has been directly observed with angular resolved photoemission spectroscopy. The experimental results are confirmed by relativistic first-principles calculations.
170 citations
TL;DR: In this article, the authors show that the thermodynamic balance between fission and fusion of excitons can be tuned by the dielectric environment and charge carrier doping and observed by photoemission spectroscopy.
Abstract: When electron-hole pairs are excited in a semiconductor, it is a priori not clear if they form a plasma of unbound fermionic particles or a gas of composite bosons called excitons. Usually, the exciton phase is associated with low temperatures. In atomically thin transition metal dichalcogenide semiconductors, excitons are particularly important even at room temperature due to strong Coulomb interaction and a large exciton density of states. Using state-of-the-art many-body theory, we show that the thermodynamic fission–fusion balance of excitons and electron-hole plasma can be efficiently tuned via the dielectric environment as well as charge carrier doping. We propose the observation of these effects by studying exciton satellites in photoemission and tunneling spectroscopy, which present direct solid-state counterparts of high-energy collider experiments on the induced fission of composite particles. Owing to their atomically thin nature, 2D transition metal dichalcogenides host room temperature, strongly bound excitons. Here, the authors show that the thermodynamical balance between fission and fusion of excitons can be tuned by the dielectric environment and charge carrier doping and observed by photoemission spectroscopy.
168 citations