Showing papers on "Photovoltaic system published in 2007"

Conjugated polymer-based organic solar cells

Abstract: The need to develop inexpensive renewable energy sources stimulates scientific research for efficient, low-cost photovoltaic devices.1 The organic, polymer-based photovoltaic elements have introduced at least the potential of obtaining cheap and easy methods to produce energy from light.2 The possibility of chemically manipulating the material properties of polymers (plastics) combined with a variety of easy and cheap processing techniques has made polymer-based materials present in almost every aspect of modern society.3 Organic semiconductors have several advantages: (a) lowcost synthesis, and (b) easy manufacture of thin film devices by vacuum evaporation/sublimation or solution cast or printing technologies. Furthermore, organic semiconductor thin films may show high absorption coefficients4 exceeding 105 cm-1, which makes them good chromophores for optoelectronic applications. The electronic band gap of organic semiconductors can be engineered by chemical synthesis for simple color changing of light emitting diodes (LEDs).5 Charge carrier mobilities as high as 10 cm2/V‚s6 made them competitive with amorphous silicon.7 This review is organized as follows. In the first part, we will give a general introduction to the materials, production techniques, working principles, critical parameters, and stability of the organic solar cells. In the second part, we will focus on conjugated polymer/fullerene bulk heterojunction solar cells, mainly on polyphenylenevinylene (PPV) derivatives/(1-(3-methoxycarbonyl) propyl-1-phenyl[6,6]C61) (PCBM) fullerene derivatives and poly(3-hexylthiophene) (P3HT)/PCBM systems. In the third part, we will discuss the alternative approaches such as polymer/polymer solar cells and organic/inorganic hybrid solar cells. In the fourth part, we will suggest possible routes for further improvements and finish with some conclusions. The different papers mentioned in the text have been chosen for didactical purposes and cannot reflect the chronology of the research field nor have a claim of completeness. The further interested reader is referred to the vast amount of quality papers published in this field during the past decade.

Comparison of Photovoltaic Array Maximum Power Point Tracking Techniques

Abstract: The many different techniques for maximum power point tracking of photovoltaic (PV) arrays are discussed. The techniques are taken from the literature dating back to the earliest methods. It is shown that at least 19 distinct methods have been introduced in the literature, with many variations on implementation. This paper should serve as a convenient reference for future work in PV power generation.

Coaxial silicon nanowires as solar cells and nanoelectronic power sources

Abstract: Solar cells are attractive candidates for clean and renewable power; with miniaturization, they might also serve as integrated power sources for nanoelectronic systems. The use of nanostructures or nanostructured materials represents a general approach to reduce both cost and size and to improve efficiency in photovoltaics. Nanoparticles, nanorods and nanowires have been used to improve charge collection efficiency in polymer-blend and dye-sensitized solar cells, to demonstrate carrier multiplication, and to enable low-temperature processing of photovoltaic devices. Moreover, recent theoretical studies have indicated that coaxial nanowire structures could improve carrier collection and overall efficiency with respect to single-crystal bulk semiconductors of the same materials. However, solar cells based on hybrid nanoarchitectures suffer from relatively low efficiencies and poor stabilities. In addition, previous studies have not yet addressed their use as photovoltaic power elements in nanoelectronics. Here we report the realization of p-type/intrinsic/n-type (p-i-n) coaxial silicon nanowire solar cells. Under one solar equivalent (1-sun) illumination, the p-i-n silicon nanowire elements yield a maximum power output of up to 200 pW per nanowire device and an apparent energy conversion efficiency of up to 3.4 per cent, with stable and improved efficiencies achievable at high-flux illuminations. Furthermore, we show that individual and interconnected silicon nanowire photovoltaic elements can serve as robust power sources to drive functional nanoelectronic sensors and logic gates. These coaxial silicon nanowire photovoltaic elements provide a new nanoscale test bed for studies of photoinduced energy/charge transport and artificial photosynthesis, and might find general usage as elements for powering ultralow-power electronics and diverse nanosystems.

40% efficient metamorphic GaInP∕GaInAs∕Ge multijunction solar cells

Abstract: An efficiency of 40.7% was measured and independently confirmed for a metamorphic three-junction GaInP∕GaInAs∕Ge cell under the standard spectrum for terrestrial concentrator solar cells at 240 suns (24.0W∕cm2, AM1.5D, low aerosol optical depth, 25°C). This is the initial demonstration of a solar cell with over 40% efficiency, and is the highest solar conversion efficiency yet achieved for any type of photovoltaic device. Lattice-matched concentrator cells have now reached 40.1% efficiency. Electron-hole recombination mechanisms are analyzed in metamorphic GaxIn1−xAs and GaxIn1−xP materials, and fundamental power losses are quantified to identify paths to still higher efficiencies.

Solar energy storage using phase change materials

Abstract: The continuous increase in the level of greenhouse gas emissions and the climb in fuel prices are the main driving forces behind efforts to more effectively utilise various sources of renewable energy. In many parts of the world, direct solar radiation is considered to be one of the most prospective sources of energy. However, the large-scale utilisation of this form of energy is possible only if the effective technology for its storage can be developed with acceptable capital and running costs. One of prospective techniques of storing solar energy is the application of phase change materials (PCMs). Unfortunately, prior to the large-scale practical application of this technology, it is necessary to resolve numerous problems at the research and development stage. This paper looks at the current state of research in this particular field, with the main focus being on the assessment of the thermal properties of various PCMs, methods of heat transfer enhancement and design configurations of heat storage facilities to be used as a part of solar passive and active space heating systems, greenhouses and solar cooking.

Reciprocity relation between photovoltaic quantum efficiency and electroluminescent emission of solar cells

Abstract: A rigorous proof for a reciprocity theorem that relates the spectral and angular dependences of the electroluminescence of solar cells and light emitting diodes to the spectral and angular quantum efficiency of photocarrier collection is given. An additional relation is derived that connects the open circuit voltage of a solar cell and its electroluminescence quantum efficiency.

Correlation between Photovoltaic Performance and Impedance Spectroscopy of Dye-Sensitized Solar Cells Based on Ionic Liquids

Abstract: In this work, we study the characteristics of dye-sensitized solar cells using an ionic liquid as the electrolyte and compare them with the response of a solvent-containing electrolyte cell. Impedance spectroscopy is used to derive the key circuit elements determining the photovoltaic performance of the cell. On the basis of this data, photocurrent voltage curves are calculated and compared with experimental results.

Transparent Conducting Oxides for Photovoltaics

Abstract: Transparent conducting oxides (TCOs) are an increasingly important component of photovoltaic (PV) devices, where they act as electrode elements, structural templates, and diffusion barriers, and their work function controls the open-circuit device voltage. They are employed in applications that range from crystalline-Si heterojunction with intrinsic thin layer (HIT) cells to organic PV polymer solar cells. The desirable characteristics of TCO materials that are common to all PV technologies are similar to the requirements for TCOs for flat-panel display applications and include high optical transmissivity across a wide spectrum and low resistivity. Additionally, TCOs for terrestrial PV applications must use low-cost materials, and some may require device-technology-specific properties. We review the fundamentals of TCOs and the matrix of TCO properties and processing as they apply to current and future PV technologies.

Flexible Active Power Control of Distributed Power Generation Systems During Grid Faults

Abstract: The increasing penetration of distributed power generation into the power system leads to a continuous evolution of grid interconnection requirements. In particular, active power control will play an important role both during grid faults (low-voltage ride-through capability and controlled current injection) and in normal conditions (reserve function and frequency regulation). The aim of this paper is to propose a flexible active power control based on a fast current controller and a reconfigurable reference current selector. Several strategies to select the current reference are studied and compared using experimental results that are obtained during an unsymmetrical voltage fault. The results of the analysis allow selection of the best reference current in every condition. The proposed methods facilitate multiple choices for fault ride through by simply changing the reference selection criteria.

Transformerless Inverter for Single-Phase Photovoltaic Systems

Abstract: When no transformer is used in a grid-connected photovoltaic (PV) system, a galvanic connection between the grid and the PV array exists. In these conditions, dangerous leakage currents (common-mode currents) can appear through the stray capacitance between the PV array and the ground. In order to avoid these leakage currents, different inverter topologies that generate no varying common-mode voltages, such as the half-bridge and the bipolar pulsewidth modulation (PWM) full-bridge topologies, have been proposed. The need of a high-input voltage represents an important drawback of the half-bridge. The bipolar PWM full bridge requires a lower input voltage but exhibits a low efficiency. This letter proposes a new high-efficiency topology that generates no varying common-mode voltage and requires the same low-input voltage as the bipolar PWM full bridge. The proposed topology has been verified in a 5-kW prototype with satisfactory results

A Single-Stage Grid Connected Inverter Topology for Solar PV Systems With Maximum Power Point Tracking

Abstract: This paper proposes a high performance, single-stage inverter topology for grid connected PV systems. The proposed configuration can not only boost the usually low photovoltaic (PV) array voltage, but can also convert the solar dc power into high quality ac power for feeding into the grid, while tracking the maximum power from the PV array. Total harmonic distortion of the current, fed into the grid, is restricted as per the IEEE-519 standard. The proposed topology has several desirable features such as better utilization of the PV array, higher efficiency, low cost and compact size. Further, due to the very nature of the proposed topology, the PV array appears as a floating source to the grid, thereby enhancing the overall safety of the system. A survey of the existing topologies, suitable for single-stage, grid connected PV applications, is carried out and a detailed comparison with the proposed topology is presented. A complete steady-state analysis, including the design procedure and expressions for peak device stresses, is included. Necessary condition on the modulation index "M" for sinusoidal pulsewidth modulated control of the proposed inverter topology has also been derived for discontinuous conduction mode operation. All the analytical, simulation and experimental results are presented.

Topology Study of Photovoltaic Interface for Maximum Power Point Tracking

Abstract: This paper looks at the performance of photovoltaic modules in nonideal conditions and proposes topologies to minimize the degradation of performance caused by these conditions. It is found that the peak power point of a module is significantly decreased due to only the slightest shading of the module, and that this effect is propagated through other nonshaded modules connected in series with the shaded one. Based on this result, two topologies for parallel module connections have been outlined. In addition, dc/dc converter technologies, which are necessary to the design, are compared by way of their dynamic models, frequency characteristics, and component cost. Out of this comparison, a recommendation has been made

Nanocrystalline dye‐sensitized solar cells having maximum performance

Abstract: This paper presents an overview of the research carried out by a European consortium with the aim to develop and test new and improved ways to realise dye-sensitized solar cells (DSC) with enhanced efficiencies and stabilities. Several new areas have been explored in the field of new concepts and materials, fabrication protocols for TiO2 and scatterlayers, metal oxide blocking layers, strategies for co-sensitization and low temperature processes of platinum deposition. Fundamental understanding of the working principles has been gained by means of electrical and optical modelling and advanced characterization techniques. Cost analyses have been made to demonstrate the potential of DSC as a low cost thin film PV technology. The combined efforts have led to maximum non-certified power conversion efficiencies under full sunlight of 11% for areas <02 cm2 and 101% for a cell with an active area of 13 cm2. Lifetime studies revealed negligible device degradation after 1000 hrs of accelerated tests under thermal stress at 80°C in the dark and visible light soaking at 60°C. An outlook summarizing future directions in the research and large-scale production of DSC is presented.

Design and characterization of GaN∕InGaN solar cells

Abstract: We experimentally demonstrate the III-V nitrides as a high-performance photovoltaic material with open-circuit voltages up to 2.4V and internal quantum efficiencies as high as 60%. GaN and high-band gap InGaN solar cells are designed by modifying PC1D software, grown by standard commercial metal-organic chemical vapor deposition, fabricated into devices of variable sizes and contact configurations, and characterized for material quality and performance. The material is primarily characterized by x-ray diffraction and photoluminescence to understand the implications of crystalline imperfections on photovoltaic performance. Two major challenges facing the III-V nitride photovoltaic technology are phase separation within the material and high-contact resistances.

Metallated conjugated polymers as a new avenue towards high-efficiency polymer solar cells

Abstract: Bulk heterojunction solar cells have been extensively studied owing to their great potential for cost-effective photovoltaic devices. Although recent advances resulted in the fabrication of poly(3-hexylthiophene) (P3HT)/fullerene derivative based solar cells with efficiencies in the range 4.4-5.0%, theoretical calculations predict that the development of novel donor materials with a lower bandgap is required to exceed the power-conversion efficiency of 10%. However, all of the lower bandgap polymers developed so far have failed to reach the efficiency of P3HT-based cells. To address this issue, we synthesized a soluble, intensely coloured platinum metallopolyyne with a low bandgap of 1.85 eV. The solar cells, containing metallopolyyne/fullerene derivative blends as the photoactive material, showed a power-conversion efficiency with an average of 4.1%, without annealing or the use of spacer layers needed to achieve comparable efficiency with P3HT. This clearly demonstrates the potential of metallated conjugated polymers for efficient photovoltaic devices.

Poly(3‐hexylthiophene) Fibers for Photovoltaic Applications

Abstract: A new method for the preparation of active layers of polymeric solar cells without the need for thermal post-treatment to obtain optimal performance is presented. Poly(3-hexylthiophene) (P3HT) nanofibers are obtained in highly concentrated solutions, which enables the fabrication of nanostructured films on various substrates. Here, the preparation of these fibers along with their characterization in solution and in the solid state is detailed. By mixing these nanofibers with a molecular acceptor such as [6,6]-phenyl C61-butyric acid methyl ester (PCBM) in solution, it is possible to obtain in a simple process a highly efficient active layer for organic solar cells with a demonstrated power conversion efficiency (PCE) of up to 3.6 %. The compatibility of the room-temperature process developed herein with commonly used plastic substrates may lead to applications such as the development of large-area flexible solar cells.

Solar cells utilizing small molecular weight organic semiconductors

Abstract: In this review, we focus on the field of organic photovoltaic cells based on small molecular weight materials. In particular, we discuss the physical processes that lead to photocurrent generation in organic solar cells, as well as the various architectures employed to optimize device performance. These include the donor–acceptor heterojunction for efficient exciton dissociation, the exciton blocking layer, the mixed or bulk heterojunction, and the stacked or tandem cell. We show how the choice of materials with known energy levels and absorption spectra affect device performance, particularly the open-circuit voltage and short-circuit current density. We also discuss the typical materials and growth techniques used to fabricate devices, as well as the issue of device stability, all of which are critical for the commercialization of low-cost and high-performance organic solar cells. Copyright © 2007 John Wiley & Sons, Ltd.

Organic Photovoltaics

Abstract: Solid-state organic photovoltaic technologies are emerging and maturing with reports of power conversion efficiencies close to 5%. This tutorial will provide an overview of the chemistry, the physics and engineering of solar cells based on organic materials.

Thin-film solar cells : review of materials, technologies and commercial status

Abstract: The recent boom in the demand for photovoltaic modules has created a silicon supply shortage, providing an opportunity for thin-film photovoltaic modules to enter the market in significant quantities. Thin-films have the potential to revolutionise the present cost structure of photovoltaics by eliminating the use of the expensive silicon wafers that alone account for above 50% of total module manufacturing cost. The strengths and weaknesses of the contending thin-film photovoltaic technologies and the current state of commercial activity with each are briefly reviewed.

Hybrid solar cells with prescribed nanoscale morphologies based on hyperbranched semiconductor nanocrystals.

Abstract: In recent years, the search to develop large-area solar cells at low cost has led to research on photovoltaic (PV) systems based on nanocomposites containing conjugated polymers. These composite films can be synthesized and processed at lower costs and with greater versatility than the solid state inorganic semiconductors that comprise today's solar cells. However, the best nanocomposite solar cells are based on a complex architecture, consisting of a fine blend of interpenetrating and percolating donor and acceptor materials. Cell performance is strongly dependent on blend morphology, and solution-based fabrication techniques often result in uncontrolled and irreproducible blends, whose composite morphologies are difficult to characterize accurately. Here we incorporate three-dimensional hyperbranched colloidal semiconductor nanocrystals in solution-processed hybrid organic-inorganic solar cells, yielding reproducible and controlled nanoscale morphology.

A Photovoltaic Array Simulation Model for Matlab-Simulink GUI Environment

Abstract: A photovoltaic array (PVA) simulation model to be used in Matlab-Simulink GUI environment is developed and presented in this paper. The model is developed using basic circuit equations of the photovoltaic (PV) solar cells including the effects of solar irradiation and temperature changes. The new model was tested using a directly coupled dc load as well as ac load via an inverter. Test and validation studies with proper load matching circuits are simulated and results are presented here.

High efficiency of CdSe quantum-dot-sensitized TiO2 inverse opal solar cells

Abstract: The authors have demonstrated an approach to sensitized-type solar cells, based on TiO2 inverse opal and the use of CdSe quantum dots (QDs) as sensitizers. CdSe QDs were grown in situ on TiO2 inverse opal electrodes, utilizing a chemical bath deposition method. All of the photovoltaic performances, including short circuit photocurrent density, open circuit voltage, fill factor, and efficiency, were significantly improved by surface modification with ZnS and fluoride ions. A power conversion efficiency of about 2.7% has been attained, under solar illumination of 100mW∕cm2. This value is relatively high for metal oxide solar cells, sensitized with semiconductor QDs.

Impact of widespread photovoltaics generation on distribution systems

Abstract: Prompted by the need for clean energy sources, increasing numbers of photovoltaic (PV) generators are being connected to electricity distribution systems around the world. There is thus a growing imperative to understand and quantify the technical impact that high penetrations of such generators may have on the operation and performance of electricity distribution systems. Detailed simulations of a very high penetration of PV within a typical UK urban distribution network (11 kV, 400 V and 230 V) are reported. The study performed unbalanced three-phase load-flow analysis on an entire feeder within a time-domain simulation framework using load and generation data at 1 minute intervals. The results indicate that even at very high penetrations of PV, network voltage rises are small and unlikely to cause problems. Effects on network power flows and losses are also quantified and discussed