Topic
Polyoxometalate
About: Polyoxometalate is a research topic. Over the lifetime, 3493 publications have been published within this topic receiving 94123 citations. The topic is also known as: POM.
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TL;DR: In this paper, the performance of tungstophosphoric acid (H 3 PW 12 O 40 ) as a polyoxometalate (POM) on graphene oxide (GO) and two reduced graphene oxide supports was studied using an equilibrium adsorption technique by ultraviolet-visible spectroscopy analysis.
32 citations
TL;DR: In this article, a new route to polyoxometalate pillared layered double hydroxides (LDHs) of the type [Mg 1− x 2+ Al x 3+ (OH) 2 ][POM n − ] x/n' where POM n− is the Keggin ion H 2 W 12 O 40 6−, is reported based on the atopotactic reactions of the corresponding LDH carbonate with glycerol or triethyleneglycol at 120-130°C and subsequent ion-exchange
32 citations
TL;DR: The first (7,8)-connected polyoxometalate-based metal-organic framework (POM-MOF) has been constructed from seven- and eight-connected twin Wells-Dawson clusters, and possesses a unique structural motif that contains both organic- inorganic and all-inorganic networks.
Abstract: The first (7,8)-connected polyoxometalate-based metal–organic framework (POM–MOF) has been constructed from seven- and eight-connected twin Wells–Dawson clusters, and possesses the highest connection number of polyoxometalates to any mixed-connected POM–MOF to date and a unique structural motif that contains both organic–inorganic and all-inorganic networks.
32 citations
TL;DR: A new class of contracted lanthanide-doped MB structures that have replaced all the {Mo2} units with Lanthanide ions on the ring edge with the general formula {Mo90+2nLn10-n} (n = 0, 1).
Abstract: Polyoxometalate Molybdenum blue (MBs) complexes typically exist as discrete multianionic clusters and are composed of repeating Mo building units. MB Wheels, such as {Mo176} and {Mo154} are made fr...
32 citations
TL;DR: In this paper, the photo-induced electrons of SiW11V/graphene nanocomposite were used for exploring POMs sensitizers with lower energy levels than the CB of TiO2.
Abstract: SiW11V/graphene nanocomposite was first prepared and introduced into TiO2 film. It showed a significant photocurrent response, which can be attributed to the photoinduced electrons of SiW11V. This work provides a promising strategy for exploring POMs sensitizers with lower energy levels than the CB of TiO2.
32 citations