Topic
Platinum
About: Platinum is a research topic. Over the lifetime, 49675 publications have been published within this topic receiving 1150035 citations. The topic is also known as: Pt & element 78.
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TL;DR: Data demonstrate that spherical polyelectrolyte brushes present an ideal carrier system for metallic nanoparticles, and could be explained by the assumption of a pseudo-first-order reaction with regard to p-nitrophenol.
Abstract: We present a study on the catalytic activity of platinum nanoparticles immobilized on spherical polyelectrolyte brushes that act as carriers. The spherical polyelectrolyte brushes consist of a solid core of poly(styrene) onto which long chains of poly(2-methylpropenoyloxyethyl) trimethylammonium chloride are grafted. These positively charged chains form a dense layer of polyelectrolytes on the surface of the core particles ("spherical polyelectrolyte brush") that tightly binds divalent PtCl6-(2) ions. The reduction of these ions within the brush layer leads to nearly monodisperse nanoparticles of metallic platinum. The average size of the particles is approximately 2 nm. The composite particles exhibit excellent colloidal stability. The catalytic activity is investigated by photometrically monitoring the reduction of p-nitrophenol by an excess of NaBH4 in the presence of the nanoparticles. The kinetic data could be explained by the assumption of a pseudo-first-order reaction with regard to p-nitrophenol. In all cases, a delay time t0 has been observed, after which the reactions start. This time is shorter when the catalyst has already been used. All data demonstrate that spherical polyelectrolyte brushes present an ideal carrier system for metallic nanoparticles.
345 citations
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TL;DR: In this paper, sugar-assisted stable monometallic nanoparticles were synthesized by wet chemical method following a general scheme, which corroborates the shift of the absorbance peak positions and TEM analysis.
Abstract: Sugar-assisted stable monometallic nanoparticles were synthesized by wet chemical method following a general scheme. Judicious manipulation of the reducing capabilities of different sugars has shown to have a bearing on the particle size that corroborates the shift of the absorbance peak positions and TEM analysis. Evaporation of the precursor solutions on the solid surface (strong metal--support interaction), led to the formation of smaller particles. Under the experimental condition, spherical nanoparticles of approximately 1, 3, 10 and 20 nm sizes were prepared reproducibly for gold, platinum, silver and palladium, respectively. Fructose has been found to be the best suited sugar for the synthesis of smaller particles and remained stable for months together.
345 citations
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TL;DR: In this article, a simple and versatile technique for the preparation of novel macroporous three-dimensional gold and platinum films with regular submicron spherical holes arranged in a close-packed structure was reported.
Abstract: Here we report a simple and versatile technique for the preparation of novel macroporous three-dimensional gold and platinum films with regular submicron spherical holes arranged in a close-packed structure. Gold and platinum films were prepared by electrochemical reduction of gold or platinum complex ions dissolved in aqueous solution within the interstitial spaces between polystyrene latex spheres (500 or 750 nm in diameter) assembled on gold surfaces. The latex sphere templates were subsequently removed by dissolving in toluene to leave the structured metal films. Scanning electron microscopy of the gold and platinum films shows a well-formed regular three-dimensional, porous structure consisting of spherical voids arranged in a highly ordered face-centered cubic (fcc) structure. The spherical voids have the same diameter as the latex spheres used to form the template. Within the metal film the spherical voids are interconnected through a series of smaller pores. The metallic framework is dense, self-supporting, and free from defects. X-ray studies show the metal to be polycrystalline with a grain size smaller than 100 nm. The optical reflectivity of the macroporous gold and platinum films shows strong diffractive optical properties, which are potentially useful in many existing and emerging applications.
344 citations
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TL;DR: Modulating electron density in a metal sulfide, NiCo2S4, boosts hydrogen desorption to achieve high catalytic activity and provide valuable insights for the rational design of highly efficient catalysts for hydrogen evolution and beyond.
Abstract: Metal sulfides for hydrogen evolution catalysis typically suffer from unfavorable hydrogen desorption properties due to the strong interaction between the adsorbed H and the intensely electronegative sulfur. Here, we demonstrate a general strategy to improve the hydrogen evolution catalysis of metal sulfides by modulating the surface electron densities. The N modulated NiCo2S4 nanowire arrays exhibit an overpotential of 41 mV at 10 mA cm−2 and a Tafel slope of 37 mV dec−1, which are very close to the performance of the benchmark Pt/C in alkaline condition. X-ray photoelectron spectroscopy, synchrotron-based X-ray absorption spectroscopy, and density functional theory studies consistently confirm the surface electron densities of NiCo2S4 have been effectively manipulated by N doping. The capability to modulate the electron densities of the catalytic sites could provide valuable insights for the rational design of highly efficient catalysts for hydrogen evolution and beyond. The hydrogen evolution reaction is a promising route to produce clean hydrogen fuel; however, its efficient electrolytic generation relies on expensive platinum. Here, the authors show how modulating electron density in a metal sulfide, NiCo2S4, boosts hydrogen desorption to achieve high catalytic activity.
344 citations
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TL;DR: A series of platinum terpyridyl acetylide complexes, [Pt(trpy)(C⋮CR)]PF6 (R = C6H5,C6H4Cl-4, C 6H4OCH3-4 and C 6 H4NO2-4), have been synthesized and characterized in this paper.
344 citations