Topic
Polarography
About: Polarography is a research topic. Over the lifetime, 4772 publications have been published within this topic receiving 75478 citations.
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TL;DR: In this article, cyclic voltammograms were used to show that the B12r+e→B12s electron transfer reaction at a mercury drop electrode is quasi-reversible with a ks=1.7±0.3 cm s−1 in 0.0667 M KH2PO4−Na2HPO4.
21 citations
TL;DR: From polarographic and voltammetric measurements using carrier concentrations of the long lived isotope 99Tc, appropriate ranges of electrode potential for electrolytic reduction were determined and reaction conditions were predicted and experimentally confirmed for the electrolytic labelling of tetracycline and EDTA with carrier free 99mTc.
21 citations
TL;DR: In this article, an exact equation for the instantaneous catalytic current in pulse polarography was derived, which coincides with that of Koutecký for normal polarography, when the time elapsed without voltage application to the mercury drop is null.
21 citations
TL;DR: Le complexe d'Ag(II) avec l'hexamethyltetraazacyclotetradecane, en solution aqueuse, subit une oxydation reversible a un electron avec formation du complexe de Ag(III) as mentioned in this paper.
Abstract: Le complexe d'Ag(II) avec l'hexamethyltetraazacyclotetradecane, en solution aqueuse, subit une oxydation reversible a un electron avec formation du complexe d'Ag(III)
20 citations
20 citations