Topic
Polarography
About: Polarography is a research topic. Over the lifetime, 4772 publications have been published within this topic receiving 75478 citations.
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TL;DR: In this paper, the polarographic and voltammetric properties of tetraethylammonium hexacyanoferrate (III) were investigated in formamide, N-methylformamide, methanol, propylenecarbonate, N,N-dimethylthioformamide and butyrolactone.
38 citations
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TL;DR: An equation for the A.C. polarographic current is derived from considerations of concentration changes produced at the dropping mercury electrode in virtue of the superposition of a small sinusoidal alternating voltage onto the direct potential, for the case of reversibly reduced inorganic ions.
Abstract: An equation for the A.C. polarographic current is derived from considerations of concentration changes produced at the dropping mercury electrode in virtue of the superposition of a small sinusoidal alternating voltage onto the direct potential, for the case of reversibly reduced inorganic ions. The equation predicts the magnitude of the A.C. polarographic current at any point on the polarogram.
38 citations
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TL;DR: In this article, the simultaneous diffusion of different metal species with unequal diffusion coefficients in a metal complex system is considered, and a comprehensive account is given of the conditions under which the mean diffusion coefficient D is operative.
38 citations
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TL;DR: In this article, a polarographic detector is described and its performance is compared with that of a commercial solid-state amperometric detector using a glassy carbon electrode and with a UV detector.
38 citations
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TL;DR: In this article, the antimony film was deposited in situ on a carbon paste substrate electrode and employed in chronopotentiometric stripping mode in deoxygenated solutions of 0.01 M hydrochloric acid (pH 2).
38 citations