Topic
Redox
About: Redox is a research topic. Over the lifetime, 26853 publications have been published within this topic receiving 862368 citations. The topic is also known as: reduction-oxidation & reduction-oxidation reaction.
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TL;DR: This mixed-valence trinuclear copper cluster, which contains copper in the highly oxidized trivalent oxidation state, exhibits O2 bond scission and intriguing structural, spectroscopic, and redox properties.
Abstract: The reaction of metal complexes with dioxygen (O2) generally proceeds in 1:1, 2:1, or 4:1 (metal:O2) stoichiometry. A discrete, structurally characterized 3:1 product is presented. This mixed-valence trinuclear copper cluster, which contains copper in the highly oxidized trivalent oxidation state, exhibits O2 bond scission and intriguing structural, spectroscopic, and redox properties. The relevance of this synthetic complex to the reduction of O2 at the trinuclear active sites of multicopper oxidases is discussed.
233 citations
ARCO1
TL;DR: In this paper, a 15% manganese-5% sodium pyrophosphate-silica (SPSS) catalyst was used to achieve a 17% yield of ethane, ethylene, and higher hydrocarbons for 2 min at 850 °C and 860 GHSV.
233 citations
TL;DR: In this article, it was shown by means of X-ray diffraction to be an Fe(II)-Fe(III)-Sulphate interlayered green rust, GRso4, which belongs to the pyroaurite-sjogrenite group of layered hydroxides.
232 citations
232 citations
TL;DR: The discovery of the enzyme superoxide dismutase that catalyzed the production of hydrogen peroxide from superoxide anion defined the new field of oxygen metabolism in biologic systems and a potential role of oxidation/reduction reactions in both physiologic and pathologic conditions.
232 citations