Topic
Polyoxometalate
About: Polyoxometalate is a research topic. Over the lifetime, 3493 publications have been published within this topic receiving 94123 citations. The topic is also known as: POM.
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TL;DR: Using magnetization measurements and multifrequency high-field electron paramagnetic resonance, the largest zero-field splitting for any individual isolated Mn(II) ion has been found in a polyoxometalate complex, suggesting that the inorganic ligand induces large Ising-type magnetic anisotropy.
Abstract: Using magnetization measurements and multifrequency high-field electron paramagnetic resonance, the largest zero-field splitting for any individual isolated MnII ion has been found in a polyoxometalate complex, suggesting that the inorganic ligand induces large Ising-type magnetic anisotropy.
34 citations
27 Aug 2021
34 citations
TL;DR: In this paper, the Wells-Dawson polyoxometalate K6[P2W18O62] is grown as an interfacial layer between indium tin oxide and bulk heterojunction of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM).
Abstract: In this article the Wells–Dawson polyoxometalate K6[P2W18O62] is grown as an interfacial layer between indium tin oxide and bulk heterojunction of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM). The structure of the POM layers depends on the thickness and shows a highly anisotropic surface organization. The films have been characterized by atomic force microscopy and X-ray photoelectron spectroscopy (XPS) to gain insight into their macroscopic organization and better understand their electronic properties. Then, they were put at the anodic interface of a P3HT : PCBM organic solar cell and characterized on an optical bench. The photovoltaic efficiency is discussed in terms of the benefit of the polyoxometalate at the anodic interface of an organic photovoltaic cell.
34 citations
TL;DR: In this paper, the synthesis and characterization of di-nuclear HfIV and ZrIV complexes (the Dawson 2:2-type complexes) sandwiched between two mono-lacunary α2-Dawson polyoxometalate (POM) ligands was described.
34 citations
TL;DR: The observation of the formation process of hybrids by TEM shows that ethanol plays an important role in the self-assembly, and the hexagonal mesostructure can transform into nanofibers comprising nanofibrils in water through the disassembly.
Abstract: Hexagonally mesostructured polyoxometalate-based hybrid was prepared by a mild-solution method through the self-assembly of an amphiphilic poly(ethylene oxide) octadecyldimethylammonium (C18NEO12) and a polyanionic silicotungstic acid (HSiW). The composition of the hybrid was characterized through 1H NMR, infrared spectroscopy, mass spectroscopy, elemental analysis, and thermogravimetric analysis, indicating an approximate formula (C18NEO12)1.6H2.4(SiW12O40). The structure of the hybrid was investigated by transmission electron microscopy (TEM), scanning electron microscopy, X-ray powder diffraction, and contact angle measurement. The hybrid is a rodlike grain with the hexagonal mesostructure, which consists of one-dimensional column micelles in which alkyl chains of C18NEO12 locate at the center and poly(ethylene oxide) (PEO) part at the outside, with HSiWs anchoring at the interface, but more close to the PEO part. Furthermore, the observation of the formation process of hybrids by TEM shows that ethano...
34 citations