Topic
Polarography
About: Polarography is a research topic. Over the lifetime, 4772 publications have been published within this topic receiving 75478 citations.
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TL;DR: A simple polarographic assay for platinum determination in cis-dichlorodiammineplatinum(II)-DNA complexes is described, which makes it possible to determine the free (unbound) drug in the presence of DNA or platinum-DNA complex without a separation of free drug and macromolecular components of the solution to be analyzed.
24 citations
TL;DR: A theoretical study of the dc polarographic response with the ECE mechanism is presented in this paper, where explicit equations for the current-potential curves with Nernstian behavior and without using the steady-state approximation have been derived.
24 citations
TL;DR: Hexazinone [3-cyclohexyl-6-(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H,3H-dione] (I) is reduced in acidic media at the dropping mercury electrode in two two-electron steps as mentioned in this paper.
Abstract: Hexazinone [3-cyclohexyl-6-(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H,3H-dione] (I) is reduced in acidic media at the dropping mercury electrode in two two-electron steps. The first step corresponds to a reduction of a protonated azomethine bond which is complicated at pH 2-4 by the establishment of a hydration-dehydration equilibrium. Measurement of the first wave at pH 3.7 is suitable for analytical purposes and was used for following the adsorption of hexazinone on lignin. In comparison with acifluorfen, thiram, and DCNA, which had been studied earlier, hexazinone is less strongly adsorbed and is rapidly desorbed
24 citations
TL;DR: In this article, the interaction of nicotinamide with tryptophan in the presence and absence of nickel(II) in 0.1 M ammonium tartrate (pH 8.94) has been examined by voltammetric techniques.
24 citations
TL;DR: Extraction with 95% ethanol followed by polarographic reduction was selected as the basis of a method for the determination of flutamide as a pure compound and in tablets.
24 citations