Topic
Polarography
About: Polarography is a research topic. Over the lifetime, 4772 publications have been published within this topic receiving 75478 citations.
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TL;DR: In this article, the inhibitory effect of three homologous dialkyl-phenyl-phosphine oxides (C 6 H 5 (R) 2 ) PO; R=C 2 H 5, C 3 H 7, C 4 H 9 ) on the Cu 2+ discharge reaction at a fully covered dropping mercury electrode has been investigated by the polarographic technique.
23 citations
TL;DR: Of 26 pyrimidines investigated, 10 have been found to reduce at the dropping mercury electrode and it appears that 6-aminopyrimidine may tautomerize.
23 citations
TL;DR: In this article, double potential step chronocoulometry was employed to measure both the parameters for R adsorption and the rate of electrohydrodimerization (EHD) of the R molecules adsorbed on the electrode surface under conditions in which the contribution to the faradaic current from R molecules diffusing towards the electrode is entirely negligible.
23 citations
TL;DR: In this paper, the electrochemical properties of the compounds NbnW6−nO19(2+n)− were studied by polarography, controlled potential electrolysis and cyclic voltammetry on the mercury electrode.
23 citations
TL;DR: In this paper, the faradaic response of a slow electron transfer to a triple pulse of potentials was derived for the planar approximations of a static mercury drop electrode and the dropping mercury electrode.
Abstract: The faradaic response of a slow electron transfer to a triple pulse of potentials was derived for the planar approximations of a static mercury drop electrode and the dropping mercury electrode. The analytical solution obtained for a static mercury drop electrode is subject to no constraints in the time interval over which the different potentials are applied. The effects of the formation of the double layer have not been taken into account in the mathematical treatment
23 citations